Skip to main content
SpringerLink
Log in

Spectrophotometric Determination of Periodate, Iodate and Bromate Mixtures Based on Their Reaction with Iodide

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A rapid, simple, precise and accurate method is proposed for the determination of ternary mixtures of periodate-iodate- bromate based on their reaction with iodide ion at different pH values. The absorbance was measured at 352 nm. Three sets of reaction conditions were developed. In the first set of conditions, only periodate reacted with iodide, but in the second set the periodate and iodate reacted with iodide and in the third set the three ions reacted with iodide during the first 3 min after initiation of the reaction. The method could be used for individual determinations of periodate, iodate and bromate in the concentration range of 0.05 - 8.0 μg/ml, 0.05 - 5.0 μg/ml and 0.2 - 12 μg/ml, respectively. The data were evaluated by simultaneous equations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. K. Chipman, J. E. Davies, J. L. Parsons, J. Nair, G. Oneill, and J. K. Fowel, Toxicology, 1998, 93, 126.

    Google Scholar 

  2. F. A. Andersen, J. Am. Coll. Toxicol., 1995, 14, 231.

    Article  CAS  Google Scholar 

  3. L. Charles and D. Pepin, Anal. Chem., 1998, 70, 353.

    Article  CAS  Google Scholar 

  4. M. S. El-Shahawi, Anal. Chim. Acta, 1997, 356, 85.

    Article  CAS  Google Scholar 

  5. A. A. Ensafi and G. Bagherian Dehaghi, Anal. Sci., 2000, 16, 61.

    Article  CAS  Google Scholar 

  6. A. Afkhami and A. R. Zarei, Talanta, 2000, 53, 815.

    Article  Google Scholar 

  7. L. Jin, X. Sun, and Y. Fang, Fenexi Huaxue, 1993, 21, 1117.

    CAS  Google Scholar 

  8. D. B. Gladilovich, Zh. Anal. Khim., 1993, 48, 1520.

    CAS  Google Scholar 

  9. J. Li, C. Wang, and X. Wei, Fenxi Shiyanshi, 1999, 18, 54.

    CAS  Google Scholar 

  10. M. Yamanaka, T. Sakai, H. Kumagai, and Y. Inoue, J. Chromatogr. A, 1997, 789, 259.

    Article  CAS  Google Scholar 

  11. W. Buchberger and W. Aher, J. Chromatogr. A, 1999, 850, 99.

    Article  CAS  Google Scholar 

  12. Y. M. Temerk, M. E. Ahmed, and M. M. Kamal, Fresenius’ Z. Anal. Chem., 1980, 301, 436.

    Article  Google Scholar 

  13. E. Kavlentis, Analusis, 1988, 16, 253.

    CAS  Google Scholar 

  14. D. Perez-Bendito and M. Silva, “Kinetic Methods in Analytical Chemistry”, 1988, Ellis Horwood, Chichester.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Bu Ali Sina University, Hamadan, Iran

    Abbas Afkhami, Tayyebeh Madrakian & Ali Reza Zarei

Authors
  1. Abbas Afkhami
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tayyebeh Madrakian
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ali Reza Zarei
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Abbas Afkhami.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Afkhami, A., Madrakian, T. & Zarei, A.R. Spectrophotometric Determination of Periodate, Iodate and Bromate Mixtures Based on Their Reaction with Iodide. ANAL. SCI. 17, 1199–1202 (2001). https://doi.org/10.2116/analsci.17.1199

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.17.1199

Search

Navigation