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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Cation-Ordering in Synthetic Mg2-xFexSiO4-Olivines

  • Ch. Riekel and Armin Weiss

Abstract

In annealed, synthetic samples of Mg2-xFexSiO4 the Mg2+ and Fe2+ ions are not randomly distributed. With 0.1 ≦ x ≦ 0.6 the larger Fe2+ ions replace preferentially Mg2+ in octahedral sites of symmetry m and the lattice dimensions do not change in this range. Quenching tends to yield samples with more randomly distributed cations and the lattice dimensions approach those of natural olivines.

Received: 1977-11-9
Published Online: 2014-6-2
Published in Print: 1978-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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