Abstract:
We theoretically study interfacial properties between two coexisting phases in mixtures of a flexible polymer and a low-molecular-weight liquid crystal. By numerically solving Euler equations for compositional and orientational order parameter fields, we calculate the order parameter profiles and interfacial tensions for nematic-isotropic and isotropic-isotropic phase equilibria. We find that the order parameter profiles are non-monotonic at some temperatures. The nematic-isotropic interfacial tension increases with decreasing temperature and is approximately proportional to (T - T NI)n at temperatures below the nematic-isotropic transition temperature ( T NI) of the pure nematogen. The value of the exponent n is strongly affected by the existence of a triple point.
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Received 9 August 2002 and Received in final form 16 October 2002
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Matsuyama, A., Evans, R. & Cates, M. Non-uniformities in polymer/liquid crystal mixtures . Eur. Phys. J. E 9, 79–87 (2002). https://doi.org/10.1140/epje/i2002-10061-9
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DOI: https://doi.org/10.1140/epje/i2002-10061-9