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The research in graphdiyne (GDY) has experienced a rapid growth period in the first decade after its birth. As a new two-dimensional (2D) atomic crystal, GDY has unique structures consisting of both sp and sp2 hybridized carbon atoms, and exhibits many unprecedented intrinsic properties to scientists. Due to the inherent characteristics of GDY, some new phenomena and properties have been discovered in a wide range of research fields. GDY has made substantial breakthroughs in fundamental and applied science, formed innovative scientific concepts, and made great achievements. In these fields, the electrochemical energy storage and conversion are two important and impressive fields for the fundamental applicative investigations. This review focuses on the utilization of GDY as advanced electrochemical interface for the electrochemical energy storage and conversion. It begins with an introduction of the superiorities and inherent compatibilities of GDY as the electrochemical interface. Then, GDY's recent achievements in electrochemical storage and conversion are commented, from which we can appreciate the inherent advantages of GDY as a crucial material for alternating and innovating the electrochemical interface. Finally, new insights into the challenges and further perspectives on the GDY interface for the electrochemical energy storage and conversion are discussed, aiming at prompting in-depth investigation and their performance in practical applications.


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Advanced electrochemical energy storage and conversion on graphdiyne interface

Show Author's information Xiaoya Gao1,2Jiaofu Li3Zicheng Zuo1( )
Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Department of Chemistry, University of Chinese Academy of Sciences, Beijing 100049, China
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

Abstract

The research in graphdiyne (GDY) has experienced a rapid growth period in the first decade after its birth. As a new two-dimensional (2D) atomic crystal, GDY has unique structures consisting of both sp and sp2 hybridized carbon atoms, and exhibits many unprecedented intrinsic properties to scientists. Due to the inherent characteristics of GDY, some new phenomena and properties have been discovered in a wide range of research fields. GDY has made substantial breakthroughs in fundamental and applied science, formed innovative scientific concepts, and made great achievements. In these fields, the electrochemical energy storage and conversion are two important and impressive fields for the fundamental applicative investigations. This review focuses on the utilization of GDY as advanced electrochemical interface for the electrochemical energy storage and conversion. It begins with an introduction of the superiorities and inherent compatibilities of GDY as the electrochemical interface. Then, GDY's recent achievements in electrochemical storage and conversion are commented, from which we can appreciate the inherent advantages of GDY as a crucial material for alternating and innovating the electrochemical interface. Finally, new insights into the challenges and further perspectives on the GDY interface for the electrochemical energy storage and conversion are discussed, aiming at prompting in-depth investigation and their performance in practical applications.

Keywords: two-dimensional (2D) material, Graphdiyne, battery, electrochemical catalysis, interfacial protection, interfacial engineering

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Publication history

Received: 21 July 2022
Revised: 05 October 2022
Accepted: 07 October 2022
Published: 25 October 2022
Issue date: December 2022

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© The Author(s) 2022. Published by Tsinghua University Press.

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 51802311, U1932211, 21790050, 21790051), the National Key Research and Development Project of China (No. 2018YFA0703501), the Key Program of the Chinese Academy of Sciences (No. QYZDY-SSW-SLH015), and the Foundation of the Youth Innovation Promotion Association of Chinese Academy of Sciences (No. 2019032).

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