Elaboration and Characterization of Siloxane-PMMA Hybrid Films on Tinplate Substrates

Sandra Raquel Kunst; Rogério Freitas dos Santos; Deisi Vieira; Cláudia Trindade Oliveira; Victor Hugo Vitorino Sarmento; Célia de Fraga Malfatti

doi:10.4028/www.scientific.net/MSF.727-728.1610

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HomeMaterials Science ForumMaterials Science Forum Vols. 727-728Elaboration and Characterization of Siloxane-PMMA...

Elaboration and Characterization of Siloxane-PMMA Hybrid Films on Tinplate Substrates

Abstract:

The characteristics of siloxane-PMMA hybrid films permit the obtaining of coatings with thickness of few microns without cracking. Besides, the methacrylate groups (MMA) can be easily polymerizated by UV irradiation or thermal treatments. These hybrids can also be applied in anti-corrosive coatings for metals and alloys, replacing chromates which exhibit high toxicity. In this context, the aim of this work is to study the behavior of tinplate coated with a siloxane-PMMA hybrid film by dip-coating process and cured by thermal cure process. The systems were characterized by electrochemical, morphological and physicochemical analysis. Preliminary results showed that the systems studied presented a regular and adherent siloxane-PMMA hybrid film, which increased the corrosion resistance of tinplate substrates.

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Periodical:

Materials Science Forum (Volumes 727-728)

Pages:

1610-1615

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.727-728.1610

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Online since:

August 2012

Authors:

Sandra Raquel Kunst, Rogério Freitas dos Santos, Deisi Vieira, Cláudia Trindade Oliveira, Victor Hugo Vitorino Sarmento, Célia de Fraga Malfatti

Keywords:

Corrosion, EIS, Hybrid Films, Siloxane-PMMA, Tinplate

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References

[1] D. Cangialosi, P. T. Mcgrail, G. Emmerson, A. Valenza, E. Calderaro and G. Spadaro: Nuclear Instruments & Methods in Physics Research B Vol. 185 (2001), p.262.

DOI: 10.1016/s0168-583x(01)00805-9

Google Scholar

[2] Y.T. Shieh, K.H. Liu and T.L. Lin: The Journal Supercritical Fluids Vol. 28 (2004), p.101.

Google Scholar

[3] V.H.V. Sarmento, K. Dahmouche, S.H. Pulcinelli, C.V. Santilli and A.F. Craievichi: Journal of Applied Crystallography Vol. 36 (2003), p.473.

Google Scholar

[4] J.U. Park, W.S. Kim and B.S. Bae: Journal of Materials Chemistry Vol. 13 (2003), p.738.

Google Scholar

[5] V.H.V. Sarmento: Estrutura e propriedades de materiais híbridos siloxano-PMMA preparados pelo processo sol-gel. Doutorado (Tese). Araraquara, 2005. Universidade Estadual Paulista (UNESP). (SP).

DOI: 10.1590/s0100-46702002000200002

Google Scholar

[6] Y. Castro, A. Duran, J.J. Damborenea and A. Conde. Electrochimica Acta Vol. 53 (2008), p.6008.

Google Scholar

[7] A.S. Vuk, M. Fir, R. Jese, A. Vilcnik and B. Orel: Progress Organic Coating Vol. 63 (2008), p.123.

Google Scholar

[8] A.L.K. Tan and A.M. Soutar: Thin Solid Films Vol. 516 (2008), p.5706.

Google Scholar

[9] P.H. Suegama, V.H.V. Sarmento, M.F. Montemor, A.V. Benedetti, H.G. de Melo, I.V. Aoki and C.V. Santilli: Electrochimica Acta Vol. 55 (2010), p.5100.

DOI: 10.1016/j.electacta.2010.04.002

Google Scholar

[10] J. Gatti. Boletim de tecnologia e desenvolvimento de embalagens, ISSN 0104-3781, Vol. 20, (2008).

Google Scholar