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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Die Kristallstruktur von Tris(trimethylstannyl) acetonitril / Crystal Structure of Tris(trimethylstannyl)- acetonitrile

  • Ralf Hillwig , Klaus Harms and Kurt Dehnicke
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1997-0128

Single crystals of (Me3Sn)3CCN were obtained by the reaction of tris(trimethylstannyl)amine with boiling acetonitrile in the presence of potassium fluoride and trimethylarsane. The compound has been characterized by IR spectroscopy and by a crystal structure determination. Space group P21/n, Z = 4; lattice dimensions at -50 °C: a = 975.4(1), b = 1316.3(2), c = 1485.3(1), β = 98.55(1)°, R = 0.029. (Me3Sn)3CCN forms monomeric molecules with a linear CCN axis (bond angle 178.7(6)°) and bond lengths of CC = 142.1(8) pm and CN = 114.5(8) pm

: Tin Compound; Synthesis; IR Spectra; Crystal Structure
Received: 1996-10-7
Published Online: 2014-6-2
Published in Print: 1997-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 52 Issue 1

Journal and Issue

Articles in the same Issue

Contents
Synthese und Untersuchung neuer 1λ5, 4λ5-Diphosphapentalen- und 1λ5,4λ5 - sowie 1λ5,5λ5-Diphosphaazulen-Systeme / Synthesis of New 1λ5,4λ5-Diphosphapentalene- and 1λ5,5λ5-Diphosphaazulene Systems
Synthese und Reaktivität von γ-Triphenylstannyl-α-aminobuttersäure-derivaten / Synthesis and Reactivity of γ-Triphenylstannyl-α-aminobutyric Acid Derivatives
Coordination Chemistry of Lipoic Acid and Related Compounds, Part 1 Syntheses and Crystal Structures of the UV- and Light-Sensitive Lipoato Complexes [M(lip)2(H2O)2] (M = Zn, Cd)
Photochemische Synthese neuer zinnorganischer Verbindungen mit „aktiven“ Gruppen am Zinnatom (I) / Photochemical Synthesis of New Tinorganic Compounds with Active Substituents on Tin
1-Allylgermatrane. Synthesis, Structure and Reaction with Diazomethane
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6
Synthese von 1-Butyl-2,3,4,5-tetraphenyl-2,4-cyclopentadien und seiner Natrium-, Thallium(I)-und Eisen(II)-Komplexe / Synthesis of 1-Butyl-2,3,4,5-tetraphenyl-2,4-cyclopentadiene and its Sodium, Thallium (I) and Iron(II) Complexes
1,4-Bis(4-acylphen-1 -yl) 1,3-cy clopentadiene und 1,2,3,4-Tetra(4-alkylphen-1-yl)-1,3-cyclopentadiene und deren Natrium-, Thallium(I)- und Eisen(II)-Komplexe / 1,4-Bis(4-acylphen-1-yl)-1,3-cyclopentadienes and 1,2,3,4-Tetra(4-alkylphen-1-yl)- 1,3-cyclopentadienes and their Sodium, Thallium (I) and Iron(II) Complexes
Structural Investigation of Bis(isonitrile)gold(I) Complexes
Darstellung und spektroskopische Charakterisierung von (η3-Hexahydro-closo-hexaborato)phenylquecksilber(1-) [Hg(η3-B6H6)Ph] sowie Kristallstruktur von [PPh4][Hg(η3-B6H6)Ph] / Preparation and Spectroscopic Characterization of (η3-Hexahydro-closo-hexaborato)phenylmercury(1 -) [Hg(η3-B6H6)Ph]- and Crystal Structure of [PPh4][Hg(η3-B6H6)Ph]
Ligandenaustauschreaktionen von ReCl4(PPh3)2 mit Salicylaldehyd-2-hydroxy(mercapto)anil. Struktur von Bis[salicylaldehyd-2-hydroxyanilato(2-)]rhenium(IV) / Ligand Exchange Reactions of ReCl4 (PPh3)2 with Salicylaldehyde-2-hydroxy(mercapto)anil. Molecular Structure of Bis[salicylaldehyde-2-hydroxyanilato(2-)]rhenium(IV)
Charge - Transfer Complexes of Metal Dithiolenes XXIV: Ion Pairs of the Tetrakis(dimethylamino)ethene Dication with Dithiolene Metalate Dianions
Bis(trifluormethyl)disulfan und -trisulfan: Molekülgeometrie im festen Zustand [1] / Bis(trifluoromethyl)disulfane and Trisulfane: Molecular Geometry in the Solid State [1]
1,3-Dioxolane von N-substituierten 4-Piperidonen als Dehydrierungssubstrat / 1,3-Dioxolanes of N-Substituted 4-Piperidones as Substrates for Dehydrogenations
Synthesis and Structure of Bis[di(methylcyclopentadienyl)chloro-titanium]trisulfide [(Cp′2ClTi)2S3] - a Reagent for Trisulfide Ligand Transfer Reactions [1]
Ba(VO)4(AsO4)2(As2O7): Ein neues Divanadyl(IV)-Arsenat mit flächenverknüpften V2O8+1-Oktaederdoppeln / Ba(VO)4 (AsO4)2 (As2O7): A New Divanadyl(IV)-Arsenate Containing Face Shared V2O8+, Double Octahedra
Über die Darstellung von CH3C6H4S(O)2NCl2H+SbF-6 und die Kristallstruktur von CH3C6H4S(O)2NCl2 / On the Synthesis of CH3C6H4S(O)2NCl2,H+SbF-6 and the Crystal Structure of CH3C6H4S(O)2NCl2
Bis-und Tris[μ-nitrido-bis(diorganylphoshinato-O,O′)]- element( 1+)-Kationen / Bis- and Tris[μ-nitrido-bis(diorganylphosphinato-O,O′)]-element(1+) Cations
Die Synthese und Kristallstruktur des Borat-Phosphats: α -Zn3(BO3)(PO4) / Synthesis and Crystal Structure of the Borate-Phosphate: α-Zn3(BO3)( PO4)
Occurrence of Toxin Producing Cyanobacteria in Hungary. Isolation, Separation and Identification of Microcystins
Optimized Large Scale Synthesis of Phosphorothioate Oligonucleotides on PS-PEG Supports
Synthesis of Cationic Ruthenium Thioketene Complexes through Intramolecular 1,2-Elimination [1]
Eindimensionale Kupfer(II)-Koordinationspolymere: Kristall-Engineering durch variable Verknüpfungsmuster [1] / One Dimensional Copper(II) Coordination Polymers: Crystal Engineering through Variable Types of Linkage [1]
Darstellung und spektroskopische Charakterisierung von Trifluormethylazosulfonylmethan CH3S(O) 2NNCF3 / Preparation and Spectroscopic Characterization of Trifluoromethylazosulfonylmethan CH3S(O)2NNCF3
Kristallstruktur von 1,1,1-Trichloro-cyclo-1λ6-wolframa-3,5-dithia-2,4,6- triazin, [WCl3(N3S2 )]2 / Crystal Structure of 1,1,1-Trichloro-cyclo- 1λ6-tungsta-3,5-dithia-2,4,6-triazine, [WCl3(N3S2)]2
The Stannide Zr5CuSn3
Die Kristallstruktur von Tris(trimethylstannyl) acetonitril / Crystal Structure of Tris(trimethylstannyl)- acetonitrile
Die Kristallstrukturen von Trimethylbleiiodid und Diphenylbismutchlorid / Crystal Structures of Trimethyllead Iodide and Diphenylbismuth Chloride
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