JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

碳酸锰纳米片阵列的制备及其电化学性能研究

张凯扬 ,  肖元化 ,  吴诗德 ,  苏当成 ,  方少明

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张凯扬, 肖元化, 吴诗德, 等. 碳酸锰纳米片阵列的制备及其电化学性能研究[J]. 轻工学报, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
引用本文: 张凯扬, 肖元化, 吴诗德, 等. 碳酸锰纳米片阵列的制备及其电化学性能研究[J]. 轻工学报, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
shu
ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
Citation: ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
shu

碳酸锰纳米片阵列的制备及其电化学性能研究

  • 1. 郑州轻工业大学 材料与化学工程学院, 河南 郑州 450001;

  • 2. 河南省表界面科学重点实验室, 河南 郑州 450001;

  • 3. 郑州大学 材料科学与工程学院, 河南 郑州 450001

    • 作者简介: 张凯扬(1995—),男,河北省晋州市人,郑州轻工业大学硕士研究生,主要研究方向为电化学能源材料。E-mail:744603481@qq.com;

  • 基金项目: 国家自然科学基金项目(U1904190)
    河南省自然科学基金项目(212300410091)

  • 中图分类号: TM912;TB321

Preparation and electrochemical properties of manganese carbonate nanoplate arrays

  • 1. College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;

  • 2. Key Laboratory of Surface and Interface Science and Technology, Zhengzhou 450001, China;

  • 3. College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

  • Received Date: 2021-04-14
    Accepted Date: 2021-05-25

    CLC number: TM912;TB321

  • 摘要: 为了提高以锰基材料做正极的水系锌离子电池的工作电压,通过溶剂热法一步实现超薄MnCO3纳米片阵列(NA)在泡沫镍基底上的生长,并采用X射线衍射(XRD)、扫描电子显微镜、透射电子显微镜、电池性能测试仪等对其结构、形貌和电化学性能进行了表征。结果表明,该MnCO3纳米片厚度约为30 nm,高度约为500 nm;将该MnCO3 NA直接应用于锌离子电池,在碱性电解液体系中,展现出1.73 V的高工作电压,在0.1 A/g的电流密度下放电比容量达到255.41 mAh/g,且在0.5 A/g的电流密度下进行270次充放电循环后,容量保持率约为83.1%。基于不同电位状态下的非原位XRD和光电子能谱XPS测试表明,该电极的储锌机制为Mn2+转变为Mn3+的单相反应。
    Abstract: In order to increase the working voltage of the aqueous zinc ion batteries with manganese-based material as the positive electrode material, an ultrathin nanosheet array (MnCO3 NA) was grown on a nickel foam substrate by a one-step solvothermal method. The structure, morphology and electrochemical properties of MnCO3 NA were characterized by X-ray diffraction (XRD), scanning electron microscope, transmission electron microscope and battery performance tester. The experiments results showed that the thickness of the MnCO3 NA was about 30 nm and the height was about 500 nm. It was directly applied to the zinc ion battery in the alkaline electrolyte, delivering a high working voltage of 1.73 V, a specific discharge capacity of 255.41 mAh/g at 0.1 A/g, and a capacity retention of 83.1% after 270 charge-discharge cycles at 0.5 A/g. In addition, the zinc storage mechanism of the electrode was a mono-phase reaction from Mn2+ to Mn3+, which was analyzed by ex-situ XRD and photoelectron spectroscopy at different potential states.
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  • 收稿日期:  2021-04-14
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张凯扬, 肖元化, 吴诗德, 等. 碳酸锰纳米片阵列的制备及其电化学性能研究[J]. 轻工学报, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
引用本文: 张凯扬, 肖元化, 吴诗德, 等. 碳酸锰纳米片阵列的制备及其电化学性能研究[J]. 轻工学报, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
shu
ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
Citation: ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016
shu

碳酸锰纳米片阵列的制备及其电化学性能研究

    作者简介:张凯扬(1995—),男,河北省晋州市人,郑州轻工业大学硕士研究生,主要研究方向为电化学能源材料。E-mail:744603481@qq.com
  • 1. 郑州轻工业大学 材料与化学工程学院, 河南 郑州 450001;
  • 2. 河南省表界面科学重点实验室, 河南 郑州 450001;
  • 3. 郑州大学 材料科学与工程学院, 河南 郑州 450001
  • 收稿日期: 2021-04-14
  • 录用日期: 2021-05-25
基金项目:  国家自然科学基金项目(U1904190)河南省自然科学基金项目(212300410091)

摘要: 为了提高以锰基材料做正极的水系锌离子电池的工作电压,通过溶剂热法一步实现超薄MnCO3纳米片阵列(NA)在泡沫镍基底上的生长,并采用X射线衍射(XRD)、扫描电子显微镜、透射电子显微镜、电池性能测试仪等对其结构、形貌和电化学性能进行了表征。结果表明,该MnCO3纳米片厚度约为30 nm,高度约为500 nm;将该MnCO3 NA直接应用于锌离子电池,在碱性电解液体系中,展现出1.73 V的高工作电压,在0.1 A/g的电流密度下放电比容量达到255.41 mAh/g,且在0.5 A/g的电流密度下进行270次充放电循环后,容量保持率约为83.1%。基于不同电位状态下的非原位XRD和光电子能谱XPS测试表明,该电极的储锌机制为Mn2+转变为Mn3+的单相反应。

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