In this contribution, a brief survey of the multiple synthetic opportunities offered by the I2/Et3SiH combined system is presented. Both reagents are cheap and easy to handle, and their combination allows HI to be quickly formed in situ. A suitable stoichiometry of the mixture can be addressed to a set of very useful transformations of carbohydrate chemistry ranging from glycosidation reactions to functional group manipulation of sugars.
Conference
European Carbohydrate Symposium (Eurocarb-16), 16th, Sorrento, Italy, 2011-07-03–2011-07-07
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