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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Transition Metal Complexes of Diazenes, XVII [1]. Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

  • A. Albini , H. Kisch , C. Krüger and An-Pei Chiang
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1982-0412
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Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-1,2-diazetine (L) or its mono-N-oxide (L′) to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L′)Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

Keywords: 1,2-Diazetines; 1,2-Diazetine-N-oxide; Iron Complexes; X-ray
Received: 1981-11-13
Published Online: 2014-6-2
Published in Print: 1982-4-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 37 Issue 4

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