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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) September 25, 2009

High-pressure crystal chemistry of binary intermetallic compounds

  • Roman Demchyna , Stefano Leoni , Helge Rosner and Ulrich Schwarz

Abstract

Effects of high pressure on intermetallic compounds are reviewed with regards to structural stability and phase transitions. Changes of bonding properties and electronic structure are examplified by means of the elemental metals caesium and titanium, the latter forming an internal intermetallic compound at high pressures. After a short systematic overview regarding pressure effects, structural transformations in selected classes of intermetallic compounds like Zintl phases and AlB2-type arrangements precedes sections concerning high-pressure synthesis of Laves phases and intermetallic clathrates.

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Published Online: 2009-9-25
Published in Print: 2006-5-1

© by Oldenbourg Wissenschaftsverlag, München

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