Formation of antimony oxide clusters by gas aggregation

Abstract

Sb_xO_y clusters are produced by using a gas aggregation technique. Antimony vapor is mixed with He/O₂ or He/N₂O and cooled in a reaction channel. After photoionisation with a KrF (248 nm) or ArF (193 nm) excimer laser the products are mass analyzed in a time of flight mass spectrometer. In the presence of N₂O no oxide clusters besides SbO⁺ can be detected, while with oxygen under similar experimental conditions dramatic changes can be observed. At low oxygen partial pressure the obtained spectra are dominated by the pure Sb ⁺_x clusters with low intensity of Sb_xO ⁺_y , whereas at high oxygen partial pressure antimony oxides following the general sequence SbO⁺(Sb₂O₃)n are most abundant. The same stable species can furthermore be produced via aggregation of vaporised solid antimony oxide (Sb₂O₃). Within these experiments another new Series of antimony oxides tentatively assigned to (Sb₂O₃) ⁺_n appeared in the mass spectra.