Author Contributions
Conceptualization, N.M.A.; methodology, L.D.B. and N.M.A.; formal analysis, L.D.B.; investigation, L.D.B. and N.M.A.; resources, N.D.B.; writing—original draft preparation, L.D.B.; writing—review and editing, N.D.B. and N.M.A.; visualization, L.D.B.; supervision, N.M.A. and N.D.B.; funding acquisition, N.M.A. and N.D.B. All authors have read and agreed to the published version of the manuscript.
Figure 1.
Curing and exposure conditions.
Figure 1.
Curing and exposure conditions.
Figure 2.
Schematic overview of the procedure (beam casting, samples cutting, immersion, and drying in oven) for water absorption under vacuum.
Figure 2.
Schematic overview of the procedure (beam casting, samples cutting, immersion, and drying in oven) for water absorption under vacuum.
Figure 3.
Measurements of carbonation depth on concrete samples.
Figure 3.
Measurements of carbonation depth on concrete samples.
Figure 4.
Schematic overview of the preconditioning (cutting, side-sealing, immersion, and drying) and the capillary imbibition test.
Figure 4.
Schematic overview of the preconditioning (cutting, side-sealing, immersion, and drying) and the capillary imbibition test.
Figure 5.
Moisture content measured on site (n = 16).
Figure 5.
Moisture content measured on site (n = 16).
Figure 6.
Resistivity measured on site (n = 8).
Figure 6.
Resistivity measured on site (n = 8).
Figure 7.
Water absorption (WA), capillary porosity (CP), and open porosity (OP) of (a) PC4 after 2 months (n = 2), (b) PC6 after 2 months (n = 2), (c) PC4 after 6 months (n = 5), and (d) PC6 after 6 months (n = 5). The standard deviation is represented by error bars.
Figure 7.
Water absorption (WA), capillary porosity (CP), and open porosity (OP) of (a) PC4 after 2 months (n = 2), (b) PC6 after 2 months (n = 2), (c) PC4 after 6 months (n = 5), and (d) PC6 after 6 months (n = 5). The standard deviation is represented by error bars.
Figure 8.
Compressive strength of PC4 and PC6 (a) after 2 months and (b) after 6 months of exposure (n = 3).
Figure 8.
Compressive strength of PC4 and PC6 (a) after 2 months and (b) after 6 months of exposure (n = 3).
Figure 9.
Carbonation depth of PC4 and PC6 (a) after 2 months and (b) after 6 months of exposure.
Figure 9.
Carbonation depth of PC4 and PC6 (a) after 2 months and (b) after 6 months of exposure.
Figure 10.
Chloride concentration as a function of depth for PC4 and PC6 sea exposed after 2 months of exposure.
Figure 10.
Chloride concentration as a function of depth for PC4 and PC6 sea exposed after 2 months of exposure.
Figure 11.
Chloride concentration as a function of depth for PC4 and PC6 sea sheltered after 6 months of exposure.
Figure 11.
Chloride concentration as a function of depth for PC4 and PC6 sea sheltered after 6 months of exposure.
Figure 12.
3D chloride ingress.
Figure 12.
3D chloride ingress.
Figure 13.
Chloride concentration as a function of depth after capillary imbibition with a 3.5% NaCl solution of PC4 and PC6.
Figure 13.
Chloride concentration as a function of depth after capillary imbibition with a 3.5% NaCl solution of PC4 and PC6.
Figure 14.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with water as the imbibing liquid.
Figure 14.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with water as the imbibing liquid.
Figure 15.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with a NaCl solution as the imbibing liquid.
Figure 15.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with a NaCl solution as the imbibing liquid.
Figure 16.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with a Na2SO4 solution as the imbibing liquid.
Figure 16.
Capillary imbibition rate (CIR) of samples cured in different exposure conditions with a Na2SO4 solution as the imbibing liquid.
Table 1.
Mix composition PC4 and PC6.
Table 1.
Mix composition PC4 and PC6.
| PC4 | PC6 |
---|
Sand 0/4 [kg/m3] | 673.8 | 616.4 |
Gravel 2/8 [kg/m3] | 790.8 | 723.4 |
Gravel 8/16 [kg/m3] | 561.3 | 513.5 |
CEM I 52.5 N [kg/m3] | 325.9 | 325.9 |
Water [kg/m3] | 130.4 | 195.5 |
Superplasticizer [L/m3] | 2.9 | - |
Table 2.
Fresh properties concrete.
Table 2.
Fresh properties concrete.
| PC4 | PC6 |
---|
Slump [mm] | 50 | 165 |
Air content [%] | 1.7 | 1.7 |
Density [kg/m3] | 2387.5 | 2331.25 |
Table 3.
Grinding patterns.
Table 3.
Grinding patterns.
Condition | Number of Layers (n) | Thickness Layers |
---|
Sea exposed PC4 2 months | 12 | 1 mm |
Sea exposed PC6 2 months | 10 | 3 mm |
Sea exposed PC4 6 months | 10 | 3 mm |
Sea exposed PC6 6 months | 10 | 3 mm |
Sea sheltered PC4 6 months | 6 | 4 mm |
Sea sheltered PC6 6 months | 6 | 4 mm |
Capillary imbibition PC4 2 months | 6 | 4 mm |
Capillary imbibition PC6 2 months | 6 | 4 mm |
Table 4.
Torrent permeability measured on site (a) after 2 months of exposure (b) after 6 months of exposure (n = 16).
Table 4.
Torrent permeability measured on site (a) after 2 months of exposure (b) after 6 months of exposure (n = 16).
(a) | (b) |
---|
Torrent Permeability [10−6 m2] | Torrent Permeability [10−6 m2] |
---|
| PC4 | PC6 | | PC4 | PC6 |
---|
Ideal | 0.13 ± 0.03 | 25.43 ± 12.76 | Ideal | 0.15 ± 0.04 | 23.58 ± 10.78 |
City exposed | 0.26 ± 0.05 | 0.48 ± 0.21 | City exposed | 0.19 ± 0.03 | 0.26 ± 0.09 |
City sheltered | 0.15 ± 0.03 | 22.61 ± 11.45 | City sheltered | 0.21 ± 0.08 | 61.62 ± 14.73 |
Sea exposed | 0.28 ± 0.06 | 0.13 ± 0.03 | Sea exposed | 0.78 ± 0.97 | 0.16 ± 0.04 |
| | | Sea sheltered | 0.11 ± 0.02 | 13.41 ± 2.29 |
Table 5.
ANOVA test for equality of means between different exposure conditions: p-value and average coefficient of variation (COV) (in %).
Table 5.
ANOVA test for equality of means between different exposure conditions: p-value and average coefficient of variation (COV) (in %).
Situation | p | Mean COV (%) |
---|
W-4-2 | 0.05 | 5.20 |
C-4-2 | 0.19 | 5.80 |
S-4-2 | 0.15 | 13.15 |
W-6-2 | 0.11 | 10.49 |
C-6-2 | 0.074 | 13.10 |
S-6-2 | 0.47 | 21.27 |
W-4-6 | 0.005 | 4.45 |
C-4-6 | 0.346 | 7.20 |
S-4-6 | 0.017 | 7.29 |
W-6-6 | 0.45 | 15.14 |
C-6-6 | 0.55 | 12.22 |
S-6-6 | 0.42 | 19.83 |
Table 6.
ANOVA test for equality of means between different imbibition liquids: mean value, p-value (in %) and COV (in %).
Table 6.
ANOVA test for equality of means between different imbibition liquids: mean value, p-value (in %) and COV (in %).
| | µ (mg/mm2) | COV (%) | p |
---|
PC4 2 months | Water | 0.161 | 7.59 | 0.10% |
| NaCl | 0.133 | 6.36 | |
| Na2SO4 | 0.076 | 6.54 | |
PC6 2 months | Water | 1.186 | 9.55 | 24.30% |
| NaCl | 1.523 | 12.99 | |
| Na2SO4 | 1.436 | 28.67 | |
PC4 6 months | Water | 0.171 | 5.17 | 0.10% |
| NaCl | 0.152 | 6.86 | |
| Na2SO4 | 0.117 | 6.73 | |
PC6 6 months | Water | 1.253 | 16.04 | 74.20% |
| NaCl | 1.371 | 13.99 | |
| Na2SO4 | 1.218 | 26.91 | |