Research Article
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Year 2022, Volume: 25 Issue: 4, 9 - 22, 01.12.2022
https://doi.org/10.5541/ijot.1121062

Abstract

References

  • L. Lomba, B. Giner, M. C. Lopez, “Thermophysical properties of furfural compounds”, J. Chem. Eng. Data., 59(2), 329-338, 2014.
  • M. Saad Qureshi, P. Vrbka, V. Dohnal, “Thermodynamic properties of five biofuel-relevant compounds at infinite dilution in water”, Fuel., 191, 518-527, 2017.
  • M. Almasi, L. Mousavi, “Excess molar volumes of binary mixtures of aliphatic alcohols (C1–C5) with Nitromethane over the temperature range 293.15 to 308.15 K: Application of the ERAS model and cubic EOS”, J. Mol. Liq., 163, 46-52, 2011.
  • K. Uma Sivakami, S. Vaideeswaran and A. Rosevenis, “Thermodynamic properties and interaction abilities of ternary liquid mixtures at 308.15K and 318.15K”, J. Environ. Nanotechnol., 7(3),22, 2018.
  • B. Satheesh, J. K. Ega, K. Siddoju, S. Marupati, Tangeda Savitha Jyostna, “Thermodynamic properties of binary liquid mixtures of isoamyl alcohol with heterocyclic compounds at varying temperatures”, Chem. Data Coll., 37, 100812, 2022.
  • A.Sharma, M.Rani, S.Maken, “Thermodynamics of haloarenes with n-hexane at 298.15–318.15 K: Density, Ultrasonic Speed and Viscosity”, J. Mol. Liq., 321, 14366, 2021.
  • S. Karlapudi, R.L. Gardas, P. Venkateswarlu, K. Sivakumar, ”FT-IR studies on excess thermodynamic properties of binary liquid mixtures o-chlorotoluene with 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and 1-heptanol at different temperatures”, J. Chem. Thermodyn., 67, 203-209, 2013.
  • K. Uma Sivakami, S. Vaideeswaran, A. Rose Venis, K. Shenbagam, “Study on Interaction Capabilities of Ternary Liquid Mixtures by Thermodynamic Parameters at 308.15 K”, Int. J. Thermodyn., 25(2), 040-048, 2022.
  • R. Umapathi, C.Narasimha Rao, P. Naidoo, “Effect of temperature on molecular interactions betweentri(butyl) methylphosphonium methylsulfate and furfural”, J. Chem. Thermodyn., 149, 106150, 2020.
  • L. Lomba, B. Giner, I. Bandres, “physicochemical properties of green solvent derived from biomass”, Green Chem., 13, 2062-2070, 2011.
  • P. Prabhu, A. Rose Venis, “Molecular interaction of hexylene glycol with toluene, aniline, chlorobenzene, nitrobenzene, benzaldehyde and N,N-dimethylaniline at 308.15 and 318.15 K”, Phys. Chem. liq., 58, 529-544, 2020.
  • K. Narendra, B. Sudhamsa, M. Sarath Babu, “Study of molecular interactions in binary mixtures of diethyl carbonate + benzene derivatives at different temperatures”, J. Appl. Sol. Chem. Mod., 4,119-127, 2015.
  • M. S. Rahman, A.M. Saleh, F. Islam Chowdhury, “Density and viscosity for the solutions of 1-butanol with nitromethane and acetonitrile at 303.15 to 323.15 K”, J. Mol. Liq., 190, 208-214, 2014.
  • H.E. Hoga, RB. Torres, “Volumetric and viscometric properties of binary liquid mixtires of {methyl tert butyl ether(MTBE)+alcohol} at several temperatures and p=0.1 MPa: Experimental results and application of the ERAS mode”, J. Chem. Thermodyn., 43, 1104-1134, 2011.
  • P. Prabhu, U. Revathy, A. Rose Venis, “Transport properties of diethyl malonate with aniline and benzaldehyde at 308.15 and 318.15 K”, Asian J. Chem., 6, 1325-1330, 2018.
  • S. Felixa, U. Sivakami and R. Venis, “Molecular interaction in ternary liquid mixtures of 1,2-dichlorobenzene with cyclohexane and toluene at 318K”, World J. Pharm. Pharm. Sci., 5,1602, 2016.
  • U. Revathi, A. Rose Venis, “Thermodynamic parameters of a ternary liquid mixture at 308.15K and 318.15K”, J. Emerg. Technol. Innov. Res., 4, 6, 2019.
  • D. Ubagaramary, M. Enoch and Kesavaswamy, “comparative study of molecular interactions in binary liquid mixtures of 4-methyl-2-pentanonewith butan-2-one, furfuraldehyde, cyclohexanone at 308 K”, Orient. J. Chem., 32(1), 321-330, 2016.
  • U. Revathi, K. Uma Sivakami, P. Prabhu, “A study on thermodynamic properties of binary liquid mixtures of diethylmalonate with toluene and chlorobenzene at 308.15K and 318.15K”, World J. Pharm. Pharm. Sci., 6, 857, 2017.
  • D. K. Sharma, S. Agarwal, “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”, Int. J. Thermodyn., 25(2), 016-022, 2022.
  • C.V. Suryanarayana and J. Kuppusamy, “Free volume and internal pressure of liquids from ultrasonic velocity, J. Acoust. Soc. India, 4, 75, 1976.
  • P. Prabhu and A. Rose Venis, “Thermodynmic properties of binary liquid mixtures of methyl benzoate with chlorobenzene and benzaldehyde at 308.15 and 318.15K”, Asian J. Chem., 30(8), 1759-1764, 2018.
  • K. Uma Sivakami, S. Vaideeswaran and A. Rosevenis, “Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K”, J. Serb. Chem. Soc., 83(10), 1131–1142, 2018.
  • M. Zaoui-Djelloul-Daouadji, L. Bendiaf, I. Bahadur, “Volumetric and acoustic properties of binary systems (furfural or furfuryl alcohol + toluene) and (furfuryl alcohol + ethanol) at different temperatures”, Thermochim Acta., 611, 47-55. 2015.
  • L..M. Follegatti-Romero, F.H.B. Sosa, M.C. Costa, “Excess volumes and partial molar volumes of binary liquid mixtures of furfural or 2-methylfuran with alcohols at 298.15 K”, J. Chem. Thermodyn., 134, 20-30, 2019.
  • L. Bendiaf, I. Bahadur, A. Negadi, “Effects of alkyl group and temperature on the interactions between furfural and alcohol: Insight from density and sound velocity studies”, Thermochim Acta., 599, 13-22, 2015.
  • O. Redlich and A. T. Kister, “Algebraic Representation of Thermodynamic Properties and the Classification of Solutions”, Ind. Eng. Chem., 40, 345, 1948.
  • R. Rajalakshmia, S. Ravikumara, K. Sivakumarb, “Excess thermodynamic properties of intermolecular interactions in binary liquid mixtures of furfural with alkyl acetates (C1-C5) at different temperatures”, J. chem. data coll., 24, 100299, 2019.
  • S. Kumar, P. Jeevanandham, “Densities, viscosities, refractive indices and excess properties of aniline and o-anisidine with 1-alkoxyethanols at 303.15K”, J. Mol. Liq., 174, 34-41, 2012.

Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies

Year 2022, Volume: 25 Issue: 4, 9 - 22, 01.12.2022
https://doi.org/10.5541/ijot.1121062

Abstract

A study on thermodynamic properties of the liquid mixture is used in the industrial process, which often extends to solution chemistry. Density(ρ), Viscosity(η), and Ultrasonic velocity(U) were determined for binary liquid mixtures of furfural with chlorobenzene, nitromethane, diethyl malonate and 1- butanol at temperature of 308.15K and 318.15K at atmospheric pressure over the whole range of mole fractions. The calculated thermodynamic properties and some excess parameters such as Excess Volume(VE), Deviation in Isentropic Compressibility(∆KS), Deviation in Viscosity(∆η), Deviation in Intermolecular Free Length(∆LF), Deviation in Intermolecular Free Volume(∆VF), Deviation in Internal Pressure(∆π) and Deviation in Acoustic Impedance(∆Z) were calculated and applied to the Redlich-Kister type polynomial equation to determine the appropriate coefficients. The effects of composition and temperature on thermodynamic parameters have been studied in terms of molecule interaction in these liquid mixtures. Further, IR spectra of these liquid mixtures were recorded and the data were utilized to examine the mixing behavior of the components.

References

  • L. Lomba, B. Giner, M. C. Lopez, “Thermophysical properties of furfural compounds”, J. Chem. Eng. Data., 59(2), 329-338, 2014.
  • M. Saad Qureshi, P. Vrbka, V. Dohnal, “Thermodynamic properties of five biofuel-relevant compounds at infinite dilution in water”, Fuel., 191, 518-527, 2017.
  • M. Almasi, L. Mousavi, “Excess molar volumes of binary mixtures of aliphatic alcohols (C1–C5) with Nitromethane over the temperature range 293.15 to 308.15 K: Application of the ERAS model and cubic EOS”, J. Mol. Liq., 163, 46-52, 2011.
  • K. Uma Sivakami, S. Vaideeswaran and A. Rosevenis, “Thermodynamic properties and interaction abilities of ternary liquid mixtures at 308.15K and 318.15K”, J. Environ. Nanotechnol., 7(3),22, 2018.
  • B. Satheesh, J. K. Ega, K. Siddoju, S. Marupati, Tangeda Savitha Jyostna, “Thermodynamic properties of binary liquid mixtures of isoamyl alcohol with heterocyclic compounds at varying temperatures”, Chem. Data Coll., 37, 100812, 2022.
  • A.Sharma, M.Rani, S.Maken, “Thermodynamics of haloarenes with n-hexane at 298.15–318.15 K: Density, Ultrasonic Speed and Viscosity”, J. Mol. Liq., 321, 14366, 2021.
  • S. Karlapudi, R.L. Gardas, P. Venkateswarlu, K. Sivakumar, ”FT-IR studies on excess thermodynamic properties of binary liquid mixtures o-chlorotoluene with 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and 1-heptanol at different temperatures”, J. Chem. Thermodyn., 67, 203-209, 2013.
  • K. Uma Sivakami, S. Vaideeswaran, A. Rose Venis, K. Shenbagam, “Study on Interaction Capabilities of Ternary Liquid Mixtures by Thermodynamic Parameters at 308.15 K”, Int. J. Thermodyn., 25(2), 040-048, 2022.
  • R. Umapathi, C.Narasimha Rao, P. Naidoo, “Effect of temperature on molecular interactions betweentri(butyl) methylphosphonium methylsulfate and furfural”, J. Chem. Thermodyn., 149, 106150, 2020.
  • L. Lomba, B. Giner, I. Bandres, “physicochemical properties of green solvent derived from biomass”, Green Chem., 13, 2062-2070, 2011.
  • P. Prabhu, A. Rose Venis, “Molecular interaction of hexylene glycol with toluene, aniline, chlorobenzene, nitrobenzene, benzaldehyde and N,N-dimethylaniline at 308.15 and 318.15 K”, Phys. Chem. liq., 58, 529-544, 2020.
  • K. Narendra, B. Sudhamsa, M. Sarath Babu, “Study of molecular interactions in binary mixtures of diethyl carbonate + benzene derivatives at different temperatures”, J. Appl. Sol. Chem. Mod., 4,119-127, 2015.
  • M. S. Rahman, A.M. Saleh, F. Islam Chowdhury, “Density and viscosity for the solutions of 1-butanol with nitromethane and acetonitrile at 303.15 to 323.15 K”, J. Mol. Liq., 190, 208-214, 2014.
  • H.E. Hoga, RB. Torres, “Volumetric and viscometric properties of binary liquid mixtires of {methyl tert butyl ether(MTBE)+alcohol} at several temperatures and p=0.1 MPa: Experimental results and application of the ERAS mode”, J. Chem. Thermodyn., 43, 1104-1134, 2011.
  • P. Prabhu, U. Revathy, A. Rose Venis, “Transport properties of diethyl malonate with aniline and benzaldehyde at 308.15 and 318.15 K”, Asian J. Chem., 6, 1325-1330, 2018.
  • S. Felixa, U. Sivakami and R. Venis, “Molecular interaction in ternary liquid mixtures of 1,2-dichlorobenzene with cyclohexane and toluene at 318K”, World J. Pharm. Pharm. Sci., 5,1602, 2016.
  • U. Revathi, A. Rose Venis, “Thermodynamic parameters of a ternary liquid mixture at 308.15K and 318.15K”, J. Emerg. Technol. Innov. Res., 4, 6, 2019.
  • D. Ubagaramary, M. Enoch and Kesavaswamy, “comparative study of molecular interactions in binary liquid mixtures of 4-methyl-2-pentanonewith butan-2-one, furfuraldehyde, cyclohexanone at 308 K”, Orient. J. Chem., 32(1), 321-330, 2016.
  • U. Revathi, K. Uma Sivakami, P. Prabhu, “A study on thermodynamic properties of binary liquid mixtures of diethylmalonate with toluene and chlorobenzene at 308.15K and 318.15K”, World J. Pharm. Pharm. Sci., 6, 857, 2017.
  • D. K. Sharma, S. Agarwal, “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”, Int. J. Thermodyn., 25(2), 016-022, 2022.
  • C.V. Suryanarayana and J. Kuppusamy, “Free volume and internal pressure of liquids from ultrasonic velocity, J. Acoust. Soc. India, 4, 75, 1976.
  • P. Prabhu and A. Rose Venis, “Thermodynmic properties of binary liquid mixtures of methyl benzoate with chlorobenzene and benzaldehyde at 308.15 and 318.15K”, Asian J. Chem., 30(8), 1759-1764, 2018.
  • K. Uma Sivakami, S. Vaideeswaran and A. Rosevenis, “Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K”, J. Serb. Chem. Soc., 83(10), 1131–1142, 2018.
  • M. Zaoui-Djelloul-Daouadji, L. Bendiaf, I. Bahadur, “Volumetric and acoustic properties of binary systems (furfural or furfuryl alcohol + toluene) and (furfuryl alcohol + ethanol) at different temperatures”, Thermochim Acta., 611, 47-55. 2015.
  • L..M. Follegatti-Romero, F.H.B. Sosa, M.C. Costa, “Excess volumes and partial molar volumes of binary liquid mixtures of furfural or 2-methylfuran with alcohols at 298.15 K”, J. Chem. Thermodyn., 134, 20-30, 2019.
  • L. Bendiaf, I. Bahadur, A. Negadi, “Effects of alkyl group and temperature on the interactions between furfural and alcohol: Insight from density and sound velocity studies”, Thermochim Acta., 599, 13-22, 2015.
  • O. Redlich and A. T. Kister, “Algebraic Representation of Thermodynamic Properties and the Classification of Solutions”, Ind. Eng. Chem., 40, 345, 1948.
  • R. Rajalakshmia, S. Ravikumara, K. Sivakumarb, “Excess thermodynamic properties of intermolecular interactions in binary liquid mixtures of furfural with alkyl acetates (C1-C5) at different temperatures”, J. chem. data coll., 24, 100299, 2019.
  • S. Kumar, P. Jeevanandham, “Densities, viscosities, refractive indices and excess properties of aniline and o-anisidine with 1-alkoxyethanols at 303.15K”, J. Mol. Liq., 174, 34-41, 2012.
There are 29 citations in total.

Details

Primary Language English
Subjects Thermodynamics and Statistical Physics
Journal Section Research Articles
Authors

Revathi Uthirapathi

U.s. Kishnamoorthy This is me

R. V. Ambrose This is me

Publication Date December 1, 2022
Published in Issue Year 2022 Volume: 25 Issue: 4

Cite

APA Uthirapathi, R., Kishnamoorthy, U., & Ambrose, R. V. (2022). Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies. International Journal of Thermodynamics, 25(4), 9-22. https://doi.org/10.5541/ijot.1121062
AMA Uthirapathi R, Kishnamoorthy U, Ambrose RV. Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies. International Journal of Thermodynamics. December 2022;25(4):9-22. doi:10.5541/ijot.1121062
Chicago Uthirapathi, Revathi, U.s. Kishnamoorthy, and R. V. Ambrose. “Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural With Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies”. International Journal of Thermodynamics 25, no. 4 (December 2022): 9-22. https://doi.org/10.5541/ijot.1121062.
EndNote Uthirapathi R, Kishnamoorthy U, Ambrose RV (December 1, 2022) Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies. International Journal of Thermodynamics 25 4 9–22.
IEEE R. Uthirapathi, U. Kishnamoorthy, and R. V. Ambrose, “Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies”, International Journal of Thermodynamics, vol. 25, no. 4, pp. 9–22, 2022, doi: 10.5541/ijot.1121062.
ISNAD Uthirapathi, Revathi et al. “Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural With Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies”. International Journal of Thermodynamics 25/4 (December 2022), 9-22. https://doi.org/10.5541/ijot.1121062.
JAMA Uthirapathi R, Kishnamoorthy U, Ambrose RV. Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies. International Journal of Thermodynamics. 2022;25:9–22.
MLA Uthirapathi, Revathi et al. “Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural With Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies”. International Journal of Thermodynamics, vol. 25, no. 4, 2022, pp. 9-22, doi:10.5541/ijot.1121062.
Vancouver Uthirapathi R, Kishnamoorthy U, Ambrose RV. Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies. International Journal of Thermodynamics. 2022;25(4):9-22.