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Licensed Unlicensed Requires Authentication Published by De Gruyter September 17, 2013

Present technologies for hydrogen sulfide removal from gaseous mixtures

  • Ahmed Daham Wiheeb

    Ahmed Daham Wiheeb is a PhD student at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia. He is also an Assistant Professor at the Department of Chemical Engineering, University of Tikrit, Iraq.

    , Ili Khairunnisa Shamsudin

    Ili Khairunnisa Shamsudin is a PhD student at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

    , Mohd Azmier Ahmad

    Mohd Azmier Ahmad (PhD) is an Associate Professor at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

    , Muhamad Nazri Murat

    Muhamad Nazri Murat (PhD) is a Senior Lecturer at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

    , Jinsoo Kim

    Jinsoo Kim (PhD) is a Professor at the Department of Chemical Engineering, College of Engineering, Kyung Hee University, Republic of Korea.

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    and Mohd Roslee Othman

    Mohd Roslee Othman (PhD) is an Associate Professor at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

    EMAIL logo

Abstract

Natural gas, refinery gas, and coal gas contain acid gases such as hydrogen sulfide (H2S) and carbon dioxide that must be removed from the gas stream due to the toxicity of H2S and to prevent corrosion to piping and production facility caused by the acid gases. In this article, current technologies for the acid gas removal are selected and reviewed. The review includes absorption, adsorption, conversion of H2S into elemental sulfur, and membrane reactor for H2S decomposition and desulfurization. Recently, hollow fiber membrane contactor has been in the limelight of research in H2S absorption from gaseous mixture due to its potential to overcome problems such as foaming and loading. Recent trends on Claus tail gas cleanup technologies are highlighted due to the recent progress in membrane technology. The article also suggests current research on the acid gas removal technology using catalytic membrane reactor. The interest on finding suitable active component and support and studying the membrane structure for enhanced removal of acid gases is likely to be rekindled in the near future.


Corresponding authors: Jinsoo Kim, Department of Chemical Engineering, Kyung Hee University, Global campus, 1 Seocheon-dong, Giheung-gu, Yongin-si, Gyeonggi-do 446-701, Republic of Korea, e-mail: ; and Mohd Roslee Othman, School of Chemical Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia, e-mail:

About the authors

Ahmed Daham Wiheeb

Ahmed Daham Wiheeb is a PhD student at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia. He is also an Assistant Professor at the Department of Chemical Engineering, University of Tikrit, Iraq.

Ili Khairunnisa Shamsudin

Ili Khairunnisa Shamsudin is a PhD student at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

Mohd Azmier Ahmad

Mohd Azmier Ahmad (PhD) is an Associate Professor at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

Muhamad Nazri Murat

Muhamad Nazri Murat (PhD) is a Senior Lecturer at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

Jinsoo Kim

Jinsoo Kim (PhD) is a Professor at the Department of Chemical Engineering, College of Engineering, Kyung Hee University, Republic of Korea.

Mohd Roslee Othman

Mohd Roslee Othman (PhD) is an Associate Professor at the School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia.

The support from the Universiti Sains Malaysia under Membrane Science and Technology Research Cluster, RU-PRGS grant scheme and Short Term grants are gratefully acknowledged.

References

Abbasian J, Slimane RB. A regenerable copper-based sorbent for H2S removal from coal gases. Ind Eng Chem Res 1998; 37: 2775–2782.10.1021/ie980047hSearch in Google Scholar

Abbasian J, Rehmat A, Leppin D, Banerjee DD. An advanced coal gasification desulfurization process. Chicago, IL: Institute of Gas Technology, 1990.Search in Google Scholar

Adib F, Bagreev A, Bandosz TJ. Effect of pH and surface chemistry on the mechanism of H2S removal by activated carbons. J Colloid Interf Sci 1999; 216: 360–369.10.1006/jcis.1999.6335Search in Google Scholar

Adib F, Bagreev A, Bandosz TJ. Adsorption/oxidation of hydrogen sulfide on nitrogen-containing activated carbons. Langmuir 2000; 16: 1980–1986.10.1021/la990926oSearch in Google Scholar

Akamatsu K, Nakane M, Sugawara T, Hattori T, Nakao SI. Development of a membrane reactor for decomposing hydrogen sulfide into hydrogen using a high-performance amorphous silica membrane. J Membr Sci 2008; 325: 16–19.10.1016/j.memsci.2008.08.005Search in Google Scholar

Al-Marzouqi M, El-Naas M, Marzouk S, Abdullatif N. Modeling of chemical absorption of CO2 in membrane contactors. Sep Purif Technol 2008; 62: 499–506.10.1016/j.seppur.2008.02.009Search in Google Scholar

Alonso L, Palacios JM, García E, Moliner R. Characterization of Mn and Cu oxides as regenerable sorbents for hot coal gas desulfurization. Fuel Process Technol 2000; 62: 31–44.10.1016/S0378-3820(99)00063-6Search in Google Scholar

Atchariyawut S, Jiraratananon R, Wang R. Separation of CO2 from CH4 by using gas-liquid membrane contacting process. J Membr Sci 2007; 304: 163–172.10.1016/j.memsci.2007.07.030Search in Google Scholar

Baehr H. Gas purification by the IG alkacid process and sulfur recovery by the IG Clauss process. Refiner Natural Gas Manuf 1938; 17: 237.Search in Google Scholar

Bagreev A, Bandosz TJ. Study of hydrogen sulfide adsorption on activated carbons using inverse gas chromatography at infinite dilution. J Phys Chem B 2000; 104: 8841–8847.10.1021/jp0011037Search in Google Scholar

Bagreev A, Bandosz TJ. A role of sodium hydroxide in the process of hydrogen sulfide adsorption/oxidation on caustic-impregnated activated carbons. Ind Eng Chem Res 2002; 41: 672–679.10.1021/ie010599rSearch in Google Scholar

Bagreev A, Bandosz T. Carbonaceous materials for gas phase desulfurization: role of surface heterogeneity. Prepr Pap-Am Chem Soc Div Fuel Chem 2004; 49: 817–821.Search in Google Scholar

Bagreev A, Adib F, Bandosz TJ. pH of activated carbon surface as an indication of its suitability for H2S removal from moist air streams. Carbon 2001; 39: 1897–1905.10.1016/S0008-6223(00)00317-1Search in Google Scholar

Bagreev A, Katikaneni S, Parab S, Bandosz TJ. Desulfurization of digester gas: prediction of activated carbon bed performance at low concentrations of hydrogen sulfide. Catal Today 2005; 99: 329–337.10.1016/j.cattod.2004.10.008Search in Google Scholar

Bandosz TJ. Effect of pore structure and surface chemistry of virgin activated carbons on removal of hydrogen sulfide. Carbon 1999; 37: 483–491.10.1016/S0008-6223(98)00217-6Search in Google Scholar

Bandosz TJ. Activated carbon surfaces in environmental remediation. New York: Academic Press, Elsevier Ltd., 2006.Search in Google Scholar

Bandel G, Willing W. In the doxosulfreen Claus tail gas process-meeting enhanced sulfur emission standard. Sulphur 2000; 96.Search in Google Scholar

Bansal RC, Donnet JB, Stoeckli F. Active carbon. M. Dekker, New York, 1988; 25–118.Search in Google Scholar

Bashkova S, Baker FS, Wu X, Armstrong TR, Schwartz V. Activated carbon catalyst for selective oxidation of hydrogen sulphide: on the influence of pore structure, surface characteristics, and catalytically-active nitrogen. Carbon 2007; 45: 1354–1363.10.1016/j.carbon.2007.01.005Search in Google Scholar

Bashkova S, Armstrong TR, Schwartz V. Selective catalytic oxidation of hydrogen sulfide on activated carbons impregnated with sodium hydroxide. Energ Fuel 2009; 23: 1674–1682.10.1021/ef800711cSearch in Google Scholar

Basu R, Clausen E, Gaddy J. Biological conversion of hydrogen sulfide into elemental sulfur. Environ Prog 1996; 15: 234–238.10.1002/ep.670150412Search in Google Scholar

Battersby S, Teixeira PW, Beltramini J, Duke MC, Rudolph V, Diniz da Costa JC. An analysis of the Peclet and Damkohler numbers for dehydrogenation reactions using molecular sieve silica (MSS) membrane reactors. Catal Today 2006; 116: 12–17.10.1016/j.cattod.2006.04.004Search in Google Scholar

Berben PH, Geus JW. Catalyst for the selective oxidation of sulfur containing compounds to elemental sulfur. US Patent 1989; 4,818,740.Search in Google Scholar

Bineesh KV, Kim DK, Kim DW, Cho HJ, Park DW. Selective catalytic oxidation of H2S to elemental sulfur over V2O5/Zr-pillared montmorillonite clay. Energy Environ Sci 2010; 3: 302–310.10.1039/b921937dSearch in Google Scholar

Bineesh KV, Kim DK, Kim MIL, Park DW. Selective catalytic oxidation of H2S over V2O5 supported on TiO2-pillared clay catalysts in the presence of water and ammonia. Appl Clay Sci 2011; 53: 204–211.10.1016/j.clay.2010.12.022Search in Google Scholar

Boucif N, Favre E, Roizard D, Belloul M. Hollow fiber membrane contactor for hydrogen sulfide odor control. AIChE J 2008; 54: 122–131.10.1002/aic.11348Search in Google Scholar

Bontozoglou V, Karabelas AJ. Simultaneous absorption of H2S and CO2 in NaOH solutions: experimental and numerical study of the performance of a short-time contactor. Ind Eng Chem Res 1993; 32: 165–172.10.1021/ie00013a022Search in Google Scholar

Borgwardt RH, Bruce KR, Blake J. An investigation of product-layer diffusivity for calcium oxide sulfation. Ind Eng Chem Res 1987; 26: 1993–1998.10.1021/ie00070a010Search in Google Scholar

Brettschneider O, Thiele R, Faber R, Thielert H, Wozny G. Experimental investigation and simulation of the chemical absorption in a packed column for the system NH3-CO2-H2S-NaOH-H2O. Sep Purif Technol 2004; 39: 139–159.10.1016/S1383-5866(03)00165-5Search in Google Scholar

Cal M, Strickler B, Lizzio A. High temperature hydrogen sulfide adsorption on activated carbon: I. Effects of gas composition and metal addition. Carbon 2000; 38: 1757–1765.10.1016/S0008-6223(00)00010-5Search in Google Scholar

Chan PPY, Vanidjee K, Adesina AA, Rogers PL. Modeling and simulation of non-isothermal catalytic packed bed membrane reactor for H2S decomposition. Catal Today 2000; 63: 379–385.10.1016/S0920-5861(00)00482-XSearch in Google Scholar

Cho DR, Kim SY, Park DW, Mutin PH. Selective catalytic oxidation of H2S using nonhydrolytic vanadia-titania xerogels. Korean J Chem Eng 2009; 26: 377–381.10.1007/s11814-009-0063-4Search in Google Scholar

Chou CHSJ. Hydrogen sulfide: Human health aspects. Geneva: World Health Organization, 2003.Search in Google Scholar

Chun SW, Jang JY, Park DW, Woo HC, Chung JS. Selective oxidation of H2S to elemental sulfur over TiO2/SiO2 catalysts. Appl Catal B Environ 1998; 16: 235–243.10.1016/S0926-3373(97)00078-7Search in Google Scholar

Claus CF. British Patent 1883; 5958.10.1038/scientificamerican02241883-5958csuppSearch in Google Scholar

DeBerry D. Chemical evolution of liquid redox processes. Environ Prog 1997; 16: 193–199.10.1002/ep.3300160316Search in Google Scholar

Delgado JA, Uguina MA, Sotelo JL, Águeda VI, Sanz A. Simulation of CO2 absorption into aqueous DEA using a hollow fiber membrane contactor: evaluation of contactor performance. Chem Eng J 2009; 152: 396–405.10.1016/j.cej.2009.04.064Search in Google Scholar

Dindore VY, Brilman DWF, Versteeg GF. Modelling of cross-flow membrane contactors: mass transfer with chemical reactions. J Membr Sci 2005; 255: 275–289.10.1016/j.memsci.2005.01.042Search in Google Scholar

Dolan MD, Ilyushechkin AY, McLennan KG, Sharma SD. Sulfur removal from coal-derived syngas: thermodynamic considerations and review. Asia Pac J Chem Eng 2012; 7: 1–13.10.1002/apj.528Search in Google Scholar

Dubois L, Thomas D. Comparison of various alkaline solutions for H2S/CO2 selective absorption applied to biogas purification. Chem Eng Technol 2010; 33: 1601–1609.10.1002/ceat.201000171Search in Google Scholar

Edlund D. A membrane reactor for H2S decomposition. USDOE Morgantown Energy Technology Center, West Virginia (United States), 1996. In proceed. Advanced coal-fired power systems review meeting.Search in Google Scholar

Edlund DJ, Pledger WA. Catalytic platinum-based membrane reactor for removal of H2S from natural gas streams. J Membr Sci 1994; 94: 111–119.10.1016/0376-7388(93)E0140-FSearch in Google Scholar

Eow JS. Recovery of sulfur from sour acid gas: a review of the technology. Environ Prog 2002; 21: 143–162.10.1002/ep.670210312Search in Google Scholar

Faiz R, Al-Marzouqi M. Mathematical modeling for the simultaneous absorption of CO2 and H2S using MEA in hollow fiber membrane contactors. J Membr Sci 2009; 342: 269–278.10.1016/j.memsci.2009.06.050Search in Google Scholar

Faiz R, Al-Marzouqi M. H2S absorption via carbonate solution in membrane contactors: Effect of species concentrations. J Membr Sci 2010; 350: 200–210.10.1016/j.memsci.2009.12.028Search in Google Scholar

Faiz R, Al-Marzouqi M. Insights on natural gas purification: Simultaneous absorption of CO2 and H2S using membrane contactors. Sep Purif Technol 2011; 76: 351–361.10.1016/j.seppur.2010.11.005Search in Google Scholar

Feng W, Kwon S, Borguet E, Vidic R. Adsorption of hydrogen sulfide onto activated carbon fibers: effect of pore structure and surface chemistry. Environ Sci Technol 2005; 39: 9744–9749.10.1021/es0507158Search in Google Scholar

Fenouil LA, Lynn S. Study of calcium-based sorbents for high-temperature H2S removal. 3. Comparison of calcium-based sorbents for coal gas desulfurization. Ind Eng Chem Res 1995; 34: 2343–2348.10.1021/ie00046a016Search in Google Scholar

Franken A, Nolten J, Mulder M, Bargeman D, Smolders C. Wetting criteria for the applicability of membrane distillation. J Membr Sci 1987; 33: 315–328.10.1016/S0376-7388(00)80288-4Search in Google Scholar

Gabelman A, Hwang ST. Hollow fiber membrane contactors. J Membr Sci 1999; 159: 61–106.10.1016/S0376-7388(99)00040-XSearch in Google Scholar

Garcia-Arriaga V, Alvarez-Ramirez J, Amaya M, Sosa E. H2S and O2 influence on the corrosion of carbon steel immersed in a solution containing 3 M diethanolamine. Corros Sci 2010; 52: 2268–2279.10.1016/j.corsci.2010.03.016Search in Google Scholar

Gasper-Galvin LD, Atimtay AT, Gupta RP. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Ind Eng Chem Res 1998; 37: 4157–4166.10.1021/ie930439iSearch in Google Scholar

George Z. Effect of catalyst basicity for COS-SO2 and COS hydrolysis reactions. J Catal 1974; 35: 218–224.10.1016/0021-9517(74)90200-0Search in Google Scholar

Godini HR, Mowla D. Selectivity study of H2S and CO2 absorption from gaseous mixtures by MEA in packed beds. Chem Eng Res Des 2008; 86: 401–409.10.1016/j.cherd.2007.11.012Search in Google Scholar

Govind R, Atnoor D. Development of a composite palladium membrane for selective hydrogen separation at high temperature. Ind Eng Chem Res 1991; 30: 591–594.10.1021/ie00051a024Search in Google Scholar

Graham JR, Cheng JY. Activated carbon for odor control and method for making same. US Patent 2005. 6,858,192.Search in Google Scholar

Gupta PK, Turk BS, Vierheilig AA. Desulfurization sorbents for transport-bed application, in: Advanced Coal-Based Power and Environmental Systems ‘98 Conference,” Morgantown, WV, USA, July 21–23, 1998.Search in Google Scholar

Hawboldt K, Monnery W, Svrcek W. New experimental data and kinetic rate expression for H2S pyrolysis and re-association. Chem Eng Sci 2000; 55: 957–966.10.1016/S0009-2509(99)00366-8Search in Google Scholar

Heguy DL, Nagl GJ. Consider optimized iron-redox processes to remove sulfur. Hydrocarb Process 2003; 82: 53–57.Search in Google Scholar

Hendrickson RG, Chang A, Hamilton RJ. Co-worker fatalities from hydrogen sulfide. Am J Ind Med 2004; 45: 346–350.10.1002/ajim.10355Search in Google Scholar PubMed

Hua GX, McManus D, Woollins JD. The evolution, chemistry and applications of homogeneous liquid redox sulfur recovery techniques. Comment Inorg Chem 2001; 22: 327–351.10.1080/02603590108050874Search in Google Scholar

Itoh N. A membrane reactor using palladium. AlChE J 1987; 33: 1576–1578.10.1002/aic.690330921Search in Google Scholar

Itoh N, Tamura E, Hara S, Takahashi T, Shono A, Satoh K, Namba T. Hydrogen recovery from cyclohexane as a chemical hydrogen carrier using a palladium membrane reactor. Catal Today 2003; 82: 119–125.10.1016/S0920-5861(03)00210-4Search in Google Scholar

Jalan V, Ryu J. Continuous sulfur removal process. US Patent 1994; 5,306,476.Search in Google Scholar

Jefferson B, Nazareno C, Georgaki S, Gostelow P, Stuetz RM, Longhurst P, Robinson T. Membrane gas absorbers for H2S removal, design, operation and technology integration into existing odour treatment strategies. Environ Technol 2005; 26: 793–804.10.1080/09593332608618511Search in Google Scholar

Jensen AB, Webb C. Treatment of H2S-containing gases: A review of microbiological alternatives. Enzyme Microb Technol 1995; 17: 2–10.10.1016/0141-0229(94)00080-BSearch in Google Scholar

Jose AR, Amitesh M. Adsorption and decomposition of H2S on MgO(100), NiMgO(100), and ZnO(0001) surfaces: a first-principles density functional study. J Phys Chem B 2000; 104: 3630–3638.10.1021/jp000011eSearch in Google Scholar

Jun HK, Lee TJ, Ryu SO, Kim JC. A study of Zn-Ti-based H2S removal sorbents promoted with cobalt oxides. Ind Eng Chem Res 2001; 40: 3547–3556.10.1021/ie0011167Search in Google Scholar

Kaloidas VE, Papayannakos NG. Kinetics of thermal, non-catalytic decomposition of hydrogen sulphide. Chem Eng Sci 1989; 44: 2493.10.1016/0009-2509(89)85193-0Search in Google Scholar

Kameyama T, Dokiya M, Fujishige M, Yokokawa H, Fukuda K. Production of hydrogen from hydrogen sulfide by means of selective diffusion membranes. Int J Hydrogen Energ 1983; 8: 5–13.10.1016/0360-3199(83)90029-0Search in Google Scholar

Keller N, Pham-Huu C, Crouzet C, Ledoux MJ, Savin-Poncet S, Nougayrede JB, Bousquet J. Direct oxidation of H2S into S: new catalysts and processes based on SiC support. Catal Today 1999; 53: 535–542.10.1016/S0920-5861(99)00141-8Search in Google Scholar

Keller N, Pham-Huu C, Ledoux MJ. Continuous process for selective oxidation of H2S over SiC-supported iron catalysts into elemental sulfur above its dew point. Appl Catal A Gen 2001; 217: 205–217.10.1016/S0926-860X(01)00601-9Search in Google Scholar

Kim BS, Harriott P. Critical entry pressure for liquids in hydrophobic membranes. J Colloid Interf Sci 1987; 115: 1–8.10.1016/0021-9797(87)90002-6Search in Google Scholar

Ko TH, Chu H, Chaung LK, Tseng TK. High temperature removal of hydrogen sulfide using an N-150 sorbent. J Hazard Mater 2004; 114: 145–152.10.1016/j.jhazmat.2004.08.023Search in Google Scholar

Ko TH, Chu H, Chaung L. The sorption of hydrogen sulfide from hot syngas by metal oxides over supports. Chemosphere 2005; 58: 467–474.10.1016/j.chemosphere.2004.09.029Search in Google Scholar

Konshenko E, Balaev A, Ismagilov F, Spivak S, Safin R. Direct catalytic oxidation of hydrogen sulfide. Chem Tech Fuels Oil 2001; 37: 212–218.10.1023/A:1017941209151Search in Google Scholar

Lagas JA, Borboom J, Berben PH, Geus JW. A process for recovering sulfur from sulfur-containing gases. European Patent 1988; 0,242,006.Search in Google Scholar

Lampert J. Selective catalytic oxidation: a new catalytic approach to the desulfurization of natural gas and liquid petroleum gas for fuel cell reformer applications. J Power Sources 2004; 131: 27–34.10.1016/j.jpowsour.2004.01.022Search in Google Scholar

Landau M, Molyneux A, Houghton R. In Laboratory and plant evaluation of catalysts for sulfur recovery from lean H2S gas streams. London, UK: Symp. Ser. No. 27, Institution of Chemical Engineers, 1968: 228.Search in Google Scholar

Laperdrix E, Justin I, Costentin G, Saur O, Lavalley J, Aboulayt A, Ray J, Nedez C. Comparative study of CS2 hydrolysis catalyzed by alumina and titania. Appl Catal B Environ 1998; 17: 167–173.10.1016/S0926-3373(98)00014-9Search in Google Scholar

Laperdrix E, Sahibed-dine A, Costentin G, Bensitel M, Lavalley JC. Evidence of the reverse Claus reaction on metal oxides: influence of their acid-base properties. Appl Catal B Environ 2000; 27: 137–142.10.1016/S0926-3373(00)00144-2Search in Google Scholar

Ledoux MJ, Pham-Huu C, Keller N, Nougayrède JB, Savin-Poncet S, Bousquet J. Selective oxidation of H2S in Claus tail-gas over SiC supported NiS2 catalyst. Catal Today 2000; 61: 157–163.10.1016/S0920-5861(00)00365-5Search in Google Scholar

Lee EK, Jung KD, Joo OS, Shul YG. Selective oxidation of hydrogen sulfide to elemental sulfur with Fe/MgO catalysts in a slurry reactor. B Kor Chem Soc 2005a; 26: 281–284.10.5012/bkcs.2005.26.2.281Search in Google Scholar

Lee JD, Jun JH, Park NK, Ryu SO, Lee TJ. A study on selective oxidation of hydrogen sulfide over zeolite-NaX and-KX catalysts. Korean J Chem Eng 2005b; 22: 36–41.10.1007/BF02701459Search in Google Scholar

Lee JD, Han GB, Park NK, Ryu SO, Lee TJ. The selective oxidation of H2S on V2O5/zeolite-X catalysts in an IGCC system. J Ind Eng Chem 2006; 12: 80–85.Search in Google Scholar

Leon CAL, In LRR, Thrower PA. Chemistry and physics of carbon. New York, 1992; 24: 213.Search in Google Scholar

Li JL, Chen BH. Review of CO2 absorption using chemical solvents in hollow fiber membrane contactors. Sep Purif Technol 2005; 41: 109–122.10.1016/j.seppur.2004.09.008Search in Google Scholar

Li K, Wang D, Koe CC, Teo WK. Use of asymmetric hollow fibre modules for elimination of H2S from gas streams via a membrane absorption method. Chem Eng Sci 1998; 53: 1111–1119.10.1016/S0009-2509(97)00343-6Search in Google Scholar

Li K, Kong JF, Wang D, Teo WK. Tailor-made asymmetric PVDF hollow fibers for soluble gas removal. AIChE J 1999; 45: 1211–1219.10.1002/aic.690450607Search in Google Scholar

Li K, Kong J, Tan X. Design of hollow fibre membrane modules for soluble gas removal. Chem Eng Sci 2000; 55: 5579–5588.10.1016/S0009-2509(00)00193-7Search in Google Scholar

Lu JG, Zheng YF, He DL. Selective absorption of H2S from gas mixtures into aqueous solutions of blended amines of methyldiethanolamine and 2-tertiarybutylamino-2-ethoxyethanol in a packed column. Sep Purif Technol 2006; 52: 209–217.10.1016/j.seppur.2006.04.003Search in Google Scholar

Lu JG, Zheng YF, Cheng MD. Wetting mechanism in mass transfer process of hydrophobic membrane gas absorption. J Membr Sci 2008; 308: 180–190.10.1016/j.memsci.2007.09.051Search in Google Scholar

Lu Y, Yu X, Tu ST, Yan J, Dahlquist E. Wetting of polypropylene hollow fiber membrane contactors. J Membr Sci 2010; 362: 444–452.10.1016/j.memsci.2010.06.067Search in Google Scholar

Ma G, Yan H, Shi J, Zong X, Lei Z, Li C. Direct splitting of H2S into H2 and S on CdS-based photocatalyst under visible light irradiation. J Catal 2008; 260: 134–140.10.1016/j.jcat.2008.09.017Search in Google Scholar

Malek A, Li K, Teo W. Modeling of microporous hollow fiber membrane modules operated under partially wetted conditions. Ind Eng Chem Res 1997; 36: 784–793.10.1021/ie960529ySearch in Google Scholar

Mamrosh D, Beitler C, Fisher K. Consider improved scrubbing designs for acid gases: Better application of process chemistry enables efficient sulfur abatement. Hydrocarb Process 2008; 69–74.Search in Google Scholar

Manahan S. Fundamentals of aquatic chemistry. Environmental chemistry. 6th edition. Boca Raton, FL: CRC Press, 1994: 47–86.Search in Google Scholar

Mandal B, Bandyopadhyay S. Simultaneous absorption of carbon dioxide and hydrogen sulfide into aqueous blends of 2-amino-2-methyl-1-propanol and diethanolamine. Chem Eng Sci 2005; 60: 6438–6451.10.1016/j.ces.2005.02.044Search in Google Scholar

Mansourizadeh A, Ismail AF. Hollow fiber gas-liquid membrane contactors for acid gas capture: a review. J Hazard Mater 2009; 171: 38–53.10.1016/j.jhazmat.2009.06.026Search in Google Scholar PubMed

Mansourizadeh A, Ismail A, Matsuura T. Effect of operating conditions on the physical and chemical CO2 absorption through the PVDF hollow fiber membrane contactor. J Membr Sci 2010; 353: 192–200.10.1016/j.memsci.2010.02.054Search in Google Scholar

Marcano JGS, Tsotsis TT, Wiley J. Catalytic membranes and membrane reactors. Weimheim: Wiley-VCH, 2002.Search in Google Scholar

Mavroudi M, Kaldis SP, Sakellaropoulos GP. A study of mass transfer resistance in membrane gas-liquid contacting processes. J Membr Sci 2006; 272: 103–115.10.1016/j.memsci.2005.07.025Search in Google Scholar

Mojtahedi W, Abbasian J. H2S removal from coal gas at elevated temperature and pressure in fluidized bed with zinc titanate sorbents. 1. Cyclic tests. Energ Fuel 1995; 9: 429–434.10.1021/ef00051a006Search in Google Scholar

Monnery WD, Svrcek WY, Behie LA. Modelling the modified Claus process reaction furnace and the implications on plant design and recovery. Can J Chem Eng 1993; 71: 711–724.10.1002/cjce.5450710509Search in Google Scholar

Monnery W, Hawboldt K, Pollock A, Svrcek W. New experimental data and kinetic rate expression for the Claus reaction. Chem Eng Sci 2000; 55: 5141–5148.10.1016/S0009-2509(00)00146-9Search in Google Scholar

Mora RL. Sulphur condensation influence in Claus catalyst performance. J Hazard Mater 2000; 79: 103–115.10.1016/S0304-3894(00)00193-XSearch in Google Scholar

Nasato LV, Karan K, Mehrotra AK, Behie LA. Modeling reaction quench times in the waste heat boiler of a Claus plant. Ind Eng Chem Res 1994; 33: 7–13.10.1021/ie00025a002Search in Google Scholar

Neomagus H, van Swaaij W, Versteeg G. The catalytic oxidation of H2S in a stainless steel membrane reactor with separate feed of reactants. J Membr Sci 1998; 148: 147–160.10.1016/S0376-7388(98)00155-0Search in Google Scholar

Nguyen TD, Bandosz TJ. Activated carbons with metal containing bentonite binders as adsorbents of hydrogen sulfide. Carbon 2005; 43: 359–367.10.1016/j.carbon.2004.09.023Search in Google Scholar

Nguyen P, Nhut JM, Edouard D, Pham C, Ledoux MJ, Pham-Huu C. Fe2O3/β-SiC: a new high efficient catalyst for the selective oxidation of H2S into elemental sulfur. Catal Today 2009; 141: 397–402.10.1016/j.cattod.2008.10.047Search in Google Scholar

Ni JQ, Heber AJ, Diehl CA, Lim TL. Ammonia, hydrogen sulfide and carbon dioxide release from pig manure in under-floor deep pits. J Agric Eng Res 2000; 77: 53–66.Search in Google Scholar

Nomura M, Seshimo M, Aida H, Nakatani K, Gopalakrishnan S, Sugawara T, Ishikawa T, Kawamura M, Nakao S. Preparation of a catalyst composite silica membrane reactor for steam reforming reaction by using a counterdiffusion CVD method. Ind Eng Chem Res 2006; 45: 3950–3954.10.1021/ie051345zSearch in Google Scholar

Ohashi H, Ohya H, Aihara M, Negishi Y, Semenova SI. Hydrogen production from hydrogen sulfide using membrane reactor integrated with porous membrane having thermal and corrosion resistance. J Membr Sci 1998; 146: 39–52.10.1016/S0376-7388(98)00089-1Search in Google Scholar

Ohashi H, Ohya H, Aihara M, Takeuchi T, Negishi Y, Fan J, Semenova SI. Analysis of a two-stage membrane reactor integrated with porous membrane having Knudsen diffusion characteristics for the thermal decomposition of hydrogen sulfide. J Membr Sci 2000; 166: 239–247.10.1016/S0376-7388(99)00267-7Search in Google Scholar

Paik SC, Chung JS. Selective catalytic reduction of sulfur dioxide with hydrogen to elemental sulfur over Co-Mo/Al2O3. Appl Catal B Environ 1995; 5: 233–243.10.1016/0926-3373(94)00041-7Search in Google Scholar

Park DW, Park BK, Park DK, Woo HC. Vanadium-antimony mixed oxide catalysts for the selective oxidation of H2S containing excess water and ammonia. Appl Catal A Gen 2002; 223: 215–224.10.1016/S0926-860X(01)00760-8Search in Google Scholar

Park DW, Hwang BH, Ju WD, Kim MI, Kim KH, Woo HC. Selective oxidation of hydrogen sulfide containing excess water and ammonia over Bi-V-Sb-O catalysts. Korean J Chem Eng 2005a; 22: 190–195.10.1007/BF02701483Search in Google Scholar

Park NK, Lee DH, Lee JD, Chang W, Ryu SO, Lee TJ. Effects of reduction of metal oxide sorbents on reactivity and physical properties during hot gas desulphurization in IGCC. Fuel 2005b; 84: 2158–2164.10.1016/j.fuel.2005.06.004Search in Google Scholar

Pi JH, Lee DH, Lee JD, Jun JH, Park NK, Ryu SO, Lee TJ. The study on the selective oxidation of H2S over the mixture zeolite NaX-WO3 catalysts. Korean J Chem Eng 2004; 21: 126–131.10.1007/BF02705390Search in Google Scholar

Pillai KC, Chung SJ, Raju T, Moon IS. Experimental aspects of combined NOx and SO2 removal from flue-gas mixture in an integrated wet scrubber-electrochemical cell system. Chemosphere 2009; 76: 657–664.10.1016/j.chemosphere.2009.04.013Search in Google Scholar PubMed

Przepiorski J, Oya A. K2CO3-loaded deodorizing activated carbon fibre against H2S gas: factors influencing the deodorizing efficiency and the regeneration method. J Mater Sci Lett 1998; 17: 679–682.10.1023/A:1006636710959Search in Google Scholar

Puchyr DMJ, Mehrotra AK, Behie LA, Kalogerakis N. Hydrodynamic and kinetic modelling of circulating fluidized bed reactors applied to a modified Claus plant. Chem Eng Sci 1996; 51: 5251–5262.10.1016/S0009-2509(96)00364-8Search in Google Scholar

Rajabzadeh S, Yoshimoto S, Teramoto M, Al-Marzouqi M, Matsuyama H. CO2 absorption by using PVDF hollow fiber membrane contactors with various membrane structures. Sep Purif Technol 2009; 69: 210–220.10.1016/j.seppur.2009.07.021Search in Google Scholar

Ryu CK, Lee JB, D.H. DH, Kim JJ, Yi CK. Highly attrition resistant zinc oxide-based sorbents for H2S removal by spray drying technique. In: Presented at Fifth International Symposium on Gas Cleaning at High Temperatures, Morgantown, West Virginia, 2002.Search in Google Scholar

Sassi M, Gupta AK. Sulfur recovery from acid gas using the Claus process and high temperature air combustion (HiTAC) technology. Am J Environ Sci 2008; 4: 502–511.10.3844/ajessp.2008.502.511Search in Google Scholar

Seredych M, Bandosz TJ. Adsorption of hydrogen sulfide on graphite derived materials modified by incorporation of nitrogen. Mater Chem Phys 2009; 113: 946–952.10.1016/j.matchemphys.2008.08.073Search in Google Scholar

Shahid M, Faisal M. Effect of hydrogen sulfide gas concentration on the corrosion behavior of “ASTM A-106 grade-A” carbon steel in 14% diethanol amine solution. Arab J Sci Eng 2009; 34: 179–186.Search in Google Scholar

Slimane RB, Abbasian J. Regenerable mixed metal oxide sorbents for coal gas desulfurization at moderate temperatures. Adv Environ Res 2000; 4: 147–162.10.1016/S1093-0191(00)00017-4Search in Google Scholar

Sloot H, Versteeg G, Van Swaaij W. A non-permselective membrane reactor for chemical processes normally requiring strict stoichiometric feed rates of reactants. Chem Eng Sci 1990; 45: 2415–2421.10.1016/0009-2509(90)80123-VSearch in Google Scholar

Su H, Wang S, Niu H, Pan L, Wang A, Hu Y. Mass transfer characteristics of H2S absorption from gaseous mixture into methyldiethanolamine solution in a T-junction microchannel. Sep Purif Technol 2010; 72: 326–334.10.1016/j.seppur.2010.02.024Search in Google Scholar

Trujillo FJ, Hardiman KM, Adesina AA. Catalytic decomposition of H2S in a double-pipe packed bed membrane reactor: numerical simulation studies. Chem Eng J 2008; 143: 273–281.10.1016/j.cej.2008.02.028Search in Google Scholar

Tsai JH, Tsai CL, Hsu YC, Chiang HL. Adsorption of hydrogen sulfide and methyl mercaptan mixture gas on alkaline activated carbon. J Chin Inst Environ Eng 1999; 9: 145–152.Search in Google Scholar

Tsuru T, Yamaguchi K, Yoshioka T, Asaeda M. Methane steam reforming by microporous catalytic membrane reactors. AlChE J 2004; 50: 2794–2805.10.1002/aic.10215Search in Google Scholar

Turpin A, Couvert A, Laplanche A, Paillier A. Experimental study of mass transfer and H2S removal efficiency in a spray tower. Chem Eng Process Process Intensif 2008; 47: 886–892.10.1016/j.cep.2007.02.002Search in Google Scholar

Uhm JH, Shin MY, Zhidong J, Chung JS. Selective oxidation of H2S to elemental sulfur over chromium oxide catalysts. Appl Catal B Environ 1999; 22: 293–303.10.1016/S0926-3373(99)00057-0Search in Google Scholar

Wang D, Teo WK, Li K. Removal of H2S to ultra-low concentrations using an asymmetric hollow fibre membrane module. Sep Purif Technol 2002; 27: 33–40.10.1016/S1383-5866(01)00186-1Search in Google Scholar

Wang D, Teo WK, Li K. Selective removal of trace H2S from gas streams containing CO2 using hollow fibre membrane modules/contractors. Sep Purif Technol 2004a; 35: 125–131.10.1016/S1383-5866(03)00135-7Search in Google Scholar

Wang R, Li DF, Liang DT. Modeling of CO2 capture by three typical amine solutions in hollow fiber membrane contactors. Chem Eng Process 2004b; 43: 849–856.10.1016/S0255-2701(03)00105-3Search in Google Scholar

Wang R, Li D, Zhou C, Liu M, Liang D. Impact of DEA solutions with and without CO2 loading on porous polypropylene membranes intended for use as contactors. J Membr Sci 2004c; 229: 147–157.10.1016/j.memsci.2003.10.022Search in Google Scholar

Wang R, Zhang HY, Feron PHM, Liang DT. Influence of membrane wetting on CO2 capture in microporous hollow fiber membrane contactors. Sep Purif Technol 2005; 46; 33–40.10.1016/j.seppur.2005.04.007Search in Google Scholar

Wang L, Cao B, Wang S, Yuan Q. H2S catalytic oxidation on impregnated activated carbon: experiment and modelling. Chem Eng J 2006; 118: 133–139.10.1016/j.cej.2005.12.021Search in Google Scholar

Wu X, Schwartz V, Overbury SH, Armstrong TR. Desulfurization of gaseous fuels using activated carbons as catalysts for the selective oxidation of hydrogen sulfide. Energ Fuel 2005; 19: 1774–1782.10.1021/ef0500890Search in Google Scholar

Xie W, Chang L, Wang D, Xie K, Wall T, Yu J. Removal of sulfur at high temperatures using iron-based sorbents supported on fine coal ash. Fuel 2010; 89: 868–873.10.1016/j.fuel.2009.01.006Search in Google Scholar

Xiao Y, Wang S, Wu D, Yuan Q. Catalytic oxidation of hydrogen sulfide over unmodified and impregnated activated carbon. Sep Purif Technol 2008; 59: 326–332.10.1016/j.seppur.2007.07.042Search in Google Scholar

Yang X, Park DW, Kim MI. Selective oxidation of hydrogen sulfide over LaSrCoO4 and LaSrCoO3.6F0.4 mixed oxides. Ind Eng Chem Res 2007; 13: 265–271.Search in Google Scholar

Zaman J, Chakma A. Production of hydrogen and sulfur from hydrogen sulfide. Fuel Process Technol 1995; 41: 159–198.10.1016/0378-3820(94)00085-8Search in Google Scholar

Zhai LF, Song W, Tong ZH, Sun M. A fuel-cell-assisted iron redox process for simultaneous sulfur recovery and electricity production from synthetic sulfide wastewater. J Hazard Mater 2002; 243: 350–356.10.1016/j.jhazmat.2012.10.046Search in Google Scholar

Zhang J, Tong Z. Study on catalytic wet oxidation of H2S into sulfur on Fe/Cu catalyst. J Nat Gas Chem 2006; 15: 63–69.10.1016/S1003-9953(06)60009-1Search in Google Scholar

Zhang HY, Wang R, Liang DT, Tay JH. Modeling and experimental study of CO2 absorption in a hollow fiber membrane contactor. J Membr Sci 2006; 279: 301–310.10.1016/j.memsci.2005.12.017Search in Google Scholar

Zhang HY, Wang R, Liang DT, Tay JH. Theoretical and experimental studies of membrane wetting in the membrane gas-liquid contacting process for CO2 absorption. J Membr Sci 2008; 308: 162–170.10.1016/j.memsci.2007.09.050Search in Google Scholar

Zhang S, Osterman M, Shrivastava A, Kang R, Pecht MG. The influence of H2S exposure on immersion-silver-finished PCBs under mixed-flow gas testing. IEEE Trans Device Mater Reliab 2010; 10: 71–81.10.1109/TDMR.2009.2033194Search in Google Scholar

Zhao H, Zhang D, Wang F, Wu T, Gao J. Modification of ferrite-manganese oxide sorbent by doping with cerium oxide. Process Saf Environ 2008; 86: 448–454.10.1016/j.psep.2008.06.002Search in Google Scholar

Zhu B, Li H, Yang W. AgBiVMo oxide catalytic membrane for selective oxidation of propane to acrolein. Catal Today 2003; 82: 91–98.10.1016/S0920-5861(03)00206-2Search in Google Scholar

Received: 2013-5-19
Accepted: 2013-7-31
Published Online: 2013-09-17
Published in Print: 2013-12-01

©2013 by Walter de Gruyter Berlin Boston

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