Abstract.
This outlook paper focuses on micelles formed by ABC triblock copolymers (triblock terpolymers) and related systems resulting from mixtures of diblock copolymers. Micelles with different internal structure such as micelles with a heterogeneous core and a homogeneous corona or micelles with a homogeneous core and a mixed corona are presented. More complex nanoobjects such as vesicles and Janus particles are also reviewed. Finally, potential applications of these objects are discussed.
Similar content being viewed by others
References
I.W. Hamley, The Physics of Block Copolymers (Oxford University Press, New York, 1998).
G. Riess, Prog. Polym. Sci. 28, 1107 (2003).
H. Mori, A.H.E. Müller, Prog. Polym. Sci. 28, 1403 (2003).
F.S. Bates, G.H. Fredrickson, Phys. Today 52, February issue, 32 (1999).
U. Breiner, U. Krappe, V. Abetz, R. Stadler, Macromol. Chem. Phys. 198, 1051 (1997).
V. Abetz, in Encyclopedia of Polymer Science and Technology, edited by J.I. Kroschwitz, 3rd edition, Vol. 1 (John Wiley & Sons, New York, 2003).
S. Brinkmann, R. Stadler, E.L. Thomas, Macromolecules 31, 6566 (1998).
V. Abetz, K. Markgraf, V. Rebizant, Macromol. Symp. 177, 139 (2002).
J. Kriz, B. Masar, J. Plestil, Z. Tuzar, H. Pospisil, D. Doskocilova, Macromolecules 31, 41 (1998).
G.E. Yu, A. Eisenberg, Macromolecules 31, 5546 (1998).
T. Ishizone, K. Sugiyama, Y. Sakano, H. Mori, A. Hirao, S. Nakahama, Polym. J. 31, 983 (1999).
O. Lambert, S. Reutenauer, G. Hurtrez, P. Dumas, Macromol. Symp. 161, 97 (2000).
Z.L. Zhou, Z.B. Li, Y. Ren, M.A. Hillmyer, T.P. Lodge, J. Am. Chem. Soc. 125, 10182 (2003).
K. Prochazka, T.J. Martin, S.E. Webber, P. Munk, Macromolecules 29, 6526 (1996).
M.R. Talingting, P. Munk, S.E. Webber, Z. Tuzar, Macromolecules 32, 1593 (1999).
J. Plestil, J. Kriz, Z. Tuzar, K. Prochazka, Y.B. Melnichenko, G.D. Wignall, M.R. Talingting, P. Munk, S.E. Webber, Macromol. Chem. Phys. 202, 553 (2001).
C. Tsitsilianis, D. Voulgaris, M. Stepanek, K. Podhajecka, K. Prochazka, Z. Tuzar, W. Brown, Langmuir 16, 6868 (2000).
A. Harada, K. Kataoka, Science 283, 65 (1999).
D.V. Pergushov, E.V. Remizova, M. Gradzielski, P. Lindner, J. Feldthusen, A.B. Zezin, A.H.E. Müller, V.A. Kabanov, Polymer 45, 367 (2004).
F.T. Liu, G.J. Liu, Macromolecules 34, 1302 (2001).
X.S. Wang, M.A. Winnik, I. Manners, Macromolecules 35, 9146 (2002).
C.S. Patrickios, W.R. Hertler, N.L. Abbott, T.A. Hatton, Macromolecules 27, 930 (1994).
W.Y. Chen, P. Alexandridis, C.K. Su, C.S. Patrickios, W.R. Hertler, T.A. Hatton, Macromolecules 28, 8604 (1995).
C.S. Patrickios, A.B. Lowe, S.P. Armes, N.C. Billingham, J. Polym. Sci. Part A: Polym. Chem. 36, 617 (1998).
A.I. Triftaridou, M. Vamvakaki, C.S. Patrickios, Polymer 43, 2921 (2002).
A.I. Triftaridou, M. Vamvakaki, C.S. Patrickios, L. Lue, Macromol. Symp. 183, 133 (2002).
M. Gadzinowski, S. Sosnowski, J. Polym. Sci. Part A: Polym. Chem. 41, 3750 (2003).
C. Tsitsilianis, V. Sfika, Macromol. Rapid Commun. 22, 647 (2001).
C.M. Fernyhough, D. Pantazis, S. Pispas, N. Hadjichristidis, Eur. Polym. J. 40, 237 (2004).
J.F. Gohy, E. Khousakoun, N. Willet, S. Varshney, R. Jérôme, Macromol. Rapid Commun. 25, 1536 (2004).
R. Erhardt, A. Böker, H. Zettl, H. Kaya, W. Pyckhout-Hintzen, G. Krausch, V. Abetz, A.H.E. Müller, Macromolecules 34, 1069 (2001).
H. Xu, R. Erhardt, V. Abetz, A.H.E. Müller, W.A. Goedel, Langmuir 17, 6787 (2001).
R. Erhardt, M.F. Zhang, A. Böker, H. Zettl, C. Abetz, P. Frederik, G. Krausch, V. Abetz, A.H.E. Müller, J. Am. Chem. Soc. 125, 3260 (2003).
Y.F. Liu, V. Abetz, A.H.E. Müller, Macromolecules 36, 7894 (2003).
R. Saito, A. Fujita, A. Ichimura, K. Ishizu, J. Polym. Sci. Part A: Polym. Chem. 38, 2091 (2000).
S.I. Stupp, V. LeBonheur, K. Walker, L.S. Li, K.E. Huggins, M. Keser, A. Amstutz, Science 276, 384 (1997).
G.N. Tew, L.M. Li, S.I. Stupp, J. Am. Chem. Soc. 120, 5601 (1998).
M.U. Pralle, K. Urayama, G.N. Tew, D. Neher, G. Wegner, S.I. Stupp, Angew. Chem. Int. Ed. 39, 1486 (2000).
D.E. Discher, A. Eisenberg, Science 297, 967 (2002).
R. Bieringer, V. Abetz, A.H.E. Müller, Eur. Phys. J. E 5, 5 (2001).
S. Schrage, R. Sigel, H. Schlaad, Macromolecules 36, 1417 (2003).
L.B. Luo, A. Eisenberg, Angew. Chem. Int. Ed. 41, 1001 (2002).
H.G. Dobereiner, E. Evans, M. Kraus, U. Seifert, M. Wortis, Phys. Rev. E 55, 4458 (1997).
L.B. Luo, A. Eisenberg, Langmuir 17, 6804 (2001).
L.B. Luo, A. Eisenberg, J. Am. Chem. Soc. 123, 1012 (2001).
S. Stewart, G.J. Liu, Chem. Mater. 11, 1048 (1999).
S. Stewart, G. Liu, Angew. Chem. Int. Ed. 39, 340 (2000).
R.S. Underhill, G.J. Liu, Chem. Mater. 12, 2082 (2000).
M.V.D. Banez, K.L. Robinson, V. Butun, S.P. Armes, Polymer 42, 29 (2001).
S.Y. Liu, S.P. Armes, J. Am. Chem. Soc. 123, 9910 (2001).
V. Butun, X.S. Wang, M.V.D. Banez, K.L. Robinson, N.C. Billingham, S.P. Armes, Z. Tuzar, Macromolecules 33, 1 (2000).
S.Y. Liu, Y.H. Ma, S.P. Armes, Langmuir 18, 7780 (2002).
S.Y. Liu, J.V.M. Weaver, M. Save, S.P. Armes, Langmuir 18, 8350 (2002).
S.Y. Liu, J.V.M. Weaver, Y.Q. Tang, N.C. Billingham, S.P. Armes, K. Tribe, Macromolecules 35, 6121 (2002).
Q.G. Ma, K.L. Wooley, J. Polym. Sci. Part A: Polym. Chem. 38, 4805 (2000).
J.F. Gohy, N. Willet, S. Varshney, J.X. Zhang, R. Jérôme, Angew. Chem. Int. Ed. 40, 3214 (2001).
J.F. Gohy, N. Willet, S.K. Varshney, J.X. Zhang, R. Jérôme, e-Polymers paper no. 035 (2002).
L.C. Lei, J.F. Gohy, N. Willet, J.X. Zhang, S. Varshney, R. Jérôme, Polymer 45, 4375 (2004).
L.C. Lei, J.F. Gohy, N. Willet, J.X. Zhang, S. Varshney, R. Jérôme, Macromolecules 37, 1089 (2004).
M. Stepanek, J. Humpolickova, K. Prochazka, M. Hof, Z. Tuzar, M. Spirkova, T. Wolff, Collect. Czech. Chem. Commun. 68, 2120 (2003).
A. Khanal, Y. Li, N. Takisawa, N. Kawasaki, Y. Oishi, K. Nakashima, Langmuir 20, 4809 (2004).
J.F. Gohy, B.G.G. Lohmeijer, S.K. Varshney, B. Decamps, E. Leroy, S. Boileau, U.S. Schubert, Macromolecules 35, 9748 (2002).
E. Giebeler, R. Stadler, Macromol. Chem. Phys. 198, 3815 (1997).
C.S. Patrickios, C. Forder, S.P. Armes, N.C. Billingham, J. Polym. Sci. Part A: Polym. Chem. 35, 1181 (1997).
K. Szczubialka, M. Nowakowska, Polymer 44, 5269 (2003).
Y.Q. Tang, S.Y. Liu, S.P. Armes, N.C. Billingham, Biomacromolecules 4, 1636 (2003).
S. Sugihara, S. Kanaoka, S. Aoshima, J. Polym. Sci. Part A: Polym. Chem. 42, 2601 (2004).
L. Leibler, F. Court, V. Rebizant, V. Abetz, F. Tournilhac, C. Navarro, Shock-reinforced thermoplastic compositions comprising a polyamide and a block copolymer, World Patent no. WO2004072180, 2004.
V. Rebizant, V. Abetz, F. Tournilhac, F. Court, L. Leibler, Macromolecules 36, 9889 (2003)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Fustin, C.A., Abetz, V. & Gohy, J.F. Triblock terpolymer micelles: A personal outlooka. Eur. Phys. J. E 16, 291–302 (2005). https://doi.org/10.1140/epje/i2004-10086-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1140/epje/i2004-10086-0