Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
Licensed Unlicensed Requires Authentication Published by De Gruyter August 6, 2021

Three metal(II) complexes constructed using the 2-(1H-benzo[d]imidazol-2-yl)quinoline ligand

  • Feriel Aouatef Sahki , Mehdi Bouchouit , Sofiane Bouacida , Lyamine Messaadia , Elsa Caytan , Aissa Chibani , Thierry Roisnel and Abdelmalek Bouraiou EMAIL logo
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-2021-0071

Abstract

2-(1H-benzo[d]imidazol-2-yl)quinoline (BQ) as ligand and three coordination compounds of formula {Zn(BQ)Cl2} (1), {Pb(BQ)Cl2} n (2) and {[Cu(BQ)2(OC(O)CH3)]OC(O)CH3 · CH3COOH} (3) have been synthesized and fully characterized. The complexes crystallize in triclinic space group P 1 ‾ . In complexes 1 and 2, the coordination geometry is a distorted tetrahedral environment around the zinc center and a distorted sixfold coordination geometry around the lead center, respectively. In complex 3 the central Cu(II) center is in a trigonal bipyramidal coordination geometry. The Cu(II) ion is surrounded by two bidentate 2-(2′-quinolyl)benzimidazole (BQ) ligands and one coordinated acetate molecule. One further acetate anion associated by a strong hydrogen bond with a molecule of acetic acid balances the charge of the compound.

Keywords: benzimidazole; copper(II); coordination compounds; lead(II); single-crystal X-ray diffraction; zinc(II)
Corresponding author: Abdelmalek Bouraiou, Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Université des Frères Mentouri, Constantine 25000, Algeria, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research received no specific grant from any funding agency in the public, commercial, or not-for-profit sectors.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Zhang, X.-L., Guo, C.-P., Yang, Q.-Y., Wang, W., Liu, W.-S., Kang, B.-S., Su, C.-Y. Chem. Commun. 2007, 41, 4242–4244; https://doi.org/10.1039/b709118d.Search in Google Scholar

2. Bodman, S. E., Crowther, A. C., Geraghty, P. B., Fitchett, C. M. Cryst.Eng.Comm. 2015, 17, 81–89; https://doi.org/10.1039/c4ce01851f.Search in Google Scholar

3. Lalegani, A., Sardashti, M. K., Khalaj, M., Gajda, R., Woźniak, K. Inorg. Chim. Acta 2017, 457, 136–144; https://doi.org/10.1016/j.ica.2016.12.021.Search in Google Scholar

4. Maekawa, M., Minamino, A., Sugimoto, K., Okubo, T., Kuroda-Sowa, T., Munakata, M. Inorg. Chim. Acta 2014, 413, 257–263; https://doi.org/10.1016/j.ica.2014.02.016.Search in Google Scholar

5. Nasani, R., Saha, M., Mobin, S. M. Dalton Trans. 2014, 43, 9944–9954; https://doi.org/10.1039/c4dt00531g.Search in Google Scholar

6. Crowley, J. D., McMorran, D. A. “Click-triazole” coordination chemistry: exploiting 1,4-disubstituted-1,2,3-triazoles as ligands. In Topics in Heterocyclic Chemistry; Košmrlj, J., Ed.; Springer: Berlin, Heidelberg, Vol. 28, 2012; pp. 31–38.10.1007/7081_2011_67Search in Google Scholar

7. Bernabé-Pablo, E., Campirán-Martínez, A., Jancik, V., Martínez-Otero, D., Moya-cabrera, M. Polyhedron 2016, 110, 305–313; https://doi.org/10.1016/j.poly.2015.08.004.Search in Google Scholar

8. Cary, D. R., Zaitseva, M. P., Gray, K., O’Day, K. E., Darrow, C. B., Lane, S. M., Peyser, T. A., Satcher, J. H., Van Antwerp, W. P., Nelson, A. J., Reynolds, J. G. Inorg. Chem. 2002, 41, 1662–1669; https://doi.org/10.1021/ic010202b.Search in Google Scholar

9. Tyson, D. S., Henbest, K. B., Bialecki, J., Castellano, F. N. J. Phys. Chem. A 2001, 105, 8154–8161; https://doi.org/10.1021/jp011770f.Search in Google Scholar

10. Sangilipandi, S., Nagarajaprakash, R., Sutradhar, D., Kaminsky, W., Chandra, A. K., Rao, K. M. Inorg. Chim. Acta 2015, 437, 177–187; https://doi.org/10.1016/j.ica.2015.09.001.Search in Google Scholar

11. Li, G., Zhang, D., Liu, G., Pu, S. Tetrahedron Lett. 2016, 57, 5205–5210; https://doi.org/10.1016/j.tetlet.2016.10.027.Search in Google Scholar

12. Zhao, Y., Chai, W. X., Song, L., Zhang, Y. C., Shi, H. S., Tao, X. D., Shu, K. Y. Phosphorus Sulfur Relat. Elem. 2016, 191, 1123–1128; https://doi.org/10.1080/10426507.2016.1146274.Search in Google Scholar

13. Zhang, W. J., Huang, W., Liang, T. L., Sun, W. H. Chin. J. Polym. Sci. 2013, 31, 601–609; https://doi.org/10.1007/s10118-013-1253-4.Search in Google Scholar

14. Dayan, O., Tercan, M., Özdemir, N. J. Mol. Struct. 2016, 1123, 35–43 and references cited therein; https://doi.org/10.1016/j.molstruc.2016.06.017.Search in Google Scholar

15. Gong, D. P., Gao, T. B., Cao, D. K., Ward, M. D. Dalton Trans. 2017, 46, 275–286; https://doi.org/10.1039/c6dt04091h.Search in Google Scholar

16. Bouchouit, M., Bouraiou, A., Bouacida, S., Belfaitah, A., Merazig, H. J. Struct. Chem. 2016, 57, 835–839; https://doi.org/10.1134/s0022476616040338.Search in Google Scholar

17. Bouchouit, M., Said, M. E., Kara Ali, M., Bouacida, S., Merazig, H., Kacem Chaouche, N., Chibani, A., Zouchoune, B., Belfaitah, A., Bouraiou, A. Polyhedron 2016, 119, 248–259; https://doi.org/10.1016/j.poly.2016.08.045.Search in Google Scholar

18. Sahki, F. A., Messaadia, L., Merazig, H., Chibani, A., Bouraiou, A., Bouacida, S. J. Chem. Sci. 2017, 129, 21–29; https://doi.org/10.1007/s12039-016-1210-1.Search in Google Scholar

19. Wang, X., Fan, R., Dong, Y., Su, T., Huang, J., Du, X., Wang, P., Yang, Y. Cryst. Growth Des. 2017, 17, 5406–5421; https://doi.org/10.1021/acs.cgd.7b00891.Search in Google Scholar

20. Mamedov, V. A., Saifina, D. F., Gubaidullin, A. T., Ganieva, V. R., Kadyrova, S. F., Rakov, D. V., Rizvanov, I. K., Sinyashin, O. G. Tetrahedron Lett. 2010, 51, 6503–6506; https://doi.org/10.1016/j.tetlet.2010.10.007.Search in Google Scholar

21. Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., De Caro, L., Giacovazzo, C., Polidori, G., Spagna, R. J. Appl. Crystallogr. 2005, 38, 381–388; https://doi.org/10.1107/s002188980403225x.Search in Google Scholar

22. Sheldrick, G. M. Acta Crystallogr 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Search in Google Scholar

23. Farrugia, L. J. J. Appl. Crystallogr. 2012, 45, 849–854; https://doi.org/10.1107/s0021889812029111.Search in Google Scholar

24. Sheldrick, G. M. Sadabs; Bruker AXS Inc.: Madison, Wisconsin (USA), 2002.Search in Google Scholar
Received: 2021-05-08
Accepted: 2021-07-10
Published Online: 2021-08-06
Published in Print: 2021-10-26

© 2021 Walter de Gruyter GmbH, Berlin/Boston

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 76 Issue 9

Journal and Issue

Articles in the same Issue

Frontmatter
In this issue
Research Articles
Antimycobacterial cycloartane derivatives from the roots of Trichilia welwistchii C. DC (Meliaceae)
Three metal(II) complexes constructed using the 2-(1H-benzo[d]imidazol-2-yl)quinoline ligand
Low-perchlorate blue-flame pyrotechnic compositions
A convenient synthesis of trifluoromethyl-substituted quinolino[8,7-h]quinolines and quinolino[7,8-h]quinolines
Curie temperature adjustment in the solid solution Gd1–xY x PtMg
Synthesis of oligotetramethylene oxides with terminal amino groups as curing agents for an epoxyurethane oligomer
Synthesis, characterization and optoelectronic properties of 2D hybrid RPbX4 semiconductors based on an isomer mixture of hexanediamine-based dications
Electrochemical sensing of hydrogen peroxide on a carbon paste electrode modified by a silver complex based on the 1,3-bis(1H-benzimidazole-2-yl)propane ligand
Downloaded on 27.4.2024 from https://www.degruyter.com/document/doi/10.1515/znb-2021-0071/html
Scroll to top button