Abstract
We investigated the effects of water molecules in CsLiB6O10 (CLBO) crystals on UV optical properties. Our results show that long-term heat treatment is necessary to adequately remove water molecules from inside the crystal. The reducing the number of water molecules contained in the crystal improves the transmittance at 266 nm. In addition, the long-term heat-treated crystal can generate three-times higher 266-nm output without bulk damage than a normal sample.