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Silver(I)-selective Coated-wire Electrode Based on an Octahydroxycalix[4]arene Derivative

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Abstract

The performance of octahydroxycalix[4]arene derivative used as a neutral carrier for silver polymeric membrane electrode was studied. The sensor gave a good Nernstian response of 58 ± 1 mV per decade for silver ion in the activity range 3.3 × 10–6 to 3.3 × 10–2 M Ag+. The limit of detection reached 2.1 × 10–6 M Ag+ and exhibited high selectivity for silver ion against the alkali, alkaline earth and transition metal ions. The sensor can be used in wide pH range from 1.5 to 6.5. The response time of the sensor is less than 20 s. The potentiometric sensor was used as the indicator electrode in the titration of Ag+ ions by sodium chloride solution.

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Authors and Affiliations

  1. Department of Chemistry, Kashan University, Kashan, Iran

    Mohammad Mazloum Ardakani

  2. College of Chemistry, Isfahan University of, Technology, Isfahan, 84154, Iran

    Ali Asghar Ensafi, Mohammad Salavati Niasari & Hossain Mirhoseini

Authors
  1. Mohammad Mazloum Ardakani
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  2. Ali Asghar Ensafi
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  3. Mohammad Salavati Niasari
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  4. Hossain Mirhoseini
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Mazloum Ardakani, M., Ensafi, A.A., Salavati Niasari, M. et al. Silver(I)-selective Coated-wire Electrode Based on an Octahydroxycalix[4]arene Derivative. ANAL. SCI. 19, 1187–1190 (2003). https://doi.org/10.2116/analsci.19.1187

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  • DOI: https://doi.org/10.2116/analsci.19.1187

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