CHINESE JOURNAL OF ENERGETIC MATERIALS
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含氮桥头类含能稠环的合成和性能研究
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北京理工大学材料学院

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国家自然科学基金(22075023)


Synthesis and Properties of N-bridgehead Energetic Fused Heterocycles
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Beijing Institute of Technology, Beijing 100081, China

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    摘要:

    稠环含能化合物由2个或2个以上的共用原子和1个化学键的环构成,具有较大π-π共轭结构,是一类热门的新型含能材料。含能稠环独特的多环共面结构和较大共轭体系,表现出良好的安定性,同时多个含氮杂环组成的共面结构还使得其具有较高的生成热、较大的环张力和优异的能量水平,能够在高性能和分子稳定性之间取得平衡。含氮桥头类稠环骨架以C—N键为共用键连接多个氮杂环,此类稠环大多具有良好的密度、稳定性和多个可修饰位点,是含能稠环领域中的一类新型含能骨架。本研究简要介绍了近年来报道的氮桥头型含能稠环化合物的合成、爆轰性能和稳定性研究,为该类化合物后续的研究和发展提供一定的参考。

    Abstract:

    Fused-ring energetic compounds, composed of two or more rings sharing two atoms and one chemical bond, have sizeable π-π conjugate structures and are a kind of popular new energetic materials. The polycyclic coplanar structure of energetic fused rings shows good molecular stability. Furthermore, the coplanar structure is featured with high heat of formation, significant ring tension, and high energetic performance. It can achieve a balance between high performance and molecular stability. With a C—N bond as the common building block, these nitrogen heterocycles have good density, stability, and numerous modifiable sites, which have become a new class of backbones in the field of energetic fused heterocycles. In this paper, the authors review the recent advance of synthesis, detonation properties, stability, and outlook of C—N type fused-ring energetic materials, which will be useful for the energetic community in future studies.

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钱亚东,尹平,庞思平.含氮桥头类含能稠环的合成和性能研究[J].含能材料, 2023, 31(11):1158-1172. DOI:10.11943/CJEM2022103.
QIAN Ya-dong, YIN Ping, PANG Si-ping. Synthesis and Properties of N-bridgehead Energetic Fused Heterocycles[J]. Chinese Journal of Energetic Materials, 2023, 31(11):1158-1172. DOI:10.11943/CJEM2022103.

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历史
  • 收稿日期: 2022-04-23
  • 最后修改日期: 2023-10-11
  • 录用日期: 2023-09-13
  • 在线发布日期: 2023-09-14
  • 出版日期: 2023-11-25