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Oligocarbazoles as Ligands for Lead-selective Liquid Membrane Electrodes

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Abstract

Oligocarbazoles have been applied as new ionophores in liquid membrane electrodes (ISEs) destined for lead(II) determination in water samples. The oligocarbazole-containing ISEs demonstrated a close-to-Nernstian potentiometric response towards Pb2+ in the activity range 10-7 - 10-2 M. The selectivity coefficients measured by the matched potential method (MPM) confirmed their good selectivity against common interfering mono- and doubly charged cations. The oligocarbazole-containing ISEs do not respond towards protons. Their applicability has been checked by performing the recovery test while using a sample of wastewater.

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Authors and Affiliations

  1. Division of Food Science, Institute of Animal Reproduction of Polish Academy of Sciences, 10 Tuwima 10-747, Olsztyn, Poland

    Jerzy Radecki

  2. Faculty of Environmental Sciences and Fisheries, University of Warmia and Mazury, 10 Oczapowskiego 5-719, Olsztyn, Poland

    Izabela Grzybowska

  3. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium

    Ahmed Hameurlaine & Wim Dehaen

Authors
  1. Jerzy Radecki
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  2. Izabela Grzybowska
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  3. Ahmed Hameurlaine
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  4. Wim Dehaen
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Radecki, J., Grzybowska, I., Hameurlaine, A. et al. Oligocarbazoles as Ligands for Lead-selective Liquid Membrane Electrodes. ANAL. SCI. 20, 1599–1603 (2004). https://doi.org/10.2116/analsci.20.1599

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  • DOI: https://doi.org/10.2116/analsci.20.1599

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