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Home » Archive » 2023 » issue: #3, September 2023 » Theoretical and experimental studies of the conversion of CO2 to synthesis gas

UNIV. NEWS. NORTH-CAUCAS. REG. TECHNICAL SCIENCES SERIES. 2023; 3: 59-64

 

http://dx.doi.org/10.17213/1560-3644-2023-3-59-64

 

Theoretical and experimental studies of the conversion of CO2 to synthesis gas

I.N. Zubkov, A.N. Saliev, M.A. Timokhina, S.A. Lavrenov, T.G. Ivanova, V.A. Taranushich, R.E. Yakovenko

Ivan N. Zubkov – Junior Researcher Officer, Laboratory «Catalysts and Technologies for Processing of Carbonaceous Materials», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia,  71650021.qwe@mail.ru

Aleksei N. Saliev – Cand. Sci. (Eng.), Associate Professor, Department «Chemical Technology», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia, saliev.aleksei@yandex.ru

Mariya A. Timokhina – Technician, Laboratory «Catalysts and Technologies for Processing of Carbonaceous Materials», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia,  timoxmasha14@mail.ru

Sergey A. Lavrenov – Technician, Laboratory «Catalysts and Technologies for Processing of Carbonaceous Materials», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia,  vip.sergo0195@mail.ru

Tat'yana G. Ivanova – Cand. Sci. (Chim.), Associate Professor, Department «Chemical Technology», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia,  tgalikyan@rambler.ru

Vitaliy A. Taranushich – Dr. Sci. (Eng.), Professor, Department «Chemical Technologу», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia,  vitaliy.taranushich@bk.ru

Roman E. Yakovenko – Can. Sci. (Eng.) Senior Research, Laboratory «Catalysts and Technologies for Processing of  Carbonaceous Materials», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia, jakovenko39@gmail.com

 

Abstract

In this work, by minimizing the value of the Gibbs free energy, thermodynamic studies of the conversion of CO2 into synthesis gas by the reverse reaction of water gas in the temperature range of 300-1000 °C, pressure of 0,1-1,0 MPa and the ratio H2/CO2 = 0,5-3,0. Experimental studies of the process of CO2 conversion in synthesis gas were carried out on an industrial catalyst of the NIAP 06-06 brand at a pressure of 0,1 MPa, a temperature of 500-800 °C, a ratio of H2/CO2 = 1, GHSV 32000 h-1. It has been established that at a temperature of 650 °C, synthesis gas is formed with an H2/CO ratio to 2, which makes it possible to use it in the synthesis of hydrocarbons by the Fischer-Tropsch method or in the synthesis of methanol.

 

Acknowledgments: the work was carried out with the financial support of the Ministry of Education and Science of the Russian Federation within the framework of the state task FENN-2020-0021 (application no. 2019-0990), using the equipment of the CCP "Nanotechnology" of the M. I. Platov SRSPU (NPI).

For citation: Zubkov I.N., Saliev A.N., Timokhina M.A., Lavrenov S.A., Ivanova T.G., Taranushich V.A., Yakovenko R.E. Theoretical and  experimental studies of the conversion of CO2 to synthesis gas. Izv. vuzov. Sev.-Kavk. region. Techn. nauki=Bulletin of Higher Educational Institutions. North Caucasus Region. Technical Sciences. 2023;(3):59-64. (In Russ.). http://dx.doi.org/ 10.17213/1560-3644-2023-3-59-64

 

Keywords: carbon dioxide, synthesis gas, thermodynamic calculations

 

Full text: [in elibrary.ru]

 

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