Abstract
The coal is an imperative source of energy, which on combustion, it emits sulphur dioxide, which cause air pollution. In the present study, microwave mediated desulphurization of coal was investigated and input variables were optimized by response surface methodology (RSM). The proximate analysis and ultimate analysis report indicate the sample belongs to subbituminous having sulphur (6.96%), volatile matter (34.5%) and calorific value (5099 kcal/kg). Under microwave irradiation, up to 68% of sulphur was leached in alkaline medium. The particle size of coal, concentration of potassium hydroxide (KOH), microwave exposure time and power of microwave radiation were systematically optimized for maximum desulphurization of the coal. Under optimum conditions of the process variables, 63.06% desulphurization of coal was achieved. The optimum levels of process variables are as, particle size 500 µm, irradiation time 8.54 min, radiation power 720 W and concentration of KOH 15% (w/v). Findings revealed that the microwave-assisted desulphurization under alkaline condition furnished promising efficiency, which can be employed for the desulphurization of coal.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was supported by Researchers Supporting Project number (RSP2023R100), King Saud University, Riyadh, Saudi Arabia.
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Conflict of interest statement: The authors declare that they have no conflicts of interest.
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