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Publicly Available Published by De Gruyter January 1, 2009

Organometallic pentalene complexes

  • F. Geoffrey N. Cloke

Abstract

There has been a recent renaissance in the organometallic chemistry of pentalene, following the discovery of the first complexes incorporating pentalene η8-ligated to a single metal center. This short review outlines recent work in the author's laboratory on the preparation of silylated pentalene ligands and the subsequent synthesis of novel, monometallic, and bimetallic pentalene sandwich and half-sandwich complexes of the f- and d-block elements.


Conference

International Conference on Organometallic Chemistry (XIX ICOMC), International Conference on Organometallic Chemistry, ICOMC, Organometallic Chemistry, XIXth, Shanghai, China, 2000-07-23–2000-07-28


Published Online: 2009-01-01
Published in Print: 2001-01-01

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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