Abstract
We study the interface between un-alloyed a-Si:H,F and an a-Si0.4,Ge0.6:H,F alloy using superlattice structures. From infrared spectroscopy we estimate a width of 8 A for the excess hydrogen layer, and X-ray diffraction data give us a width of 2Å contributing to the width of the diffraction peak. Vibrational Raman scattering data show that the ratios of the number of Si-Si, Ge-Ge and Si-Ge bonds is not altered by changing the number of interfaces. This fact allows us to establish an upper limit for the interface width of 3 atomic layers, i.e. one layer in each partner plus an intermediate layer.
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Conde, J.P., Shen, DS., Campbell, I.H. et al. The Structure of a-Si:H,F/a-Si,Ge:H,F Interfaces. MRS Online Proceedings Library 77, 629–634 (1986). https://doi.org/10.1557/PROC-77-629
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DOI: https://doi.org/10.1557/PROC-77-629