Research Article
BibTex RIS Cite

Küspe (Nigella sativa) Kullanılarak Sulu Çözeltilerden Adsorpsiyon ile Boyar Madde Giderimi

Year 2018, Volume: 33 Issue: 4, 147 - 154, 31.12.2018
https://doi.org/10.21605/cukurovaummfd.525153

Abstract

Dünya’da su kirliliği en önemli problemlerden birisidir. Bu amaçla atık suların çevreye deşarj edilmeden önce arıtılması gerekmektedir. Adsorpsiyonun sulu ortamda kirleticilerin arıtımı için iyi bir proses olduğu bilinmektedir. Bu çalışmada sulu çözeltilerden Malachite green’in (MG) küspe ile (Nigella sativa) giderimi araştırılmıştır. MG’nin adsorpsiyonu  üzerine pH, başlangıç boya konsantrasyonu ve zamanın etkisi kesikli bir sistemde çalışılmıştır. Elde edilen veriler Langmuir ve Freundlich İzoterm Modellerine uygulanmıştır. Langmuir izoterm modelinin (R2=0,9996) küspe (Nigella sativa) kullanılarak MG’nin adsorpsiyonla gideriminde en iyi uyum sağladığı görülmüştür. Ayrıca adsorpsiyon kinetiği de hesaplanmıştır. Küspe yüzey alanı ile boya arasındaki etkileşim Taramalı elektron mikroskobu ile belirlenmiştir. Çalışma, Nigella sativa küspesinin MG’nin gideriminde maliyetsiz ve güçlü bir adsorban olduğunu vurgulamıştır. 

References

  • 1. Hong, G.H., Yi Kai Wang, Y.K., 2017. Synthesis of Low-cost Adsorbent from Rice Bran for the Removal of Reactive Dye Based on the Response Surface Methodology. Applied Surface Science, 423, 800–809.
  • 2. Ooi, J., Lee, L.Y., Hiew, B.Y.Z., ThangalazhyGopakumar, S., Lim, S.S., Gan, S., 2017. Assessment of Fish Scales Waste as a Low Cost and Eco-friendly Adsorbent for Removal of an Azo Dye: Equilibrium, Kinetic and Thermodynamic Studies. Bioresource Technology, 245, 656–664.
  • 3. Hamid, S.A., Shahadat, M., Ismail, S., 2017. Development of Cost Effective Bentonite Adsorbent Coating for the Removal of Organic Pollutant. Applied Clay Science, 149, 79-86.
  • 4. Ramesh, T.N., Kirana, D.V., Ashwini, A., Manasa, T.R., 2017. Calcium Hydroxide as Low Cost Adsorbent for the; Effective Removal of Indigo Carmine Dye in Water. Journal of Saudi Chemical Society, 21, 165-171.
  • 5. Somasekhara Reddy, M.C., Nirmala, V., 2017. Bengal Gram Seed Husk as an Adsorbent for the Removal of Dye From Aqueous Solutions- Batch Studies. Arabian Journal of Chemistry, 10, 2554–2566.
  • 6. Banerjee, S., Chattopadhyaya, M.C., 2017. Adsorption Characteristics for the Removal of a Toxic Dye, Tartrazine from Aqueous Solutions by a Low Cost Agricultural byproduct. Arabian Journal of Chemistry, 10(2017), 1629–1638.
  • 7. Lina, Q., Wang, K., Gaoa, M., Bai, Y., Chen, L., Ma, H., 2017. Effectively Removal of Cationic and Anionic Dyes by pH-sensitive Amphoteric Adsorbent Derived from Agricultural Waste-wheat Straw. Journal of the Taiwan Institute of Chemical Engineers, 76, 65–72.
  • 8. Agarwal, S., Gupta, V. K., Ghasemi, M., Azimi-Amin, J., 2017. Peganum Harmala-L Seeds Adsorbent for the Rapid Removal of Noxious Brilliant Green Dyes from Aqueous Phase. Journal of Molecular Liquids, 231, 296-305.
  • 9. Pettignanoa, A., Tanchouxa, N., Cacciaguerra, T., Vincent, T., Bernardi, L., Guibal, E., Quignard, F., 2017. Sodium and Acidic Alginate Foams with Hierarchical Porosity: Preparation, Characterization and Efficiency as a Dye Adsorbent. Carbohydrate Polymers, 178, 78–85.
  • 10. Ezechi, E.H., Kutty, S.R.B.M., Malakahmad, A., Isa, M.H., 2017. Characterization and Optimization of Effluent Dye Removal Using a New Low Cost Adsorbent: Equilibrium, Kinetics and Thermodynamic Study. Process Safety and Environmental Protection, 98, 16-32.
  • 11. Intra deo mall, Srivastage, V.C., Agarwal, N., K., Mishara, I.V., 2005. Adsorptive Removal of Malachite Green Dye from Aqueous Solution by Bagasse Fly Ash and Activated Carbon Kinetic Study and Equilibrium Isotherm Analyses. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 264, 17-28.
  • 12. Kumar, K.V., Sivanesan, S., Ramamurthi, V., 2005. Adsorption of Malachite Green Onto Pithophora sp., a Fresh Water Algae: Equilibrium and Kinetic Modelling. Process Biochemistry, 40, 2865-2872.
  • 13. Kılıç, C., Arabacı, O., 2016. Çörek Otu (Nigella sativa L.)’nda Farklı Ekim Zamanı ve Tohumluk Miktarının Verim ve Kaliteye Etkisi, Journal of Adnan Menderes University Agricultural Faculty, 13(2), 49-56.
  • 14. https://en.wikipedia.org/wiki/Methylene_blue. Erişim Tarihi: 02.06.2015.
  • 15. Baek, M.H., Ijagbemi, C.O., Se-Jin, O., Kim, D.S., 2010. Removal of Malachite Green from Aqueous Solution Using Degreased Coffee Bean, Journal of Hazardous Materials, 176, 820-828.
  • 16. Ertas, M., Acemioglu, B., Alma, M.H., Usta, M., 2010. Removal of Methylene Blue from Aqueous Solution Using Cotton Stalk, Cotton Waste and Cotton Dust, Journal of Hazardous Materials, 183, 421-427.
  • 17. Hameed, B.H., 2009. Removal of Cationic Dye from Aqueous Solution Using Jackfruit Peel as Nnon-conventional Low-cost adsorbent, Journal of Hazardous Material, 162(1), 344-350.
  • 18. Abdi, J., Vossoughi, M., Mahmoodi, N.M., Alemzadeh, I., 2017. Synthesis of MetalOrganic Framework Hybrid Nanocomposites Based on GO and CNT with High Adsorption Capacity for Dye Removal. Chemical Engineering Journal 326, 1145–1158.
  • 19. Ho, Y.S., 2006. Isotherms for the Sorption of Lead onto Peat: Comparison of Linear and Non-Linear Methods. Polish Journal of Environmental Studies, 15(1), 81-86.
  • 20. Acemioğlu, B., 2005. Batch Kinetic Study of Sorption of Methylene Blue by Perlit, Chemical Engineering Journal, 106, 73-81.
  • 21. Hameed, B.H., El-Khaiary, M.I., 2008. Removal of Basic Dye from Aqueous Medium Using a Novel Agricultural Waste Material: Pumpkin Seed Hull, Journal of Hazardous Material, 155, 601-609.
  • 22. Sartape, A.S., Mandhare, A.M., Jadhav V.V., Raut, P.D., Anuse, M.A., Kolekar, S.S., 2017. Removal of Malachite Green Dye from Aqueous Solution With Adsorption Technique Using Limonia Acidissima (Wood Apple) Shell as Low Cost Adsorbent. Arabian Journal of Chemistry, 10, 3229–3238.
  • 23. Arellano-Cárdenas, S., López-Cortez, S., Cornejo-Mazón, M., Mares-Gutiérrez, J.C., 2013. Study of Malachite Green Adsorption by Organically Modified Clay Using a Batch Method. Applied Surface Science, 280, 74–78.
  • 24. Zhang, J., Li, Y., Zhang, C., Jing, Y., 2008. Adsorption of Malachite Green from Aqueous Solution Onto Carbon Prepared from Arundo Donax Root. Journal of Hazardous Materials, 150, 774-782.
  • 25. Ozdes, D., Gundogdu, A., Duran, C., Senturk, H.B., 2010. Evaluation of Adsorption Characteristics of Malachite Green onto Almond Shell (Prunus dulcis), Separation Science and Technology, 45, 2076–2085.
  • 26. Coşkun, R., Savcı, S., Delibaş, A., 2018. Adsorption Properties of Activated Almond Shells for Methylene Blue (MB), Environmental Research & Technology, 1(2), 31-38.
  • 27. Bulut, Y., Aydin, H., 2006. A Kinetics and Thermodynamics Study of Methylene Blue Adsorption on Wheat Shells, Desalination, 194 (1-3), 259-267.
  • 28. Zhang J., Li, Y., Zhang C., Jing Y., 2008. Adsorption of Malachite Green from Aqueous Solution Onto Carbon Prepared from Arunda Donax Root. Journal of Hazardous Material, 150, 774-782.

Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa)

Year 2018, Volume: 33 Issue: 4, 147 - 154, 31.12.2018
https://doi.org/10.21605/cukurovaummfd.525153

Abstract

In the world, water pollution is one of the most important problems. For this purpose, it is necessary that waste water must be treatment before discharge to the environment. It is known that adsorption is the well process for treatment of pollutant in an aqueous environment. In this study, the removal of Malachite green (MG) from aqueous solution using pulp (Nigella sativa) was investigated. Effects of pH, initial dye concentration and time on adsorption of MG were studied in a batch system. The available data were applied to Langmuir and Freundlich isotherms. The Langmuir model is the best fitted (R2=0.999) for the adsorption of MG from using pulp (Nigella sativa). Moreover, kinetic of adsorption were also calculated. The interaction between the pulp surface area and the dye was determined by scanning electron microscopy. The study emphasized that the Nigella sativa pulp is a no-cost and powerful adsorbent for the removal of MG. 

References

  • 1. Hong, G.H., Yi Kai Wang, Y.K., 2017. Synthesis of Low-cost Adsorbent from Rice Bran for the Removal of Reactive Dye Based on the Response Surface Methodology. Applied Surface Science, 423, 800–809.
  • 2. Ooi, J., Lee, L.Y., Hiew, B.Y.Z., ThangalazhyGopakumar, S., Lim, S.S., Gan, S., 2017. Assessment of Fish Scales Waste as a Low Cost and Eco-friendly Adsorbent for Removal of an Azo Dye: Equilibrium, Kinetic and Thermodynamic Studies. Bioresource Technology, 245, 656–664.
  • 3. Hamid, S.A., Shahadat, M., Ismail, S., 2017. Development of Cost Effective Bentonite Adsorbent Coating for the Removal of Organic Pollutant. Applied Clay Science, 149, 79-86.
  • 4. Ramesh, T.N., Kirana, D.V., Ashwini, A., Manasa, T.R., 2017. Calcium Hydroxide as Low Cost Adsorbent for the; Effective Removal of Indigo Carmine Dye in Water. Journal of Saudi Chemical Society, 21, 165-171.
  • 5. Somasekhara Reddy, M.C., Nirmala, V., 2017. Bengal Gram Seed Husk as an Adsorbent for the Removal of Dye From Aqueous Solutions- Batch Studies. Arabian Journal of Chemistry, 10, 2554–2566.
  • 6. Banerjee, S., Chattopadhyaya, M.C., 2017. Adsorption Characteristics for the Removal of a Toxic Dye, Tartrazine from Aqueous Solutions by a Low Cost Agricultural byproduct. Arabian Journal of Chemistry, 10(2017), 1629–1638.
  • 7. Lina, Q., Wang, K., Gaoa, M., Bai, Y., Chen, L., Ma, H., 2017. Effectively Removal of Cationic and Anionic Dyes by pH-sensitive Amphoteric Adsorbent Derived from Agricultural Waste-wheat Straw. Journal of the Taiwan Institute of Chemical Engineers, 76, 65–72.
  • 8. Agarwal, S., Gupta, V. K., Ghasemi, M., Azimi-Amin, J., 2017. Peganum Harmala-L Seeds Adsorbent for the Rapid Removal of Noxious Brilliant Green Dyes from Aqueous Phase. Journal of Molecular Liquids, 231, 296-305.
  • 9. Pettignanoa, A., Tanchouxa, N., Cacciaguerra, T., Vincent, T., Bernardi, L., Guibal, E., Quignard, F., 2017. Sodium and Acidic Alginate Foams with Hierarchical Porosity: Preparation, Characterization and Efficiency as a Dye Adsorbent. Carbohydrate Polymers, 178, 78–85.
  • 10. Ezechi, E.H., Kutty, S.R.B.M., Malakahmad, A., Isa, M.H., 2017. Characterization and Optimization of Effluent Dye Removal Using a New Low Cost Adsorbent: Equilibrium, Kinetics and Thermodynamic Study. Process Safety and Environmental Protection, 98, 16-32.
  • 11. Intra deo mall, Srivastage, V.C., Agarwal, N., K., Mishara, I.V., 2005. Adsorptive Removal of Malachite Green Dye from Aqueous Solution by Bagasse Fly Ash and Activated Carbon Kinetic Study and Equilibrium Isotherm Analyses. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 264, 17-28.
  • 12. Kumar, K.V., Sivanesan, S., Ramamurthi, V., 2005. Adsorption of Malachite Green Onto Pithophora sp., a Fresh Water Algae: Equilibrium and Kinetic Modelling. Process Biochemistry, 40, 2865-2872.
  • 13. Kılıç, C., Arabacı, O., 2016. Çörek Otu (Nigella sativa L.)’nda Farklı Ekim Zamanı ve Tohumluk Miktarının Verim ve Kaliteye Etkisi, Journal of Adnan Menderes University Agricultural Faculty, 13(2), 49-56.
  • 14. https://en.wikipedia.org/wiki/Methylene_blue. Erişim Tarihi: 02.06.2015.
  • 15. Baek, M.H., Ijagbemi, C.O., Se-Jin, O., Kim, D.S., 2010. Removal of Malachite Green from Aqueous Solution Using Degreased Coffee Bean, Journal of Hazardous Materials, 176, 820-828.
  • 16. Ertas, M., Acemioglu, B., Alma, M.H., Usta, M., 2010. Removal of Methylene Blue from Aqueous Solution Using Cotton Stalk, Cotton Waste and Cotton Dust, Journal of Hazardous Materials, 183, 421-427.
  • 17. Hameed, B.H., 2009. Removal of Cationic Dye from Aqueous Solution Using Jackfruit Peel as Nnon-conventional Low-cost adsorbent, Journal of Hazardous Material, 162(1), 344-350.
  • 18. Abdi, J., Vossoughi, M., Mahmoodi, N.M., Alemzadeh, I., 2017. Synthesis of MetalOrganic Framework Hybrid Nanocomposites Based on GO and CNT with High Adsorption Capacity for Dye Removal. Chemical Engineering Journal 326, 1145–1158.
  • 19. Ho, Y.S., 2006. Isotherms for the Sorption of Lead onto Peat: Comparison of Linear and Non-Linear Methods. Polish Journal of Environmental Studies, 15(1), 81-86.
  • 20. Acemioğlu, B., 2005. Batch Kinetic Study of Sorption of Methylene Blue by Perlit, Chemical Engineering Journal, 106, 73-81.
  • 21. Hameed, B.H., El-Khaiary, M.I., 2008. Removal of Basic Dye from Aqueous Medium Using a Novel Agricultural Waste Material: Pumpkin Seed Hull, Journal of Hazardous Material, 155, 601-609.
  • 22. Sartape, A.S., Mandhare, A.M., Jadhav V.V., Raut, P.D., Anuse, M.A., Kolekar, S.S., 2017. Removal of Malachite Green Dye from Aqueous Solution With Adsorption Technique Using Limonia Acidissima (Wood Apple) Shell as Low Cost Adsorbent. Arabian Journal of Chemistry, 10, 3229–3238.
  • 23. Arellano-Cárdenas, S., López-Cortez, S., Cornejo-Mazón, M., Mares-Gutiérrez, J.C., 2013. Study of Malachite Green Adsorption by Organically Modified Clay Using a Batch Method. Applied Surface Science, 280, 74–78.
  • 24. Zhang, J., Li, Y., Zhang, C., Jing, Y., 2008. Adsorption of Malachite Green from Aqueous Solution Onto Carbon Prepared from Arundo Donax Root. Journal of Hazardous Materials, 150, 774-782.
  • 25. Ozdes, D., Gundogdu, A., Duran, C., Senturk, H.B., 2010. Evaluation of Adsorption Characteristics of Malachite Green onto Almond Shell (Prunus dulcis), Separation Science and Technology, 45, 2076–2085.
  • 26. Coşkun, R., Savcı, S., Delibaş, A., 2018. Adsorption Properties of Activated Almond Shells for Methylene Blue (MB), Environmental Research & Technology, 1(2), 31-38.
  • 27. Bulut, Y., Aydin, H., 2006. A Kinetics and Thermodynamics Study of Methylene Blue Adsorption on Wheat Shells, Desalination, 194 (1-3), 259-267.
  • 28. Zhang J., Li, Y., Zhang C., Jing Y., 2008. Adsorption of Malachite Green from Aqueous Solution Onto Carbon Prepared from Arunda Donax Root. Journal of Hazardous Material, 150, 774-782.
There are 28 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Halis Seçme This is me

Serpil Savcı

Publication Date December 31, 2018
Published in Issue Year 2018 Volume: 33 Issue: 4

Cite

APA Seçme, H., & Savcı, S. (2018). Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa). Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 33(4), 147-154. https://doi.org/10.21605/cukurovaummfd.525153
AMA Seçme H, Savcı S. Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa). cukurovaummfd. December 2018;33(4):147-154. doi:10.21605/cukurovaummfd.525153
Chicago Seçme, Halis, and Serpil Savcı. “Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella Sativa)”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33, no. 4 (December 2018): 147-54. https://doi.org/10.21605/cukurovaummfd.525153.
EndNote Seçme H, Savcı S (December 1, 2018) Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa). Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33 4 147–154.
IEEE H. Seçme and S. Savcı, “Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa)”, cukurovaummfd, vol. 33, no. 4, pp. 147–154, 2018, doi: 10.21605/cukurovaummfd.525153.
ISNAD Seçme, Halis - Savcı, Serpil. “Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella Sativa)”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33/4 (December 2018), 147-154. https://doi.org/10.21605/cukurovaummfd.525153.
JAMA Seçme H, Savcı S. Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa). cukurovaummfd. 2018;33:147–154.
MLA Seçme, Halis and Serpil Savcı. “Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella Sativa)”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, vol. 33, no. 4, 2018, pp. 147-54, doi:10.21605/cukurovaummfd.525153.
Vancouver Seçme H, Savcı S. Dye Removal by Adsorption from Aqueous Solution Using Pulp (Nigella sativa). cukurovaummfd. 2018;33(4):147-54.