Abstract.
A system of three electrolytes separated by two parallel planes is considered. Each region is described by a dielectric constant and a Coulomb fluid in the Debye-Hückel regime. In their book Dispersion Forces, Mahanty and Ninham have given the van der Waals free energy of this system. We rederive this free energy by a different method, using linear response theory and the electrostatic Maxwell stress tensor for obtaining the dispersion force.
Similar content being viewed by others
References
J. Mahanty, B.W. Ninham, Dispersion Forces (Academic, London, 1976), equation (7.49)
B.W. Ninham, V.A. Parsegian, G.H. Weiss, J. Stat. Phys. 2, 323 (1970)
R.R. Netz, Eur. Phys. J. E 5, 189 (2001)
B. Jancovici, L. Šamaj, J. Stat. Mech. P08006 (2004)
A. Alastuey, W. Appel, Physica A 276, 508 (2000)
P.R. Buenzli, Ph.A. Martin, Europhys. Lett. 72, 42 (2005)
B. Jancovici, L. Šamaj, Europhys. Lett. 72, 35 (2005)
J.D. Jackson, Classical Electrodynamics (John Wiley, New York, 1975)
L. Šamaj, I. Travěnec, J. Stat. Phys. 101, 713 (2000)
B.W. Ninham, V. Yaminsky, Langmuir 13, 2097 (1997)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jancovici, B. A van der Waals free energy in electrolytes revisited. Eur. Phys. J. E 19, 1–4 (2006). https://doi.org/10.1140/epje/e2005-00056-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1140/epje/e2005-00056-3