Theory of Nematic Ordering in Polydisperse Thermotropic Main-Chain Polymers

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, , Citation A. N. Semenov 1993 EPL 21 37 DOI 10.1209/0295-5075/21/1/007

0295-5075/21/1/37

Abstract

Nematic phase transition in thermotropic semi-flexible polymers is considered. A general theory for polydispersity effects in the system is proposed. It is shown that nematic transition occurs in a finite-temperature gap, δT, where the system separates into lower-(isotropic) and higher-molecular-weight (anisotropic) phases. The width of the gap depends on the polydispersity index, δ; for a given δ, it is inverse proportional to the average degree of polymerization.

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10.1209/0295-5075/21/1/007