Skip to main content
SpringerLink
Log in

Mobility Range in Hybrid Materials

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

The dynamical properties of hybrid materials obtained from mixtures of silicon alkoxides and polyethers are studied. Different techniques are used to analyze the mobility of the different parts of the material: thermal analysis (DSC, DTMA) and NMR to probe the collective motion modes and EPR to probe the local scale. The motions are dependent on the organic ratio in the blend and the covalent grafting between the two phases. Some structural models of these blends are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Bibliography

  1. C. J. Brinker, Sol-Gel Science, The Physics and Chemistry of Sol-Gel Processing, (Academic Press, San Diego, 1981).

    Google Scholar 

  2. Proceedings of the First European Workshop on Hybrid Organic-Inorganic Materials, (Eds. C. Sanchez, F. Ribot, 1993).

    Google Scholar 

  3. B. M. Novak, Adv. Mater.,5, 422, (1993).

    Article  CAS  Google Scholar 

  4. D. E. Rodrigues, A. B. Brennan, C. Betrabet, B. Wang, G. L. Wilkes, Chem. Mater., 4, 1437, (1992).

    Article  CAS  Google Scholar 

  5. P. Judeinstein, J. Titman, M. Stamm, H. Schmidt, Chem. Mater, 6, 127, (1994).

    Article  CAS  Google Scholar 

  6. P. Judeinstein, H. Schmidt, J. Sol-Gel Sci. and Tech., (accepted).

  7. R. K. Harris, Nuclear Magnetic Resonance Spectroscopy, (Pitman Books Ltd., London, 1983).

    Google Scholar 

  8. A. R. McGhie, Electrochemical Science and Technology of Polymers-2, (Ed. R. G. Linford, Elsevier, London, 1991), 201.

  9. P. Judeinstein, P. W. Oliveira, H. Krug, H. Schmidt, Chem. Phys. Lett., (accepted).

  10. R. A. Dwek, Nuclear Magnetic Resonance in Biochemistry, (Clarendon Press, Oxford,1975), 285.

    Google Scholar 

  11. P. L. Kumler, R. F. Boyer, Macromolecules, 9, 903, (1976).

    Article  CAS  Google Scholar 

  12. T. Marinovic, S. Valic, M. Andreis, Z. Veksli, Polymer,32, 2519, (1991).

    Article  CAS  Google Scholar 

  13. J. E. Gambogi, F. D. Blum, Macromolecules,25, 4526, (1992).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie Structurale Organique (URA 1384), Université Paris Sud, Bât. 410, 91405, Orsay, France

    P. Judeinstein, M. E. Brik, J. P. Bayle & J. Courtieu

  2. Laboratoire de Physique des Solides, Université Paris Sud, Bât 510, 91405, Orsay, France

    J. Rault

Authors
  1. P. Judeinstein
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. E. Brik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. P. Bayle
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Courtieu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Rault
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Judeinstein, P., Brik, M.E., Bayle, J.P. et al. Mobility Range in Hybrid Materials. MRS Online Proceedings Library 346, 937–942 (1994). https://doi.org/10.1557/PROC-346-937

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-346-937

Search

Navigation