Urea Selective Catalytic Reduction (urea SCR) system is widely used for diesel engine to reduce the emission of NO_x by NH₃ which is provided by a hydrolysis of urea water. Concentration distribution of NH₃ in an exhaust pipe is an important factor for improvement of the SCR efficiency and prevention of NH₃ slip and urea deposit. Therefore, it is necessary to measure two-dimensional (2D) concentration of NH₃ in detail. The purpose of this study is to develop the real-time two cross-sectional measurements technology of NH₃ concentration using the computed tomography-tunable diode laser absorption spectroscopy (CT-TDLAS). Theoretical NH₃ concentration distribution which was reconstructed by CT agreed to CFD results and quadruple pipe’s results showed good resolution by 14th order reconstruction. Therefore, this method has enough resolution and accuracy for measuring the concentration distribution of NH₃. And this method was employed in a bent pipe model demonstrated a urea SCR system. The experimental results of two cross-sectional 2D concentration of NH₃ show differences of the concentration distribution of NH₃ each cross-section and flow pattern like swirl flow. It was found that CT-TDLAS was an effective method to measure concentration distribution of NH₃ and observe characteristics of flow. In addition, observing flow pattern enable to validate CFD results, and it helps to improve efficiency of after treatment system.