Abstract
Asphalt release agents (ARAs) are used for reducing the adherence of asphalt residue to tools used for asphalt mix production, while bitumen removers (BRs) are used for cleaning the asphalt residue from the tools after their use. In order to be able to formulate well performing and safe bio-based ARAs and BRs, the performance, safety and chemistry of the currently available bio-degradable ARAs and BRs from both French and American construction industry were analysed. This provided insight into how ARAs and BRs functioned, insight that is as of now, not available. In addition to these, biodegradable short-chain esters were also tested. The testing of the damage to asphalt pavement by ARAs and BRs and of the quantification of their performance, were developed in Part I of this article. In this paper, gas chromatography examined the chemical composition of the agents while Fourier transformed infrared spectrometry was used to chemically investigate the agents’ chemical modification of the bitumen. It was found that commercial ARAs can be classified by their functioning as either surfactants or softeners. Additionally, it was found that short-chained esters are very effective as BRs.
Similar content being viewed by others
References
Acton QA (2013) Silicones—advances in research and application. Scholarly Editions, Atlanta
Artamendi I, Allen B, Ward C, Phillips P (2012) Differential thermal contraction of asphalt components. In: Scarpas A, Kringos N, Al-Qadi IAL (eds) 7th RILEM international conference on cracking in pavements, RILEM Bookseries. Springer, Delft, pp 953–962
Atkins HN (2003) Highway materials, soils, and concretes, 4th edn. Prentice-Hall Inc., Upper Saddle River
Ballenger WT, Jr., Light TJ, Sr. (1993) Method of prevention of adhesion of hot-mix asphalt to containers and equipment. US Patent 5186979
Bymaster DL, Smith K (2009) Asphalt release agent and method of use. US Patent Application 2009/0038503
Chesky SR (2001) Bituminous substance removal composition. PCT International Application WO2002008379
Crum J (2008) Asphalt release agent automated spray system. US Patent Application 2008/0185455
Davies G (2005) Release agent formulas and methods. US Patent 6,902,606
Delmas G-H (2011) La Biolignine™: Structure et Application à l’élaboration de résines époxy. PhD Thesis, Institut Nationale Polytechnique de Toulouse, Université de Toulouse
DeLong WM (1994) Asphalt release agent and system. US Patent 5322554
DeLong WM (1996) Asphalt release agent. US Patent 5494502
Dituro MA, Lockwood FE, Dotson DJ, Fang J (2002) Asphalt release agent. US Patent 648624926
Eisenberg DS, Kauzmann W (1969) The structure and properties of water. Oxford University Press
El Béze L (2008) Recyclage à chaud des agrégats d’enrobés bitumineux: Identification de traceurs d’homogénéité du mélange entre bitume vieilli et bitume neuf d’apport. Université Paul Cézanne Aix-Marseille III, Marseille
Higgins F (2012) Gasoline and diesel fuel quality confirmation and composition by FTIR, presented at Gulf Coast Conference 2012. Houston, USA
Katman HY, Ibrahim MR, Matori MY, Norhisham S, Ismail N (2013) Effects of reclaimed asphalt pavement on indirect tensile strength test of foamed asphalt mix tested in dry condition. IOP Conf Ser Earth Environ Sci 16(1):1–4. doi:10.1088/1755-1315/16/1/012091
Kinnaird MG (2000) Method of releasing asphalt from equipment using surfactant solutions. US Patent 6126757
Knapp DR (1979) Handbook of analytical derivatization reactions. Wiley, New York
Kodali DR, Mahoney FG, Olson RH (1997) Release agent composition for industrial application. PCT International Application WO1998020075
Kriech AJ, Osborn LV, Snawder JE, Olsen LD, Herrick RF, Cavallari JM, McCLEAN MD, Blackburn GR (2011) Study design and methods to investigate inhalation and dermal exposure to polycyclic aromatic compounds and urinary metabolites from asphalt paving workers: research conducted through partnership. Polycycl Aromat Compd 31:243–269. doi:10.1080/10406638.2011.586398
Kultala M (2000) Release oil. PCT International Application WO1998032833
Lamontagne J, Dumas P, Mouillet V, Kister J (2001) Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens. Fuel 80:483–488
Lavin P (2003) Asphalt pavements: a practical guide to design, production and maintenance for engineers and architects. CRC Press, London
Lockwood F, Dituro M, Dotson D, Fang J (1999) Asphalt release agent. Asphalt Release Agent, WO1999054413
Mahr G, Okabe T, Ito K (2003) Release agents for bituminous substances. US Patent 6,506,444
Martin ER (1978) Release composition for bituminous materials. US Patent 4,078,104
Martin ER, Coffey ML (2000) Asphalt release agents and use thereof. US Patent 6,143,812
Mikhailenko P, Ringot E, Bertron A, Escadeillas G (2015) Determination of the performance and damage to asphalt of bio-sourced asphalt release agents (ARAs) Part I: developing test methods. Struct Mater. doi:10.1617/s11527-015-0585
Mikhailenko P, Ringot E, Bertron A, Escadeillas G (2014) Developing test methods for the determination of the performance and safety of bio-sourced Asphalt Release Agents (ARAs). Asphalt pavements: proceedings of 12th ISAP conference on asphalt pavements in Raleigh, North Carolina. CRC Press, London, pp 1713–1723
Mouillet V, Lamontagne J, Durrieu F, Planche J-P, Lapalu L (2008) Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers. Fuel 87:1270–1280. doi:10.1016/j.fuel.2007.06.029
Nakanishi K (1962) Infrared absorption spectroscopy, practical. Holden-Day, San Francisco
NTPEP (2014) Standard practice for ntpep evaluation of asphalt release agents. AASHTO, Des Moines
Olard F (2003) Comportement thermomécanique des enrobés bitumineux à basses températures Relations entre les propriétés du liant et de l’enrobé. PhD Thesis, Institut National des Sciences Appliquées de Lyon, Lyon, France. Comportement thermomécanique des enrobés bitumineux à basses températures Relations entre les propriétés du liant et de l’enrobé. PhD Thesis, Institut National des Sciences Appliquées de Lyon, Lyon
Olson RH, Mahoney FG, Kodali DR (1999) Release agent composition for industrial application. US Patent 5,900,048
Peralta EJF (2009) Study of the interaction between Bitumen and Rubber. Master's Dissertation, Universidade do Minho, Escola de Engenharia, Braga, Portugal
Salmonsen ST, Frailey MD, Proctor JJ, Krantz LP, Crooks S.M (1999) Asphalt release agent for truck beds. US Patent 5,888,279
Santos VO Jr, Oliveira FCC, Lima DG, Petry AC, Garcia E, Suarez PAZ, Rubim JC (2005) A comparative study of diesel analysis by FTIR, FTNIR and FT-Raman spectroscopy using PLS and artificial neural network analysis. Anal Chim Acta 547:188–196. doi:10.1016/j.aca.2005.05.042
Scardina M (2007) An introduction to asphalt release agent. Asph RAP 7(1):1–4
Siddiqui MN, Ali MF (1999) Studies on the aging behavior of the Arabian asphalts. Fuel 78:1005–1015. doi:10.1016/S0016-2361(99)00018-6
Sobus JR, Mcclean MD, Herrick RF, Waidyanatha S, Onyemauwa F, Kupper LL, Rappaport SM (2009) Investigation of PAH biomarkers in the urine of workers exposed to hot asphalt. Ann Occup Hyg 53:551–560. doi:10.1093/annhyg/mep041
Tachon N (2008) Nouveaux types de liants routiers à hautes performances, à teneur en bitume réduite par addition de produits organiques issus des agroressources. PhD Thesis, L’institut National Polytechnique de Toulouse, Toulouse
Tang B (2008) Applications of solid-phase microextraction to chemical characterization of materials used in road construction. PhD Thesis, Division of Highway Engineering, Royal Institute of Technology, Stockholm
Tang B, Isacsson U (2005) Determination of aromatic hydrocarbons in asphalt release agents using headspace solid-phase microextraction and gas chromatography–mass spectrometry. J Chromatogr A 1069:235–244. doi:10.1016/j.chroma.2005.02.011
Tang B, Isacsson U (2006) Chemical characterization of oil-based asphalt release agents and their emissions. Fuel 85:1232–1241. doi:10.1016/j.fuel.2005.11.002
Woods JR, Kung J, Pleizier G, Kotlyar LS, Sparks BD, Adjaye J, Chung KH (2004) Characterization of a coker gas oil fraction from athabasca oilsands bitumen. Fuel 83:1907–1914. doi:10.1016/j.fuel.2003.08.024
Yao H, You Z, Li L, Goh SW, Lee CH, Yap YK, Shi X (2013) Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy. Constr Build Mater 38:327–337. doi:10.1016/j.conbuildmat.2012.08.004
Zaki NN, Troxler RE (2013) Asphalt release agent. US Patent Application 2013/0156962
Zanzotto L (2003) Dynamic and transient testing of asphalt binder and paving mix. In: 6th international RILEM symposium on performance testing and evaluation of bituminous materials, pp 66–73. doi:10.1617/2912143772.005
Acknowledgments
The authors would like to thank FUI (French Designated Inter-Ministry Fund) and AGRIBTP research project (www.agribtp.fr) (BPI France—Région Midi-Pyrénées) for their financial support as well as Kemerid (France, www.kemerid.com) for their technical support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mikhailenko, P., Bertron, A. & Ringot, E. Determination of the performance and damage to asphalt of bio-sourced asphalt release agents (ARAs) Part II: evaluation of biodegradable products for use as ARAs and bitumen removers (BRs). Mater Struct 49, 1419–1432 (2016). https://doi.org/10.1617/s11527-015-0663-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1617/s11527-015-0663-x