Impedance Measurements during Anodization of Aluminum

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© 1979 ECS - The Electrochemical Society
, , Citation H. J. de Wit et al 1979 J. Electrochem. Soc. 126 779 DOI 10.1149/1.2129138

1945-7111/126/5/779

Abstract

The impedance of a growing anodic oxide layer is inductive in a certain frequency range. This effect is related to the occurrence of transients after changes in current density or applied electric field. Measurements on aluminum samples in the frequency range 5 mHz‐10 kHz and the current density range and in various electrolytes are presented and compared with a theory in which the relaxation effect is ascribed to a buildup of surface charge at the metal‐oxide interface.

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10.1149/1.2129138