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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Triphenylstannyltris(trimethylphosphan)cobalt - Molekülstruktur und Eigenschaften / Triphenylstannyltris(trimethylphosphane)cobalt -Molecular Structure and Properties

  • Hans-Friedrich Klein , Klaus Ellrich , Dietmar Neugebauer , Olli Orama and Karl Krüger
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1983-0305
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Abstract

Potassium cobaltates K+CoLsL' -(L = Me3P, L' = N2, olefin) react with SnCl(C6H5)3 or GeBr(CeH5)3 to give tetracoordinate complexes containing Co-Sn and Co-Ge bonds. Crystal and molecular structures of two single crystals were determined. They show tetrahedral molecules Co[Sn(C6H5)3][P(CH3)3]3 in different packing order. Both tetra-coordinate compounds take up small ligands thereby completing their 18-electron valence shells in compounds Co[E(C6H5)3]L3L' (L = (CH3)3P; E = Ge, L' = CO; E = Sn, L' = CO, C2H4). A sparingly soluble paramagnetic adduct Co[Sn(C6H5)3]L4 is believed to contain a tin-bonded phosphane.

: Triphenylstannyl and Triphenylgermyl Cobalt(I) Complexes; Synthesis; Reactions; Crystal Structures; Molecular Structure
Received: 1982-11-29
Published Online: 2014-6-2
Published in Print: 1983-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 38 Issue 3

Journal and Issue

Articles in the same Issue

Atran-analoge Verbindungen des Typs / Atrane Analogous Compounds of Type
Alternativ-Liganden, XIV [1]. Neue Chelatliganden des Typs (2-Me2E′C6H4)Si(EMe2)Me2 (E, E′ = N, P, As; Me = CH3) / Alternative Ligands, XIV [1]. Novel Chelating Ligands of the Type (2-Me2E′C6H4)Si(EMe2)Me2 (E, E′ = N, P, As; Me = CH3)
Alternativ-Liganden, XV [1]. Neue Liganden des Typs (4-XC6H4)SiMe(EMe2)CH2CH2E′Me2 (E, E′ = N, P, As; X = Cl, F; Me = CH3) / Alternative Ligands, XV [1]. Novel Ligands of the Type (4-XC6H4)SiMe(EMe2)CH2CH2E′Me2 (E, E′ = N, P, As; X = Cl, F; Me = CH3)
Darstellung and Kristallstruktur von [(C6H5)4As]2M(NO3)5 (M = Ho, Er, Tm, Yb) / Preparation and Crystal Structure of [(C6H5)4As]2M(NO3)5 (M = Ho, Er, Tm, Yb)
Triphenylstannyltris(trimethylphosphan)cobalt - Molekülstruktur und Eigenschaften / Triphenylstannyltris(trimethylphosphane)cobalt -Molecular Structure and Properties
Die quaternären Systeme ZnAl2S4-ZnGa2S4, ZnAl2S4-CdAl2S4 und ZnAl2S4-ZnAl2Se4. Röntgenographische und schwingungsspektroskopisehe Untersuchungen / Investigation of the Quaternary Systems ZnAl2S4-ZnGa2S4, ZnAl2S4-CdAl2S4 and ZnAl2S4-ZnAl2Se4 by X-Ray Diffraction and Vibrational Spectroscopy
Über die Staudinger-Reaktion mit Tantaltetrachloridazid. Die Kristallstruktur von Tantal(V)-(triphenylphosphinimino)tetrachlorid, Ta[NP(C6H5)3]Cl4 / On the Staudinger Reaction with Tantalum Tetrachloride Azide. The Crystal Structure of Tantalum(V)(triphenyl-phosphinimino)tetrachloride, Ta[NP(C6H5)3]Cl4
[1]Metallocenophane: 1H-NMR-Untersuchungen / [1]Metallocenophanes: 1H NMR Investigations
Schwefel-Stickstoff-Verbindungen, XII [1]. 19F-NMR-und 13C-NMR-spektroskopische Untersuchung einiger aromatisch substituierter Schwefeldiimide / Sulfur-Nitrogen Compounds, XII [1]. 19F NMR and 13C NMR Spectroscopic Investigation of Some Aromatic Substituted Sulfurdiimides
Bor- und Arsen-methoxotetrafluorotellurate(VI) / Boron and Arsenic Methoxotetrafluorotellurates(VI)
Molekülstrukturen, Schwingungsspektren und Konformation der Thiooxalsäurederivate CH3S-CO-CONH2, CH3S-CS-CONH2, C2H5O-CO-CSNH2 und K[OSC-CONH2] / Molecular Structure, Vibrational Spectra and Conformation of the Thiooxalic Acid Derivatives CH3S-CO-CONH2, CH3S-CS-CONH2, C2H5O-CO-CSNH2 and K[OSC-CONH2]
Darstellung und Kristallstruktur des 2:3-Adduktes von Antimontrichlorid und 4-Phenylpyridin, 2 SbCl3 · 3 (C11H9N) / Preparation and Crystal Structure of the 2:3 Adduct of Antimony Trichloride and 4-Phenylpyridine, SbCl3 · 3 (C11H9N)
Zur Darstellung und Struktur des 1.3-Dichloro-5-N.N-dimethylamino-1.3-dithia-2.4.6-triazins / Synthesis and Structure of 1,3-Dichloro-5-N,N-dimethylamino-1,3-dithia-2,4,6-triazine
Deprotonated Complexes of Bis(o-aminobenzenesulfonyl)ethylenediamine with Mn(II), Co(II), Ni(II) and Cu(II)
Metallomethane, VI [1]. Kristallstruktur von Tetrakis(chloroquecksilber)methan-Dimethylsulfoxid C(HgCl)4 · (CH3)2SO / Metallomethanes, VI [1]. Crystal Structure of Tetrakis(chloromercuri)methane-Dimethylsulfoxide C(HgCl)4 · (CH3)2SO
Diphenylphosphino -α -aminosäureester als Liganden in Palladium(II)-und Platin(II)-Komplexen [1] / Diphenylphosphino-α-Amino Acid Esters as Ligands in Palladium(II) and Platinum(II) Complexes [1]
Reaktionen von S-Methylthiireniumsalzen mit nucleophilen Übergangsmetall-Komplexen [1] / Reactions of S-Methylthiirenium Salts with Nucleophilic Transition Metal Complexes [1]
Zur Struktur von (Pyrazolinonyl)-(hydroxypyrazolylium)methanperchloraten NMR-, IR-spektroskopische Studien und Kristallstruktur / The Structure of (Pyrazohnonyl)-(hydroxypyrazolyhum)methaneperchlorates NMR, IR Spectroscopic Studies and Crystal Structure
Lösliche Phthalocyaninatometalloxane, Dotierung und Leitfähigkeit / Soluble Phthalocyaninatometaloxanes, Doping and Conductivity
Derivate des Benzo[1.3]dioxols, 47 [1]. Darstellung und Reaktionen des 4.8-Dimethoxy-bis[1.3]dioxolo[4.5]benzo- [1.2-d; 1′ .2′ -f] [1.3]dioxepins / Derivatives of 1,3-Benzodioxoles, 47 [1]. Preparation and Reactions of 4,8-Dimethoxy-bis[1,3]dioxolo[4,5]benzo- [1,2-d; 1',2'-f][1,3]dioxepine
Derivate des 1.3-BenzdioxoIs, 48 [1]. Darstellung und Reaktionen von substituierten 1.3-Benzdioxol-4.7-cliinonen / Derivatives of 1,3-Benzdioxoles, 48 [1]. Preparation and Reactions of 1,3-Benzdioxole-4,7-quinones
Ylide von Heterocyclen, V [1]. I-, N-und S-Ylide des 2-Pyrons und 2-Pyridons / Ylides of Heterocycles, V [1]. I-, N-and S-Ylides of 2-Pvrones and 2-Pyridones
NOTIZEN. Darstellung und Struktur von Ba6Sn2P6 / Preparation and Crystal Structure of Ba6Sn2P6
Direkte Lithiierung von BicycIo[3,2,1]octa-2.6-dien / Direct Lithiation of Bicyclo[3,2,1]octa-2,6-diene
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