Skip to main content
Log in

Properties of Composite Membranes of SPEEK and Nanodiamond

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

The manufacture of composite materials can improve the properties of proton-conducting polymers as membranes in PEM fuel cells. We have investigated composite membranes obtained by dispersion of nanodiamond particles in a sulfonated PolyEtherEtherKetone (SPEEK) matrix. SPEEK is a major proton-conducting aromatic polymer. Nanodiamond has been studied for various applications and can be functionalized with different surface groups. For use in proton-conducting membranes, surface functionalization with proton-donating groups is a promising approach. In this preliminary work, we have studied the properties of membranes made using pristine nanodiamond from diverse origins for a first assessment of the potential properties. The composites were analysed by various techniques, including Thermogravimetric Analysis, water vapor uptake and mechanical tensile tests.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Kusoglu, A. M. Karlsson, M. H. Santare, S. Cleghorn, W. B. Johnson, J. Power Sources 161 (2006) 987–996.

    Article  CAS  Google Scholar 

  2. H. Hou, M. L. Di Vona, P. Knauth, ChemSusChem, 4 (2011) DOI: 10.1002/cssc.201000415.

  3. P. Knauth, H. Hou, E. Bloch, E. Sgreccia, M. L. Di Vona, J. Anal. Appl. Pyrolysis 92 (2011) 361–365.

    Article  CAS  Google Scholar 

  4. T. Higashihara, K. Matsumoto, M. Ueda, Polymer 50 (2009) 5341–5357.

    Article  CAS  Google Scholar 

  5. S. Zhong, X. Cui, H. Cai, T. Fu, C. Zhao, H. Na, J. Power Sources 164 (2007) 65–72.

    Article  CAS  Google Scholar 

  6. M. L. Di Vona, E. Sgreccia, S. Licoccia, G. Alberti, L. Tortet, P. Knauth, J. Phys. Chem. B 113 (2009) 7505–7512.

    Article  Google Scholar 

  7. L. Li, J. Zhang, Y. Wang, J. Membr. Sci. 226 (2003) 159–167.

    Article  CAS  Google Scholar 

  8. S. Ren, C. Li, X. Zhao, Z. Wu, S. Wang, G. Sun, Q. Xin, X. Yang, J. Membr. Sci. 247 (2005) 59–63.

    Article  CAS  Google Scholar 

  9. M. L. Di Vona, E. Sgreccia, S. Licoccia, M. Khadhraoui, R. Denoyel, P. Knauth, Chem. Mater. 20 (2008) 4327–4334.

    Article  Google Scholar 

  10. H.L. Wu, C.C. M. Ma, C.H. Li, T.M. Lee, C.Y. Chen, C.L. Chiang, C. Wu, J. Membr. Sci. 280 (2006) 501–508.

    Article  CAS  Google Scholar 

  11. S.M.J. Zaidi, M.I. Ahmad, J. Membr.Sci. 279 (2006) 548–557.

    Article  CAS  Google Scholar 

  12. S. M. J. Zaidi, S. D. Mikhailenko, G. P. Robertson, M. D. Guiver, S. Kaliaguine, J. Membr. Sci. 173 (2000) 17–34.

    Article  CAS  Google Scholar 

  13. P. Krishnan, J. S. Park, C. S. Kim, J. Membr. Sci. 279 (2006) 220–229.

    Article  CAS  Google Scholar 

  14. M.H.D. Othman, A.F. Ismail, A. Mustafa, J. Membr. Sci. 229 (2007) 156–165.

    Article  Google Scholar 

  15. E.K. Cho, J.S. Park, S.H. Park, Y.W. Choi, T.H. Yang, Y. G. Yoon, C.S. Kim, W.Y. Lee, S.B. Park, J. Membr. Sci. 279 (2008) 355–362.

    Article  Google Scholar 

  16. Q. Li, R. He, J. O. Jensen, N. J. Bjerrum, Chem. Mater. 15 (2003) 4896–4915.

    Article  CAS  Google Scholar 

  17. Y. Zhang, H. Zhang, X. Zhu, C. Bi, J. Phys. Chem. B 111 (2007) 6391–6399.

    Article  CAS  Google Scholar 

  18. M.L. Di Vona, E. Sgreccia, A. Donnadio, M. Casciola, J.F. Chailan, G. Auer, P. Knauth, J. Membr. Sci. 369 (2011) 536–544.

    Article  CAS  Google Scholar 

  19. M. L. Di Vona, D. Marani, C. D’Ottavi, M. Trombetta, E. Traversa, I. Beurroies, P. Knauth, S. Licoccia, Chem. Mater. 18 (2006) 69–75.

    Article  Google Scholar 

  20. Y.S. Li, T.S. Zhao, W.W. Yang, In. J. Hydrogen Energy 35 (2010) 5656–5665.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hou, H., Maranesi, B., Khadhraoui, M. et al. Properties of Composite Membranes of SPEEK and Nanodiamond. MRS Online Proceedings Library 1384, 2 (2011). https://doi.org/10.1557/opl.2012.188

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/opl.2012.188

Navigation