Abstract
Bis(/75-cyclopentadienyl)-chloro-selenophenolatotitanium (IV), Bis(?75-cyclopentadienyl)-chloro-selenophenolatozirconium (IV), Bis(//5-cyclopentadienyl)-chloro-selenophenolatohafnium (IV), Bis(^5-cyclopentadienyl)-chloro-selenophenolatotungsten(IV), Mass Spectra The metallocene chloro selenophenolates C p;M Cl(SeChH 5) (Cp = ^5-C5H 5; M = Ti, Z r, Hf, W) were prepared by reaction of Cp2MCl2 with equivalent am ounts of LiSeC6H 5, obtained from phenylselenol and «-butyllithium, and were characterized by 'H NM R, IR and MS data. The fragmentation behaviour of the Ti and W derivatives is elucidated by observing m etastable transi tions in the mass spectra.
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