Published June 19, 1975
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The mechanism of diazo-coupling to indoles and the effect of steric hindrance on the rate limiting step
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Description
The first synthesis of 4-methyl-2-t-butyl and 2-methyl-4,6-di-t-butyl indole are described. Rates of diazo coupling and kinetic isotope effects at the 3-position of both these compounds together with those for 2-methyl and 2-t-butyl indole are reported for various p-substituted arenediazonium ions at 25C
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