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Highly (002)-oriented ZnO film grown by ultrasonic spray pyrolysis on ZnO-seeded Si (100) substrate

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Abstract

ZnO films are grown by the ultrasonic spray pyrolysis method on ZnO seeding layer deposited on Si (100) by pulsed laser deposition. The resultant film possesses a columnar microstructure perpendicular to the substrate and exhibits smooth, dense, and uniform morphology. The preferred orientation along the c-axis of the film is significantly enhanced compared to that without the seeding layer. ZnO film grown on ZnO-seeded silicon exhibits higher hall mobility, lower resisitivity, and higher photoluminescence intensity.

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References

  1. S.J. Pearton, D.P. Norton, K. Ip, Y.W. Heo, and T. Steiner: Recent progress in processing and properties of ZnO. Prog. Mater. Sci. 50, 293 (2005).

    Article  CAS  Google Scholar 

  2. D.P. Norton, Y.W. Heo, M.P. Ivill, K. Ip, S.J. Pearton, M.F. Chisholm, and T. Steiner: ZnO: Growth, doping and processing. Mater. Today 7, 34 (2004).

    Article  CAS  Google Scholar 

  3. D.C. Look and B. Claflin: P-type doping and devices based on ZnO. Phys. Status Solidi 241, 624 (2004).

    Article  CAS  Google Scholar 

  4. R.F. Service: Will UV lasers beat the blues? Science 276, 895 (1997).

    Article  CAS  Google Scholar 

  5. A. Tsukazaki, A. Ohtomo, T. Onuma, M. Ohtani, T. Makino, M. Sumiya, K. Ohtani, S.F. Chichibu, S. Fuke, Y. Segawa, H. Ohno, H. Koinuma, and M. Kawasaki: Repeated temperature modulation epitaxy for p-type doping and light-emitting diode based on ZnO. Nat. Mater. 4, 42 (2005).

    Article  CAS  Google Scholar 

  6. M. Joseph, H. Tabata, H. Saeki, K. Ueda, and T. Kawai: Fabrication of the low-resistive p-type ZnO by codoping method. Physica B (Amsterdam) 302–303, 140 (2001).

    Article  Google Scholar 

  7. J.L. Zhao, X.M. Li, J.M. Bian, W.D. Yu, and X.D. Gao: Structural, optical and electrical properties of ZnO films grown by pulsed laser deposition (PLD). J. Cryst. Growth 276, 507 (2005).

    Article  CAS  Google Scholar 

  8. J.F. Rommeluere, L. Svob, F. Jomard, J. Mimila-Arroyo, A. Lusson, V. Sallet, and Y. Marfaing: Electrical activity of nitrogen acceptors in ZnO films grown by metalorganic vapor phase epitaxy. Appl. Phys. Lett. 83, 287 (2003).

    Article  CAS  Google Scholar 

  9. C.C. Lin and S.Y. Chen: Properties of nitrogen-implanted p-type ZnO films grown on Si3N4/Si by radio-frequency magnetron sputtering. Appl. Phys. Lett. 84, 5040 (2004).

    Article  CAS  Google Scholar 

  10. T.M. Barnes, K. Olson, and C.A. Wolden: On the formation and stability of p-type conductivity in nitrogen-doped zinc oxide. Appl. Phys. Lett. 86, 112112 (2005).

    Article  Google Scholar 

  11. G.K. Paul and S.K. Sen: Sol-gel preparation, characterization and studies on electrical and thermoelectrical properties of gallium doped zinc oxide films. Mater. Lett. 57, 742 (2002).

    Article  CAS  Google Scholar 

  12. F. Paraguay, W. Estrada, D.R. Acosta, E. Andrade, and M. Miki-Yoshiba: Growth, structure and optical characterization of high quality ZnO thin films obtained by spray pyrolysis. Thin Solid Films 350, 192 (1999).

    Article  Google Scholar 

  13. J.M. Bian, X.M. Li, X.D. Gao, W.D. Yu, and L.D. Chen: Deposition and electrical properties of N-In codoped p-type ZnO films by ultrasonic spray pyrolysis. Appl. Phys. Lett. 84, 541 (2004).

    Article  CAS  Google Scholar 

  14. C.Y. Zhang, X.M. Li, J.M. Bian, W.D. Yu, and X.D. Gao: Structural and electrical properties of nitrogen and aluminum codoped p-type ZnO films. Solid State Commun. 132, 75 (2004).

    Article  CAS  Google Scholar 

  15. J.L. Zhao, X.M. Li, J.M. Bian, W.D. Yu, and C.Y. Zhang: Growth mechanism for N-doped ZnO film grown by spray pyrolysis method. J. Cryst. Growth 280, 495 (2005).

    Article  CAS  Google Scholar 

  16. E. Mirica, G. Kowach, P. Evans, and H. Du: Morphological evolution of ZnO thin films deposited by reactive sputtering. Cryst. Growth Des. 4, 147 (2004).

    Article  CAS  Google Scholar 

  17. P.B. Barna and M. Adamik: Science and Technology of Thin Films (World Scientific Publishing Co. Pte. Ltd., Singapore, 1995), p. 1.

    Book  Google Scholar 

  18. E. Ziegler, A. Heinrich, H. Oppermann, and G. Stover: Electrical properties and non-stoichiometry in ZnO single crystals. Phys. Status Solidi A 66, 635 (1981).

    Article  CAS  Google Scholar 

  19. D.C. Look, J.W. Hemsky, and J.R. Sizelove: Residual native shallow donor in ZnO. Phys. Rev. Lett. 82, 2552 (1999).

    Article  CAS  Google Scholar 

  20. C.G. Van de Walle: Hydrogen as a cause of doping in zinc oxide. Phys. Rev. Lett. 85, 1012 (2000).

    Article  Google Scholar 

  21. L.Y. Chen, W.H. Chen, J.J. Wang, F.C.N Hong, and Y.K. Su: Hydrogen-doped high conductivity ZnO films deposited by radio-frequency magnetron sputtering. Appl. Phys. Lett. 85, 5628 (2004).

    Article  CAS  Google Scholar 

  22. K. Vanheusden, W.L. Warren, C.H. Seager, D.R. Tallant, J.A. Voigt, and B.E. Gnade: Mechanisms behind green photoluminescence in ZnO phosphor powders. J. Appl. Phys. 79, 7983 (1996).

    Article  CAS  Google Scholar 

  23. Y. Ma, G.T. Du, S.R. Yang, Z.T. Li, B.J. Zhao, X.T. Yang, T.P. Yang, Y.T. Zhang, and D.L. Liu: Control of conductivity type in undoped ZnO thin films grown by metalorganic vapor phase epitaxy. J. Appl. Phys. 95, 6268 (2004).

    Article  CAS  Google Scholar 

  24. T. Matsumoto, H. Kato, K. Miyamoto, M. Sano, and E.A. Zhukov: Correlation between grain size and optical properties in zinc oxide thin films. Appl. Phys. Lett. 81, 1231 (2002).

    Article  CAS  Google Scholar 

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This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/publications/jmr/policy.html.

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Zhao, JL., Li, XM., Zhang, S. et al. Highly (002)-oriented ZnO film grown by ultrasonic spray pyrolysis on ZnO-seeded Si (100) substrate. Journal of Materials Research 21, 2185–2190 (2006). https://doi.org/10.1557/jmr.2006.0291

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