Skip to main content
Log in

Application of nanocatalytic systems for deep processing of coal and heavy petroleum feedstock

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

The specific features of the catalysis of deep processing (hydrogenation and gasification) of coal and hydroconversion of heavy petroleum feedstock are considered. It has been shown that it is reasonable to use new catalyst forms and catalyst introduction methods for the processing of these raw materials in view of their specific composition and properties (large size of molecules, thermal instability, and the presence of inorganic compounds in the feedstock). In particular, a dispersion of nanosized spherical particles of MoS2 in a liquid hydrocarbon medium is an effective catalyst for the coal hydrogenation and heavy-oil hydrocon-version processes. Gaseous alkali metal hydroxides have been proposed for the gasification of solid fuels. The mechanisms of the formation of catalyst systems and some of their properties are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Dris, H., Muller, F., Wilburn, P., et al., Neftegaz. Tekhnol., 2005, no. 6, p. 77.

  2. Shabron, G.F., Neftegaz. Tekhnol., 2005, no. 10, p. 74.

  3. Rapoport, I.B., Iskusstvennoe zhidkoe toplivo (Synthetic Liquid Fuel), Moscow: Izd. Neftyanoi i Gornotoplivnoi Literatury, 1955.

    Google Scholar 

  4. Krichko, A.A., Lebedev, V.V., and Farberov, I.L., Netoplivnoe ispol’zovanie uglei (Nofuel use of Coals), Moscow: Nedra, 1978.

    Google Scholar 

  5. Krasnobaeva, N.V., Cand. Sci. (Eng.) Dissertation, Moscow: Inst. for Fossil Fuels, 1982.

  6. Zekel’, L.A., Krasnobaeva, N.V., Pchelina, D.P., et al., Khim. Tverd. Topl. (Moscow), 1983, no. 4, p. 75.

  7. Zekel’, L.A., Krasnobaeva, N.V., and Shpirt, M.Ya., Tr. IGI, 1986, p. 49.

  8. Zekel’, L.A., Krasnobaeva, N.V., Samuilova, L.N., and Shpirt, M.Ya., Khim. Tverd. Topl. (Moscow), 1982, no. 4, p. 68.

  9. Shpirt, M.Ya., Zekel’, L.A., and Krasnobaeva, N.V., Tr. IGI, 1984, p. 39.

  10. Zekel’, L.A., Krichko, A.A., Krasnobaeva, N.V., and Shpirt, M.Ya., USSR Inventor’s Certificate no. 1559636; Byull. Izobret., 1989, no. 11.

  11. Krichko, A.A., Makar’ev, S.S., Khadzhiev, S.N., et al., USSR Inventor’s Certificate no. 1 777 346.

  12. SU Patent No. 1 822 571.

  13. Maloletnev, A.S., Krichko, A.A., and Garkusha, A.A., Poluchenie sinteticheskogo zhidkogo topliva gidrogenizatsiei uglei (Manufacture of Synthetic Fuel by Coal Hydrogenation), Moscow: Nedra, 1992.

    Google Scholar 

  14. Zekel’, L.A., Khim. Tverd. Topl. (Moscow), 2001, no. 5, p. 49.

  15. Krichko, A.A., Shpirt, M.Ya., Glazunov, M.L., et al., Khim. Tverd. Topl. (Moscow), 1988, no. 5, p. 62.

  16. Krichko, A.A., Makar’ev, S.S., Khadzhiev, S.N., et al., 7-i Neftekhimicheskii kongress sots. stran (The 7th Petrochemical Congress of Socialist Countries), Moscow, 1990, p. 15.

  17. Hadjiew, S.N., Krichko, A.A., and Suvorov, Ju.P., 15th World Petroleum Congress, Beijing, 1997, poster 14, topic 9.

  18. RF Patent no. 2 219220; Byull. Izobret., No. 35 (2003).

  19. Krichko, A.A., Ozerenko, A.A., Frosin, S.B., et al., Katal. Neftepererab. Prom-sti, 2007, no. 3, p. 23.

  20. Dmitrievskii, A.N., Rezunenko, V.I., Gafarov, N.A., et al., in Materialy nauchno-prakticheskoi konf. “Neftepererabotka i neftekhimiya” (Proceedings of Theoretical and Practical Conference on Pertoleum Refing and Petroleum Chemistry), Ufa, 2003, p. 375.

  21. RF Patent no. 2 241 022 (2003).

  22. Zekel’, L.A., Krasnobaeva, N.V., Shpirt, M.Ya., et al., Sovrem. Problemy Khim. Khim. Prom-sti, 1982, no. 4 (125), p. 61.

  23. Chernenkov, I.I. and Zakhar’yants, E.O., Tr. IGI, 1988, p. 5.

  24. Shpirt, M.Ya., Zekel’, L.A., and Golovin, G.S., Khim. Tverd. Topl. (Moscow), 2000, no. 4, p. 56.

  25. Zekel’, L.A. and Krasnobaeva, N.V., Khim. Tverd. Topl. (Moscow), 2003, no. 6, p. 60.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. A. Zekel.

Additional information

Original Russian Text © L.A. Zekel, N.V. Krasnobayeva, Kh.M. Kadiev, S.N. Khadzhiev, M.Ya. Shpirt, 2010, published in Khimiya Tverdogo Topliva, 2010, No. 6, pp. 22–30.

About this article

Cite this article

Zekel, L.A., Krasnobayeva, N.V., Kadiev, K.M. et al. Application of nanocatalytic systems for deep processing of coal and heavy petroleum feedstock. Solid Fuel Chem. 44, 387–395 (2010). https://doi.org/10.3103/S0361521910060042

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0361521910060042

Keywords

Navigation