Abstract
The present work introduces the preliminary outcome of one of the tasks inside the MOBARTECH project, that is the creation of the prototype for a compact FORS spectrophotometer capable of automatically identifying pigments and dyes. On the road toward this goal, we focused on the automation of pigment identification, as aspect of great interest which would allow real time analysis with benefit especially for unskilled operators. In this paper, we evaluate high-order derivative approximation pre-processing and features extraction methods, strictly related to the way the database is built; we have chosen to use a dynamic database to be able to elaborate data and give an answer in real time, independently from the experimental set up, and we are planning an interface suitable for both non-skilled and expert users. The aim of the present research is thus to evaluate how spectra pre-processing affects the response and the ability of the search algorithm to correctly identify an unknown spectrum, in order to develop a totally automated pipeline for spectra identification or to prefer an interactive framework.
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Data Availability Statement
This manuscript has associated data in a data repository. [Authors’ comment: The original data and spectra used in this work are available from the corresponding author on request.]
References
M. Picollo, M. Bacci, A. Casini, F. Lotti, S. Porcinai, B. Radicati, L. Stefani, in Optical Sensors and Microsystems: New Concepts, Materials, Technologies. ed. by S. Martellucci, A.N. Chester, A.G. Mignani (Springer, Boston, 2000), pp. 259–265
M. Gargano, N. Ludwig, D. Pandini, J. Int. Colour Assoc. 8, 36–43 (2012)
L. Bonizzoni, S. Bruni, A. Galli, M. Gargano, V. Guglielmi, N. Ludwig, L. Lodi, M. Martini, Microchem. J. 126, 172–180 (2016)
A. Cosentino, Archeomatica 5, 16–22 (2014)
T. Cavaleri, A. Giovagnoli, M. Nervo, Procedia Chem. 8, 45 (2013)
M. Aceto, A. Agostino, G. Fenoglio, A. Idone, M. Gulmini, M. Picollo, P. Ricciardi, J.K. Delaney, Anal. Methods 6, 1488 (2014)
G. Dupuis, M. Menu, Appl. Phys. A 83, 469–474 (2006)
M. Bacci, M. Picollo, G. Trumpy, M. Tsukada, D. Kunzelman, J. Am. Inst. Conserv. 46, 27 (2007)
B. Fonseca, C. Schmidt Patterson, M. Ganio, D. MacLennan, K. Trentelman, Heritage Science 7, 92 (2019)
H. Deborah, N. Richard, J.Y. Hardeberg, IEEE J. Select. Top. Appl. Earth Obser. Remote Sens. 8, 3224 (2015)
V. Kumar, J.K. Chhabra, D. Kumar, INFOCOMP J. Comput. Sci. 13, 38 (2014)
J. Li, D.B. Hibbert, S. Fuller, G. Vaughn, Chemom. Intell. Lab. Syst. 82, 50 (2006)
F. van der Meer, Int. J. Appl. Earth Obs. Geoinf. 8, 3 (2006)
K. Wang, H. Wang, Z. Wang, Y. Yin, L. Mao, Y. Zhang, Optik 178, 74 (2019)
A. Plutino, N. Richard, H. Deborah, C. Fernandez-Maloigne, N.G. Ludwig, Color Imaging Conf. 2017, 141 (2017)
F. Fazlali, S. Gorji Kandi, Herit. Sci. 8, 93 (2020).
C. Balas, G. Epitropou, A. Tsapras, N. Hadjinicolaou, Multimedia Tools Appl. 77, 9737–9751 (2018)
G.H. Li, Y. Chen, X.J. Sun, P.Q. Duan, Y. Lei, L.F. Zhang, Microchem. J. 155, 104699 (2020)
Y. Liu, S. Lyu, M. Hou, Z. Gao, W. Wang, X. Zhou, Remote Sens. 12, 3415 (2020)
N. Rohani, E. Pouyet, M. Walton, O. Cossairt, A. K. Katsaggelos, in ICASSP 2019 - 2019 IEEE International Conference on Acoustics, Speech and Signal Processing (ICASSP) (2019), pp. 3217–3221
B. Grabowski, W. Masarczyk, P. Głomb, A. Mendys, J. Cult. Herit. 31, 1 (2018)
T. Kleynhans, D.W. Messinger, J.K. Delaney, Microchem. J. 157, 104934 (2020)
C. Ruffin, R. L. King, in IEEE 1999 International Geoscience and Remote Sensing Symposium. IGARSS’99 (Cat. No.99CH36293) (1999), pp. 756–758 vol. 2
F. Tsai, W. D. Philpot, in Remote Sensing for Geography, Geology, Land Planning, and Cultural Heritage (International Society for Optics and Photonics, 1996), pp. 200–211
F.N. Fritsch, R.E. Carlson, SIAM J. Numer. Anal. 17, 238 (1980)
A. Savitzky, M.J.E. Golay, Anal. Chem. 36, 1627 (1964)
R.H. Yuhas, A.F.H. Goetz, J.W. Boardman, Proc. Summaries 3rd Annu. JPL Airborne Geosci. Workshop. 147 (1992)
DE CARVALHO, O. Abilio and MENESES, Paulo Roberto, Summaries of the 9th JPL Airborne Earth Science Workshop (2000)
Chein-I Chang, in IEEE 1999 International Geoscience and Remote Sensing Symposium. IGARSS’99 (Cat. No.99CH36293) (1999), pp. 509–511 vol.1.
H. Deborah, N. Richard, M.Ö. Úlfarsson, J.A. Benediktsson, J.Y. Hardeberg, in IGARSS 2019 - 2019 IEEE International Geoscience and Remote Sensing Symposium (2019), pp. 1104–1107
N. Eastaugh, V. Walsh, T. Chaplin, and R. Siddall, Pigment Compendium: A Dictionary of Historical Pigments, New edizione (A Butterworth-Heinemann Title, Amsterdam ; Boston, 2004)
M. Gargano, L. Bonizzoni, E. Grifoni, J. Melada, V. Guglielmi, S. Bruni, N. Ludwig, J. Cult. Herit. (2020)
L. Bonizzoni, M. Gargano, N. Ludwig, M. Martini, A. Galli, Appl. Spectrosc., AS 71, 1915 (2017)
A. Galli, M. Gargano, L. Bonizzoni, S. Bruni, M. Interlenghi, M. Longoni, A. Passaretti, M. Caccia, C. Salvatore, I. Castiglioni, M. Martini, Dyes Pigm. 187, 109112 (2021)
A. Galli, M. Caccia, L. Bonizzoni, M. Gargano, N. Ludwig, G. Poldi, M. Martini, Microchem. J. 155, 104730 (2020)
P. Ricciardi, A. Pallipurath, K. Rose, Anal. Methods 5, 3819 (2013)
M.H. van Eikema Hommes, in Changing Pictures: Discoloration in 15th–17th Century Old Paintings (Stvhetype, London, 2004), pp. 51–89.
R.J. Gettens, E.W. Fitzhugh, in Artists’ Pigments (Oxford University Press, Oxford, 1997), p. 183.
R.J. Gettens, G.L. Stout, Painting materials: a short encyclopaedia (Dover Publication, New York, 1966)
A. Tharwat, Appl. Comput. Inf. 17, 168 (2020)
Acknowledgements
This work was supported by Regione Lombardia (Italy) in the framework of the Project “MOBARTECH: una piattaforma mobile tecnologica, interattiva e partecipata per lo studio, la conservazione e la valorizzazione di beni storico-artistici—Call Accordi per la Ricerca e l’Innovazione”. The authors thank the restores from Pinacoteca di Brera for support during data acquisition in situ.
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Melada, J., Bonizzoni, L., Gargano, M. et al. Pre-processing methods for automatic pigment recognition through Vis–NIR reflectance spectra. Eur. Phys. J. Plus 137, 44 (2022). https://doi.org/10.1140/epjp/s13360-021-02262-6
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DOI: https://doi.org/10.1140/epjp/s13360-021-02262-6