Study the Effect of CaCO3 Nanoparticles on the Mechanical Properties of Virgin and Waste Polypropylene

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Abstract:

This paper study the effect of the calcium carbonate (CaCO3) nanoparticleson mechanical and physical properties of virgin and waste polypropylene (pp.). 3, 5, 7 and 10 (wt. %) of CaCO3nanoparticles are mixed with each of virgin and waste pp. These mixture are blended in co-rotating twin screw extruder at 190 °Cand different screw speed (25 and 50 rpm). Different mechanical and physical technique are used to evaluate the characteristics of polymer nanocomposites ex: Tensile strength , elastic modulus , impact strength , hardness and density. The results of virgin pp./(CaCO3) showed that The tensile strength decreasing with nano(CaCO3) concentration for virgin pp. , while for waste increasing at 5% and then decreasing gradually. The impact strength increasing with nanoCaCO3concentration increasing. The hardness and density increasing with the increasing of the nanoCaCO3concentration for two type of pp.Nearly all the mechanical properties were found to increase with the processing speed of 25 rpm. In this studies, it was seen that the highest processing speed of 50 rpm does not give the material performance enhancements due to higher shear intensity which causes defect points in the structure. Also the time is smaller at high screw speeds, so there is not enough time for good dispersion to occur.

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23-33

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August 2014

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[1] Sylvie Pimbert, Ahmed Elloumi, and Alain BourmaudNanofillers improve the mechanical properties of recycled polypropylene Society of Plastics Engineers (SPE) (2010).

Google Scholar

[2] W. C. J. Zuiderduin, C. Westzaan, J. Hu´etink, and R. J. Gaymans, Toughening of polypropylene with calcium carbonate particles, Polymer 44(1), p.261–275, (2003).

DOI: 10.1016/s0032-3861(02)00769-3

Google Scholar

[3] KarimShelesh- Nezhad, Hamed Orang and Mahdi MotallebiThe Effects of Adding Nano-Calcium Carbonate Particles on the Mechanical and Shrinkage Characteristics and Molding Process Consistency of PP/nano-CaCO3Nanocomposites , University of Tabriz Iran , (2012).

Google Scholar

[4] Zhang QX, Yu ZZ, Xie XL and Mai YW. Crystallization and impact energy of polypropylene/CaCo3 nanocomposites with nonionic modifier Polymer.; 45(17): 5985-5994 , (2004).

DOI: 10.1016/j.polymer.2004.06.044

Google Scholar

[5] Guo Jiang, Han-XiongHuang, Shan-Qiang Mao dynamical rheological property and microstructure development of pp. /nano-CaCo3composite along twin-screw extruder.

Google Scholar

[6] Manias, E. Nano composites: Stiffer by Design, Nature Materials, Vol. 6, pp.9-11, (2007).

Google Scholar

[7] Daniel Eirasa, Luiz Antonio PessanMechanical properties of polypropylene‏/calcium carbonate nanocomposites , 2009.

Google Scholar

[8] JosuéAlberton, Silvia Maria Martelli and ValdirSoldiObtention and Characterization of Polypropylene, Calcium Carbonate and Poly(ethylene-co-vinyl acetate), Composites (2012).

Google Scholar

[9] Stricker, F.; Bruch, M.; Mu¨ lhaupt, R. Polymer, 38, 5347 , (1997).

Google Scholar

[10] Z. Zhang, C. Wang, Y. Meng, K. Mai, Synergistic effects of toughening of nano-CaCO3 and toughness of β-polypropylene Compos. Part A: Appl. Sci. Manuf., 43 (1), 189–197, (2012).

DOI: 10.1016/j.compositesa.2011.10.008

Google Scholar

[11] SilviuJipa• TraianZaharescu• Pitt SupapholThermal stability of isotactic polypropylene modified with calcium carbonate nanoparticles (2009).

Google Scholar

[12] Rothon RN and Hancock M. In Particulate-Filled Polymer Composites England: Longman Scientific &Technical; 1995. pp.1-42.

Google Scholar

[13] Paul DR and Robeson LM. Polymer nanotechnology: Nanocomposites, Polymer. 2008; 49(15): 3187–3204.

DOI: 10.1016/j.polymer.2008.04.017

Google Scholar

[14] M. Y. A. Fuad1, H. Hanim, R. Zarina , Z. A. Mohd. Ishak , Azman Hassan Polypropylene/calcium carbonate nanocomposites – effects of processing techniques and maleated polypropylene compatibiliser (2010).

DOI: 10.3144/expresspolymlett.2010.76

Google Scholar

[15] Luyt A S, Dramicanin M D, Antic Z , Djokovic V, Polymer Testing 28, 348 , 2009.

Google Scholar

[16] Dr. Nizar Jawad Hadi , Dr. Najim A. Saad , ZainabAbd Al RahaimStudy the Relation Between Mechanical and Thermal Behavior of PP. -Runner Waste Blend , Journal of International Academic Research for Multidisciplinary, vol. 1 , issue 12 , 2014.

Google Scholar