Synthesen mit aliphatischen Dialdehyden, XXXV. Synthesen mit 1- und 2-Adamantylmalonaldehyd/ Syntheses with Aliphatic Dialdehydes, XXXV. Syntheses with 1- and 2-Adamantyl Malonaldehyde

Christian Reichardt; Ernst-Ulrich Würthwein

doi:10.1515/znb-1982-0918

Open Access Published by De Gruyter June 2, 2014

Synthesen mit aliphatischen Dialdehyden, XXXV. Synthesen mit 1- und 2-Adamantylmalonaldehyd/ Syntheses with Aliphatic Dialdehydes, XXXV. Syntheses with 1- and 2-Adamantyl Malonaldehyde

Christian Reichardt and Ernst-Ulrich Würthwein

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1982-0918

Abstract

The reaction of 1- (1) and 2-adamantyl malonaldehyde (2) with suitable electrophiles and nucleophiles yields adainantyl-substituted open-chain (3-5), carbocyclic (6) as well as heterocyclic compounds (7-19) with peculiar properties due to the presence of the lipophilic adamantyl group. The tetrazolo[1,5-a]pyrimidine (16) exhibits a solvent-dependent tetrazolo-azido valence isomerization reaction.

Keywords: Adamantane-1-yl and Adamantane-2-yl Substituted Carbo- und Heterocycles; Tetrazole-Azido Valence Isomerization; Tetrazolo[1,5-a]pyrimidine

Received: 1982-4-5

Published Online: 2014-6-2

Published in Print: 1982-9-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Synthesen mit aliphatischen Dialdehyden, XXXV. Synthesen mit 1- und 2-Adamantylmalonaldehyd/ Syntheses with Aliphatic Dialdehydes, XXXV. Syntheses with 1- and 2-Adamantyl Malonaldehyde

Abstract

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