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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Methylated Ammonium and Hydrazinium Salts of 5,5′-Azotetrazolate

  • Anton Hammerl , G. Holl , M. Kaiser , Thomas M. Klapötke EMAIL logo , Peter Mayer , Holger Piotrowski and Martin Vogt

Abstract

Salts of the 5,5′-azotetrazolate dianion with methylated ammonium and hydrazinium cations were prepared. The compounds were characterized by elemental analysis, vibrational (IR, Raman) and multinuclear NMR spectroscopy (1H, 13C, 14N). The crystal structures of the di[ammonium], the bis[dimethylammonium] and the bis[trimethylhydrazinium] 5,5′-azo­ tetrazolate salts were determined. The thermal, shock and friction sensitivities of these com­ pounds were investigated and their explosion products were analysed.

Received: 2001-4-30
Published Online: 2014-6-2
Published in Print: 2001-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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