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Ligand Exchange Reactions of a Monomeric Zirconium Carbonate Complex with Carboxylic Acids Studied by Extended X-ray Absorption Fine Structure, UV Absorption and Raman Spectrophotometry

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Abstract

Ligand exchange reactions of a monomeric zirconium carbonate complex with carboxylic acids were studied by means of extended X-ray absorption fine structure (EXAFS), UV absorption spectrophotometry and Raman spectrometry. Three carboxylic acids, gluconic acid, and L-tartaric acid and citric acid, which are mono-, di- and tri-carboxylic acids, respectively, were employed in this study. These three carboxylic acids gave different spectral signatures and concentration dependences, respectively. In the gluconic acid system, the peaks on Fourier transform of EXAFS spectrum and Raman spectrum caused by carbonate ion coordinating to zirconium atom were obviously decreased with increasing gluconic acid concentration compared to the other two carboxylic acid systems. This indicates the high association ability of gluconic acid to zirconium, which was revealed by UV spectrophotometric analysis.

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References

  1. I. Denry and J. R. Kelly, Dent. Mater., 2008, 24, 299.

    Article  CAS  PubMed  Google Scholar 

  2. C. Piconi and G. Maccauro, Biomaterials, 1999, 20, 1.

    Article  CAS  PubMed  Google Scholar 

  3. M. P. Staiger, A. M. Pietak, J. Huadmai, and G. Dias, Biomaterials, 2006, 27, 1728.

    Article  CAS  PubMed  Google Scholar 

  4. D. W. Shoesmith and D. Zagidulin, J. Nucl. Mater., 2011, 418, 292.

    Article  CAS  Google Scholar 

  5. W. Jo, R. Dittmer, M. Acosta, J. Zang, C. Groh, E. Sapper, K. Wang, and J. Rödel, J. Electroceram., 2012, 29, 71.

    Article  CAS  Google Scholar 

  6. A. J. Gaunt, I. May, D. Collison, K. Travis Holman, and M. T. Pope, J. Mol. Struct., 2003, 656, 101.

    Article  CAS  Google Scholar 

  7. M. Sanz, M. E. G. Mosquera, and T. Cuenca, Dalton Trans., 2009, 2616.

    Google Scholar 

  8. A. Clearfield and Z. Wang, J. Chem. Soc. Dalton Trans., 2002, 2937.

    Google Scholar 

  9. K. J. Gagnon, H. P. Perry and A. Clearfield, Chem. Rev., 2012, 112, 1034.

    Article  CAS  PubMed  Google Scholar 

  10. E. Farnworth, S. L. Jones, and I. McAlpine, “The Production, Properties, and Uses of Zirconium Chemicals”, in “Specialty Inorganic Chemicals”, ed. R. Thompson, 1980, Royal Society of Chemistry, London, 248.

    Google Scholar 

  11. C. Walther, J. Rothe, M. Fuss, S. Büchner, S. Koltsov, and T. Bergmann, Anal. Bioanal. Chem., 2007, 388, 409.

    Article  CAS  PubMed  Google Scholar 

  12. P. A. Lee, P. H. Citrin, P. Eisenberger, and B. M. Kincaid, Reviews of Modern Physics, 1981, 53, 769.

    Article  CAS  Google Scholar 

  13. F. Takasaki, K. Fujiwara, Y. Nakajima, T. Nishikawa, and N. Ogawa, Chem. Lett., 2014, 43, 196.

    Article  CAS  Google Scholar 

  14. F. Takasaki, K. Fujiwara, Y. Nakajima, T. Nishikawa, H. Masu, M. Imanari, Y. Hidaka, and N. Ogawa, Dalton Trans., 2015, 44, 645.

    Article  CAS  PubMed  Google Scholar 

  15. F. Takasaki, N. Ogawa, I. Watanabe, T. Suzuki, Y. Nakajima, T. Wakita, and R. Suzuki, Bunseki Kagaku, 2010, 59, 447.

    Article  CAS  Google Scholar 

  16. P. L. Brown, E. Curti, B. Grambow, and C. Ekberg, “Chemical Thermodynamics of Zirconium”, ed. F. J. Mompean, J. Perrone, and M. Illemassène, 2006, Elsevier Science.

  17. M. T. Beck and I. Nagypal, “Chemistry of Complex Equilibria, Enlarged and Completely Revised Version”, ed. E. Horwood, 1990, Halsted Press, Australia.

  18. D. K. Chakravorty, R. Ghosh, R. Banerjee, and D. Sarkar, Polyhedron, 2009, 28, 1315.

    Article  CAS  Google Scholar 

  19. For example, commercially available as “Ammonium Zirconium(IV) Carbonate Solution in H2O, Contains 1-2% Tartaric Acid as Stabilizer”, from Sigma-Aldrich, CAS No. 12616-24-9.

  20. E. M. Larsen and E. H. Homeier, Inorg. Chem., 1972, 11, 2687.

    Article  CAS  Google Scholar 

  21. A. Clearfield, Inorg. Chim. Acta, 1970, 4, 166.

    Article  CAS  Google Scholar 

  22. S. I. Zabinsky, J. J. Rehr, A. Ankudinov, R. C. Albers, and M. J. Eller, Phys. Rev. B, 1995, 52, 2995.

    Article  CAS  Google Scholar 

  23. C. V. Kumar and Z. J. Williams, J. Phys. Chem., 1995, 99, 17632.

    Article  CAS  Google Scholar 

  24. F. Takasaki, Japan Patent, 2017, 6103818.

    Google Scholar 

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Acknowledgments

The synchrotron radiation EXAFS experiment was performed at the BL14B2 of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (Proposal Nos. 2010B1961, 2011B1826 and 2012A1777). We would like to thank Prof. Iwao Watanabe, Dr. Hiroshi Oji and Dr. Yosuke Taniguchi for help on EXAFS measurements and analyses.

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Authors and Affiliations

  1. Daiichi Kigenso Kagaku Kogyo Co. Ltd., 1-6-38 Hirabayashi-minami, Suminoe, Osaka, 559-0025, Japan

    Fumiyuki Takasaki, Yasushi Nakajima & Yasunori Toyoda

  2. Department of Life Science, Graduate School of Engineering and Resource Science, 1-1 Tegatagakuen-cho, Akita, 010-8502, Japan

    Kazuhiko Fujiwara, Tomomi Kikuchi & Nobuaki Ogawa

  3. Venture Incubation Center, Akita University, 1-1 Tegatagakuen-cho, Akita 010-8502, Japan

    Takenori Tanno

Authors
  1. Fumiyuki Takasaki
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  2. Kazuhiko Fujiwara
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  3. Tomomi Kikuchi
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  4. Takenori Tanno
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  5. Yasushi Nakajima
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  6. Yasunori Toyoda
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  7. Nobuaki Ogawa
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Correspondence to Fumiyuki Takasaki, Kazuhiko Fujiwara or Nobuaki Ogawa.

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Takasaki, F., Fujiwara, K., Kikuchi, T. et al. Ligand Exchange Reactions of a Monomeric Zirconium Carbonate Complex with Carboxylic Acids Studied by Extended X-ray Absorption Fine Structure, UV Absorption and Raman Spectrophotometry. ANAL. SCI. 33, 1007–1012 (2017). https://doi.org/10.2116/analsci.33.1007

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  • DOI: https://doi.org/10.2116/analsci.33.1007

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