Growth of Optical Quality 4-Dimethylamino-N-Methyl-4-Stilbazolium Tosylate (DAST) Single Crystals by Novel Technique and their Characterization

Article Preview

Abstract:

Optical quality 4-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST) crystals have been grown by a novel technique. In conventional growth methods, it was difficult to control the position of spontaneous nucleation, number of nuclei, cluster formation and the nucleation period. Difficulty in the nucleation and growth positioning was effectively solved by the slope nucleation method (SNM) and sizable DAST crystal was grown by two zone growth technique (TZGT) using a seed. Furthermore removal and fixing of seed crystal was difficult in the two zone growth technique. In the present study, we could obtain optical quality bulk DAST crystals by combining SNM and TZGT. The growth rates, size are estimated with respect to temperature gradient and slope shape. The structural, functional and optical analyses were carried for the grown crystals and the results are discussed in detail.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

42-46

Citation:

Online since:

October 2012

Export:

Price:

[1] Chen Yang.Y.W, Shen.T.J, Lin.S.S, Tu.Y.K. Curr Appl Phy, 2002, 2, 349-353.

Google Scholar

[2] Zhou Yang, Shanmugam Aravazhi, Arno Schneider, Paul Seiler, Mojca Jazbinsek, Peter Gunter. Adv Func Mat, 2005, 15, 1072-1076.

Google Scholar

[3] BlancaRuiz, Mojca Jazbinsek and Peter Gunter, Cryst. Growth. Des. 8 (2008) 4173-4184.

Google Scholar

[4] Mier.U, Bosch.M, Bosshard.C, Gunter.P. Synth Mat, 2000, 109, 19.

Google Scholar

[5] Hiroshi Nanjo, Kyoji Komatsu, Toshishige M.Suzuki, Thin solid films, 464-465 (2004) 425.

Google Scholar

[6] Junko Yabuzaki, Yoshinori Takahashi, Hiroaki Adachi, Yusuke Mori and Takatomo Sasaki, Bull. Mater. Sci., 22 (1999) 11-13.

Google Scholar

[7] Jagannathan.K, Kalainathan.S. Mater Res Bull, 2007, 42, 1881-1887.

Google Scholar

[8] Haja Hameed.A.S, Rohani.S, Yu.W.C, Tai.C.Y, Lan C.W. Mater Chem Phy, 2007, 102, 60-66.

Google Scholar

[9] Haja Hameed.A.S, Yu.W.C, Chen.Z.B, Tai.C.Y, Lan C.W. J Crystal Growth, 2005, 282, 117-124.

Google Scholar

[10] R.Mohan Kumar, D.Rajan Babu, G.Ravi, R.Jayavel, J. Cryst. Growth, 250 (2003) 113.

Google Scholar

[11] S.R. Marder, J.W. Perry, W.P. Schaefer, Science, 245 (1989) 626.

Google Scholar