Skip to main content
Log in

Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment

  • Reviewed Papers
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Boiler tube steels, namely low carbon steel ASTM-SA-210-Grades A1 (GrA1), 1Cr-0.5Mo steel ASTM-SA213-T-11 (T11), and 2.25Cr-1 Mo steel ASTM-SA213-T-22(T22), were used as substrate steels. Ni-22Cr-10Al-1Y powder was sprayed as a bond coat 150 μm thick before a 200 μm final coating of Ni-20Cr was applied Coatings were characterized prior to testing in the environment of a coal fire boiler. The uncoated and coated steels were inserted in the platen superheater zone of a coal fired boiler at around 755°C for 10 cycles, each 100 h. Coated steels showed lower degradation (erosion-corrosion) rate than uncoated steels showed. The lowest rate was observed in the case of Ni-20Cr coated T11 steel. Among the uncoated steels, the observed rate of degradation was the lowest for the T22 steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R.A. Rapp, J.H. Devan, D.L. Douglass, P.C. Nordine, F.S. Pettit, and D.P. Whittle, High Temperature Corrosion in Energy Systems, Mater. Sci. Eng., 1981, 50, p 1–17

    Article  CAS  Google Scholar 

  2. S. Danyluk and J.Y. Park, Technical Note: Corrosion and Grain Boundary Penetration in Type 316 Stainless Steel Exposed to a Coal Gasification Environment, Corrosion, 1979, 35 (12), p 575–576

    CAS  Google Scholar 

  3. D. Wang, Corrosion Behavior of Chromized and/or Aluminized 21/4Cr-1Mo Steel in Medium-BTU Coal Gasifier Environments, Surf. Coat. Technol., 1988, 36, p 49–60

    Article  CAS  Google Scholar 

  4. A.V. Levy, The Erosion-Corrosion of Tubing Stels in Combusion Boiler Environments, Corros. Sci., 1993, 35 (5–8), p 1035–1043

    Article  CAS  Google Scholar 

  5. S. Prakash, S. Singh, B.S. Sidhu, and A. Madeshia, Tube Failures in Coal Fired Boilers. S. Ray, S. Singh, and S.K. Nath, Ed., Proc. National Seminar on Advances in Material and Processing, IIT, R.K. Printers and Publishers, Roorkee, India, 2001, p 245–253

    Google Scholar 

  6. N. Priyantha, P. Jayaweera, A. Sanjurjo, K. Lau, F. Lu, and K. Krist, Corrosion-Resistant Metallic Coatings for Applications in Highly Aggressive Environments, Surf. Coat. Technol., 163–64, p 31–36

  7. M. Yoshiba, Effect of Hot Corrosion on the Mechanical Performances of Superalloys and Coating Systems, Corros Sci., 1993, 35 (5–8), p 1115–1124

    Article  CAS  Google Scholar 

  8. P. Fauchais, J.F. Coudert, and M. Vardelle, Transient Phenomena in Plasma Torches and in Plasma Sprayed Coating Generation, J. Phys. IV, 1997, 7, p C4-187-198

    Article  Google Scholar 

  9. R.F. Bunshah, Handbook of Hard Coatings, Deposition Technologics, Properties and Applications, Noyes Pub., Park Ridge, NJ, 2001

    Google Scholar 

  10. M.D. Modi, S.C. Modi, and M.M. Mayuram, A Case Study on the Use of Plasma Sprayed Oxide Ceramic Coatings in Hot Extrusion Dies for Non-Ferrous Metals, Proc. 11th Int. Thermal Spraying Conf., September 8–12, Montreal, Canada, 1986, p 359–366

  11. C. Wu and M. Okuyama, Evaluation of High Temperature Corrosion Resistance of AlPlasma Spray Coatings in Molten Sulfates at 1073 K by Electrochemical Measurements, Mater. Trans., JIM, 1996, 37 (5), p 991–997

    CAS  Google Scholar 

  12. V.H. Hidalgo, F.J.B. Varela, and E.F. Rico, Erosion Wear and Mechanical Properties of Plasma-Sprayed Nickel-and Iron-Based Coatings Subjected to Service Conditions in Boilers, Trib Int., 1997, 30 (9), p 641–649

    Article  CAS  Google Scholar 

  13. V.H. Hidalgo, F.J.B. Varela, S.P. Martinez, and S.G. Espana, Characterization and High Temperature Behaviour of Cr3C2−NiCr Plasma Sprayed Coatings, Proc. of the United Thermal Spray Conf., Germany, 1999, p 683–686

  14. V.H. Hidalgo, J.B. Varela, J.M. Calle, and A.C. Menendez, Characterisation of NiCr Flame and Plasma Sprayed Coatings for Use in High Temperature Regions of Boilers, Surf. Eng., 2000, 16 (2), p 137–142

    Article  CAS  Google Scholar 

  15. B.S. Sidhu and S. Prakash, Evaluation of the Corrosion Behaviour of Plasma-Sprayed Ni3Al Coatings on Steel in Oxidation and Molten Salt Environment at 900°C, Surf. Coat. Technol, 2003, 166 (1), p 89–100

    Article  CAS  Google Scholar 

  16. B.S. Sidhu and S. Prakash, Plasma Spray Coatings on Ni−20Cr on Boiler Tube Steel and Evaluation of Its Oxidation Behaviour at 900°C in Air, J. Corros. Sci. Eng., 2003, 6, Paper 88.

    Google Scholar 

  17. B.S. Sidhu, D. Puri, and S. Prakash, Characterisations of Plasma Sprayed and Laser Remelted NiCrAlY Bond Coats and Ni3Al Coatings on Boiler Tube Steels, Mater. Sci. Eng. A, 2004, 368 (1–2), p 149–158

    Google Scholar 

  18. B.S. Sidhu, D. Puri, and S. Prakash, Mechanical and Metallurgical Properties of Plasma Sprayed and Laser Remelted Ni−20Cr and Stellite-6 Coatings, J. Mater. Process. Technol., 2005, 159 (3), p 347–355

    Article  CAS  Google Scholar 

  19. H.C. Chen, Z.Y. Liu, and Y.C. Chuang, Degradation of Plasma-Sprayed Alumina and Zirconia Coatings on Stainless Steel During Thermal Cycling and Hot Corrosion, Thin Solid Films, 1993, 223 (1), p 56–64

    Article  CAS  Google Scholar 

  20. L.C. Erickson, R. Westergard, U. Wiklund, N. Axen, H.M. Hawthorne, and S. Hogmark, Cohesion in Plasma-Sprayed Coatings: A Comparison Between Evaluation Methods, Wear, 1998, 214, p 30–37

    Article  CAS  Google Scholar 

  21. V.H. Hidalgo, F.J.B. Varela, and A.C. Menendez Characterization and High Temperature Behaviour of Thermal Sprayed Coatings Used in Boilers, Proc. of the 15th Int. Thermal Spray Conf., May 25–29, Nice, France, 1998, p 617–621

  22. F.J. Belzunce, V. Higuera, and S. Poveda, High Temperature Oxidation of HFPD Thermal-Sprayed MCrAlY Coatings, Mater. Sci. Eng. A, 2001, 297 (1–2), p 162–167

    Google Scholar 

  23. P. Vuoristo, K. Niemi, A. Makela, and T. Mantyla, Abrasion and Erosion Wear Resistance of Cr3C2−NiCr Coatings Prepared by Plasma, Detonation and High-Velocity Oxyfuel Spraying, Proc. of the 7th National Thermal Spray Conf., Boston, MA, 1994, p 121–126

  24. H. Chen and I.M. Hutchings, Abrasive Wear Resistance of Plasma-Sprayed Tungsten Carbide-Cobalt Coatings, Surf. Coat. Technol., 1998, 107, p 106–114

    Article  CAS  Google Scholar 

  25. S.E. Sadique, A.H. Mollah, M.S. Islam, M.M. Ali, M.H.H. Megat, and S. Basri, High-Temperature Oxidation Behavior of Iron-Chromium-Aluminum Alloys, Oxid. Met., 2000, 54 (5–6), p 385–400

    Article  CAS  Google Scholar 

  26. P.D. Miller and H.H. Krause, Factors Influencing the Corrosion of Boiler Steels in Municipal Incinerators, Corrosion, 1971, 27 (1), p 31–45

    CAS  Google Scholar 

  27. S. Srikanth, B. Ravikumar, S.K. Das, K. Gopalakrishna, K. Nandakumar, and P. Vijayan, Analysis of Failures in Boiler Tubes Due to Fireside Corrosion in a Waste Heat Recovery Boilet, Eng. Failure Anal., 2003, 10, p 59–66

    Article  CAS  Google Scholar 

  28. H.E. Crossley, A. Poll, and F. Sweett, The Reduction of Sulphur Trioxide by Constituents of Boiler Flue Dust, J. Inst. Fuel, 1948, 21, p 207–209

    CAS  Google Scholar 

  29. Y. Longa-Nava, Y.S. Zhang, M. Takemoto, and R.A. Rapp, Hot Corrosion of Nickel-Chromium and Nickel-Chromium-Aluminum Thermal-Spray Coatings by Sodium Sulfate-Sodium Metavanadate Salt, Corrosion, 1996, 52 (9), p 680–689

    Article  CAS  Google Scholar 

  30. G. Calvarin, R. Molins, and A.M. Huntz, Oxidation Mechanism of Ni−20Cr Foils and Its Relation to the Oxide-Scale Microstructure, Oxid. Met., 2000, 53 (1–2), p 25–48

    Article  CAS  Google Scholar 

  31. H. Nickel, W.J. Quadakkers, and L. Singheiser, Analysis of Corrosion Layers on Protective Coatings and High Temperature Materials in Simulated Service Environments of Modern Power Plants Using SNMS, SIMS, SEM, TEM, RBS and X-Ray Diffraction Studies, Anal. Bioanal. Chem., 2002, 374, p 581–587

    Article  CAS  Google Scholar 

  32. R.C. John, Slag, Gas and Deposit Thermochemistry in a Coal Gasifier, J. Electrochem. Soc., 1986, 133 (1), p 205–211

    Article  CAS  Google Scholar 

  33. H.W. Nelson, H.H. Krause, E.W. Ungar, A.A. Putnam, C.J. Slunder, P.D. Miller, J.D. Hummel, and B.A. Landry, A Review of Available Information on Corrosion and Deposits in Coal- and Oil-Fired Boilers and Gas Turbines, Report of ASME Research Committee on Corrosion and Deposits from Combustion Gases, Pergamon Press and ASME, New York, 1959.

    Google Scholar 

  34. X. Wu, D. Weng, Z. Chen, and L. Xu, Effects of Plasma-Sprayed Ni−CrAl/ZrO2 Intermediate on the Combination Ability of Coatings, Surf. Coat. Technol., 2001, 140, p 231–237

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sidhu, B.S., Prakash, S. Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment. J Therm Spray Tech 15, 131–140 (2006). https://doi.org/10.1361/105996306X92695

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1361/105996306X92695

Keywords

Navigation