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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Organogallitimamide: Synthese und Kristallstrukturen von [iPr2GaN(H)tBu]2 und [Mes(Cl)GaN(H)tBu]2 / Organogallium Amides: Synthesis and Crystal Structures of [iPr2GaN(H)tBu]2 und [Mes(Cl)GaN(H)tBu]2

  • Mike R. Kopp , Thomas Kräuter , Anahita Dashti-Mommertz and Bernhard Neumüller
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1999-0510

[iPr2GaN(H)tBu]2 (1) and [Mes(Cl)GaN(H)tBu]2 (2) can be synthesized by the metathesis reaction of iPr2GaCl and MesGaCl2 with one equivalent of LiN(H)tBu, respectively. 1 and 2 were characterized by NMR, IR and MS techniques as well as by X-ray structure analyses. 1 and 2 consist of centrosymmetric dimeric molecules with a Ga2N2 skeleton. According to cryoscopic measurements in benzene, both amides are dimeric in solution, too.

Keywords : Gallium Compounds; Organogallium Amides; Crystal Structure
Received: 1999-1-8
Published Online: 2014-6-2
Published in Print: 1999-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 54 Issue 5

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