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Determination of the performance and damage to asphalt of bio-sourced asphalt release agents (ARAs) Part II: evaluation of biodegradable products for use as ARAs and bitumen removers (BRs)

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Abstract

Asphalt release agents (ARAs) are used for reducing the adherence of asphalt residue to tools used for asphalt mix production, while bitumen removers (BRs) are used for cleaning the asphalt residue from the tools after their use. In order to be able to formulate well performing and safe bio-based ARAs and BRs, the performance, safety and chemistry of the currently available bio-degradable ARAs and BRs from both French and American construction industry were analysed. This provided insight into how ARAs and BRs functioned, insight that is as of now, not available. In addition to these, biodegradable short-chain esters were also tested. The testing of the damage to asphalt pavement by ARAs and BRs and of the quantification of their performance, were developed in Part I of this article. In this paper, gas chromatography examined the chemical composition of the agents while Fourier transformed infrared spectrometry was used to chemically investigate the agents’ chemical modification of the bitumen. It was found that commercial ARAs can be classified by their functioning as either surfactants or softeners. Additionally, it was found that short-chained esters are very effective as BRs.

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References

  1. Acton QA (2013) Silicones—advances in research and application. Scholarly Editions, Atlanta

    Google Scholar 

  2. Artamendi I, Allen B, Ward C, Phillips P (2012) Differential thermal contraction of asphalt components. In: Scarpas A, Kringos N, Al-Qadi IAL (eds) 7th RILEM international conference on cracking in pavements, RILEM Bookseries. Springer, Delft, pp 953–962

  3. Atkins HN (2003) Highway materials, soils, and concretes, 4th edn. Prentice-Hall Inc., Upper Saddle River

    Google Scholar 

  4. Ballenger WT, Jr., Light TJ, Sr. (1993) Method of prevention of adhesion of hot-mix asphalt to containers and equipment. US Patent 5186979

  5. Bymaster DL, Smith K (2009) Asphalt release agent and method of use. US Patent Application 2009/0038503

  6. Chesky SR (2001) Bituminous substance removal composition. PCT International Application WO2002008379

  7. Crum J (2008) Asphalt release agent automated spray system. US Patent Application 2008/0185455

  8. Davies G (2005) Release agent formulas and methods. US Patent 6,902,606

  9. Delmas G-H (2011) La Biolignine™: Structure et Application à l’élaboration de résines époxy. PhD Thesis, Institut Nationale Polytechnique de Toulouse, Université de Toulouse

  10. DeLong WM (1994) Asphalt release agent and system. US Patent 5322554

  11. DeLong WM (1996) Asphalt release agent. US Patent 5494502

  12. Dituro MA, Lockwood FE, Dotson DJ, Fang J (2002) Asphalt release agent. US Patent 648624926

  13. Eisenberg DS, Kauzmann W (1969) The structure and properties of water. Oxford University Press

  14. El Béze L (2008) Recyclage à chaud des agrégats d’enrobés bitumineux: Identification de traceurs d’homogénéité du mélange entre bitume vieilli et bitume neuf d’apport. Université Paul Cézanne Aix-Marseille III, Marseille

    Google Scholar 

  15. Higgins F (2012) Gasoline and diesel fuel quality confirmation and composition by FTIR, presented at Gulf Coast Conference 2012. Houston, USA

    Google Scholar 

  16. Katman HY, Ibrahim MR, Matori MY, Norhisham S, Ismail N (2013) Effects of reclaimed asphalt pavement on indirect tensile strength test of foamed asphalt mix tested in dry condition. IOP Conf Ser Earth Environ Sci 16(1):1–4. doi:10.1088/1755-1315/16/1/012091

    Google Scholar 

  17. Kinnaird MG (2000) Method of releasing asphalt from equipment using surfactant solutions. US Patent 6126757

  18. Knapp DR (1979) Handbook of analytical derivatization reactions. Wiley, New York

    Google Scholar 

  19. Kodali DR, Mahoney FG, Olson RH (1997) Release agent composition for industrial application. PCT International Application WO1998020075

  20. Kriech AJ, Osborn LV, Snawder JE, Olsen LD, Herrick RF, Cavallari JM, McCLEAN MD, Blackburn GR (2011) Study design and methods to investigate inhalation and dermal exposure to polycyclic aromatic compounds and urinary metabolites from asphalt paving workers: research conducted through partnership. Polycycl Aromat Compd 31:243–269. doi:10.1080/10406638.2011.586398

    Article  Google Scholar 

  21. Kultala M (2000) Release oil. PCT International Application WO1998032833

  22. Lamontagne J, Dumas P, Mouillet V, Kister J (2001) Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens. Fuel 80:483–488

    Article  Google Scholar 

  23. Lavin P (2003) Asphalt pavements: a practical guide to design, production and maintenance for engineers and architects. CRC Press, London

    Book  Google Scholar 

  24. Lockwood F, Dituro M, Dotson D, Fang J (1999) Asphalt release agent. Asphalt Release Agent, WO1999054413

  25. Mahr G, Okabe T, Ito K (2003) Release agents for bituminous substances. US Patent 6,506,444

  26. Martin ER (1978) Release composition for bituminous materials. US Patent 4,078,104

  27. Martin ER, Coffey ML (2000) Asphalt release agents and use thereof. US Patent 6,143,812

  28. Mikhailenko P, Ringot E, Bertron A, Escadeillas G (2015) Determination of the performance and damage to asphalt of bio-sourced asphalt release agents (ARAs) Part I: developing test methods. Struct Mater. doi:10.1617/s11527-015-0585

    Google Scholar 

  29. Mikhailenko P, Ringot E, Bertron A, Escadeillas G (2014) Developing test methods for the determination of the performance and safety of bio-sourced Asphalt Release Agents (ARAs). Asphalt pavements: proceedings of 12th ISAP conference on asphalt pavements in Raleigh, North Carolina. CRC Press, London, pp 1713–1723

    Google Scholar 

  30. Mouillet V, Lamontagne J, Durrieu F, Planche J-P, Lapalu L (2008) Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers. Fuel 87:1270–1280. doi:10.1016/j.fuel.2007.06.029

    Article  Google Scholar 

  31. Nakanishi K (1962) Infrared absorption spectroscopy, practical. Holden-Day, San Francisco

    Google Scholar 

  32. NTPEP (2014) Standard practice for ntpep evaluation of asphalt release agents. AASHTO, Des Moines

    Google Scholar 

  33. Olard F (2003) Comportement thermomécanique des enrobés bitumineux à basses températures Relations entre les propriétés du liant et de l’enrobé. PhD Thesis, Institut National des Sciences Appliquées de Lyon, Lyon, France. Comportement thermomécanique des enrobés bitumineux à basses températures Relations entre les propriétés du liant et de l’enrobé. PhD Thesis, Institut National des Sciences Appliquées de Lyon, Lyon

  34. Olson RH, Mahoney FG, Kodali DR (1999) Release agent composition for industrial application. US Patent 5,900,048

  35. Peralta EJF (2009) Study of the interaction between Bitumen and Rubber. Master's Dissertation, Universidade do Minho, Escola de Engenharia, Braga, Portugal

  36. Salmonsen ST, Frailey MD, Proctor JJ, Krantz LP, Crooks S.M (1999) Asphalt release agent for truck beds. US Patent 5,888,279

  37. Santos VO Jr, Oliveira FCC, Lima DG, Petry AC, Garcia E, Suarez PAZ, Rubim JC (2005) A comparative study of diesel analysis by FTIR, FTNIR and FT-Raman spectroscopy using PLS and artificial neural network analysis. Anal Chim Acta 547:188–196. doi:10.1016/j.aca.2005.05.042

    Article  Google Scholar 

  38. Scardina M (2007) An introduction to asphalt release agent. Asph RAP 7(1):1–4

  39. Siddiqui MN, Ali MF (1999) Studies on the aging behavior of the Arabian asphalts. Fuel 78:1005–1015. doi:10.1016/S0016-2361(99)00018-6

    Article  Google Scholar 

  40. Sobus JR, Mcclean MD, Herrick RF, Waidyanatha S, Onyemauwa F, Kupper LL, Rappaport SM (2009) Investigation of PAH biomarkers in the urine of workers exposed to hot asphalt. Ann Occup Hyg 53:551–560. doi:10.1093/annhyg/mep041

    Article  Google Scholar 

  41. Tachon N (2008) Nouveaux types de liants routiers à hautes performances, à teneur en bitume réduite par addition de produits organiques issus des agroressources. PhD Thesis, L’institut National Polytechnique de Toulouse, Toulouse

  42. Tang B (2008) Applications of solid-phase microextraction to chemical characterization of materials used in road construction. PhD Thesis, Division of Highway Engineering, Royal Institute of Technology, Stockholm

  43. Tang B, Isacsson U (2005) Determination of aromatic hydrocarbons in asphalt release agents using headspace solid-phase microextraction and gas chromatography–mass spectrometry. J Chromatogr A 1069:235–244. doi:10.1016/j.chroma.2005.02.011

    Article  Google Scholar 

  44. Tang B, Isacsson U (2006) Chemical characterization of oil-based asphalt release agents and their emissions. Fuel 85:1232–1241. doi:10.1016/j.fuel.2005.11.002

    Article  Google Scholar 

  45. Woods JR, Kung J, Pleizier G, Kotlyar LS, Sparks BD, Adjaye J, Chung KH (2004) Characterization of a coker gas oil fraction from athabasca oilsands bitumen. Fuel 83:1907–1914. doi:10.1016/j.fuel.2003.08.024

    Article  Google Scholar 

  46. Yao H, You Z, Li L, Goh SW, Lee CH, Yap YK, Shi X (2013) Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy. Constr Build Mater 38:327–337. doi:10.1016/j.conbuildmat.2012.08.004

    Article  Google Scholar 

  47. Zaki NN, Troxler RE (2013) Asphalt release agent. US Patent Application 2013/0156962

  48. Zanzotto L (2003) Dynamic and transient testing of asphalt binder and paving mix. In: 6th international RILEM symposium on performance testing and evaluation of bituminous materials, pp 66–73. doi:10.1617/2912143772.005

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Acknowledgments

The authors would like to thank FUI (French Designated Inter-Ministry Fund) and AGRIBTP research project (www.agribtp.fr) (BPI France—Région Midi-Pyrénées) for their financial support as well as Kemerid (France, www.kemerid.com) for their technical support.

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Correspondence to Alexandra Bertron.

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Mikhailenko, P., Bertron, A. & Ringot, E. Determination of the performance and damage to asphalt of bio-sourced asphalt release agents (ARAs) Part II: evaluation of biodegradable products for use as ARAs and bitumen removers (BRs). Mater Struct 49, 1419–1432 (2016). https://doi.org/10.1617/s11527-015-0663-x

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