Microwave-Assisted Debromination of α-Bromoketones with Triarylstibanes in Water

Yuki Murata; Yoshiyuki Sugawara; Mio Matsumura; Naoki Kakusawa; Shuji Yasuike

doi:10.1248/cpb.c17-00533

Notes

Microwave-Assisted Debromination of α-Bromoketones with Triarylstibanes in Water

Yuki Murata, Yoshiyuki Sugawara, Mio Matsumura, Naoki Kakusawa, Shuji Yasuike

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Keywords: microwave, debromination, α-bromoketone, triarylstibane, water

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Supplementary material

2017 Volume 65 Issue 11 Pages 1081-1084

DOI https://doi.org/10.1248/cpb.c17-00533

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Abstract

Several α-bromoarylketones were reacted with triarylstibanes under microwave irradiation in water to obtain the corresponding debrominated ketones. Under similar reaction conditions, 1,2-elimination of vic-dibromides in water afforded the corresponding E-olefins. This reaction is the first example of organoantimony compounds utilized for organic transformation in water.

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