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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

[Aryl(phenyl)selenoketon]pentacarbonyl-Komplexe von Chrom und Wolfram / [Aryl(phenyl)selenoketone]pentacarbonyl Complexes of Chromium and Tungsten

  • Helmut Fischer and Siegfried Zeuner

Abstract

[Aryl(phenyl)carbene]pentacarbonyl complexes of chromium and tungsten, (CO)5M[C(p-C6H4R)Ph] (M = Cr, R = H and M = W, R = NMe2, OMe, Me, H, Br, CF3) react with phenylisoselenocyanate or potassium selenocyanate inserting selenium into the metal-carbene bond to give the first η1 -bonded bisarylselenoketone(carbonyl) complexes, (CO)5M[Se = C(p-C6H4R)Ph]. The compounds were characterized by analytical and spectroscopic means.

Received: 1983-6-27
Published Online: 2014-6-2
Published in Print: 1983-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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