From 4T to 2T solution processed silicon/perovskite tandems solar cells
César Omar Ramírez Quiroz a, Pierre J. Verlinden b, Xueling Zhang b, Martin A. Green c, Anita Ho-Baillie c, Loïc M. Roch d, Michael Salvador e, Steve Albrecht f, Tobias Unruh g, Andreas Hirsch h, Alán Aspuru-Guzik d, Christoph J. Brabec a, George D. Spyropoulos a, Bernd Rech f
a Friedrich-Alexander-Universität Erlangen-Nürnberg, Institute of Materials for Electronics and Energy Technology (i-MEET), Department of Materials Science and Engineering, 91058 Erlangen, Alemania, Erlangen, Germany
b Trina Solar, No.2 Trina Road, Trina PV Industrial Park, Xinbei District, Changzhou, Jiangsu 213031, China
c University of New South Wales, Australian Centre for Advanced Photovoltaics, School of Photovoltaic and Renewable Engineering, Sydney 2052, Sydney, Australia
d Department of Chemistry and Chemical Biology, Harvard University - USA., Cambridge, United States
e King Abdullah University of Science and Technology (KAUST) - Saudi Arabia, 4700 King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia
f Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Young Investigator Group Perovskite Tandem Solar Cells, Berlin, Germany
g Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Erlangen, Germany
h Friedrich-Alexander University Erlangen-Nürnberg. Department of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Erlangen, Alemania, Erlangen, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Oral, César Omar Ramírez Quiroz, presentation 093
DOI: https://doi.org/10.29363/nanoge.hopv.2018.093
Publication date: 21st February 2018

Reducing Fresnel reflection losses with hole transporting layer that function as optical couplers in 4T tandems; Based on the understanding of Fresnel reflection in a full device stack, we demonstrate that parasitical energy losses can be minimized using wide-band gap semiconductors with beneficial refractive index as selective contacts. Furtheremore, and as opposed to previous reports, were the improvement of efficiency is done through energy-intensive deposition of both top and bottom electrodes, here, we demonstrate that solution-processed silver nanowires, a model composite for percolation- based electrodes, allows controlling the overall optical and electrical losses with outstanding precision by a simple spray coating process. As a result we present a solution-processed semitransparent perovskite-based solar cell with 17.1% efficiency showing 84.8% overall optical transmission averaged in the relevant range 800 nm to 1100 nm. Our devices allowed the elaboration of 4-terminal silicon/perovskite tandem devices with 26.7% efficiency.

Laminated 2T tandems, an alternative approach: We explore a multipurpose interconnection layer for the fabrication of monolithic perovskite/silicon tandem solar cells with high power conversion efficiency. The interconnection of independently processed silicon and perovskite sub-cells could be a simple add-on lamination step, alleviating the common fabrication complexity of perovskite/silicon tandem devices. We envision that this lamination concept can be extrapolated for the pairing of multiple photovoltaic technologies, creating a universal platform that facilitates mass production of tandem devices with high power conversion efficiency.

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