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Structure of polymer micelles close to the solid interface

A grazing incidence small angle neutron scattering study

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Abstract.

Block copolymers are widely used in industry. For scientific interests their aqueous solutions offer a model system for the investigation of crystallisation as the macromolecules agglomerate for elevated concentrations into micelles, which crystallise when a critical volume fraction is reached. We report on grazing incidence small angle neutron scattering (GISANS) or near surface small angle neutron scattering (NS-SANS) as an experimental tool to investigate the micelle crystallisation close to interfaces with different chemical termination. We find that in general crystallization is suppressed at a repulsive surface and favoured at an attractive one. Furthermore we show that the crystallization close the interface can be controlled by the micelle stability, resulting from the different composition and length of the monomers. The effect of the interface is found more important for a high micelle stability, whereas for a low stability it is shadowed by adsorbed monomers.

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References

  • M. Vadnere, G. Amidon, S. Lindenbaum et al., Int. J. Pharm. 22, 207 (1984)

    Google Scholar 

  • E.V. Batrakova, S. Li, W.F. Elmquist et al., BJC 85, 1987 (2001)

    Google Scholar 

  • H.-K. Nguyen, P. Lemieux, S.V. Vinogradov et al., Gene Therapy 7, 126 (2000)

    Google Scholar 

  • C. Wu, T. Liu, B. Chu et al., Macromolecules 30, 4574 (1997)

    Google Scholar 

  • J.M. Kim, G.D. Strucky, Chem. Commun. 30, 1159 (2000)

    Google Scholar 

  • S. Ludwigs, A. Boker, A. Voronov et al., Nature materials 2, 744 (2003)

    Google Scholar 

  • S.O. Kim, H.H. Solak, M.P. Stoykovich et al., Nature 424, 411 (2003)

    Google Scholar 

  • E. Huang, T.P. Russell, C. Harrison et al., Macromolecules 31, 7641 (1998)

    Google Scholar 

  • K. Mortensen, Polym. Adv. Technol. 12, 2 (2001)

    Google Scholar 

  • W.-R. Chen, S.-H. Chen, F. Mallamace, Phys. Rev. E 66, 021403 (2002)

    Google Scholar 

  • D.J. McGillivray, R.K. Thomas, A.R. Rennie et al., Langmuir 19, 7719 (2003)

    Google Scholar 

  • M. Wolff, U. Scholz, R. Hock et al., Phys. Rev. Lett. 92, 255501 (2004)

    Google Scholar 

  • L.G. Parratt, Phys. Rev. 95, 359 (1954)

    Article  Google Scholar 

  • M. Wolff, A. Magerl, H. Zabel, Physica B (in press), doi: 10.1016/j.physb.2004.11.027

  • W. Brown, K. Schillen, M. Almgren et al., J. Chem. Phys. 95, 1850 (1991)

    Google Scholar 

Download references

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Authors and Affiliations

  1. Institut Laue-Langevin, BP 156, 38042, Grenoble, France

    M. Wolff

  2. Lehrstuhl für Festkörperphysik, Ruhr-Universität Bochum, 44780, Bochum, Germany

    M. Wolff & H. Zabel

  3. Lehrstuhl für Kristallographie und Strukturphysik, Universität Erlangen-Nürnberg, 91058, Erlangen, Germany

    A. Magerl

Authors
  1. M. Wolff
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  2. A. Magerl
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  3. H. Zabel
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Correspondence to M. Wolff.

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Wolff, M., Magerl, A. & Zabel, H. Structure of polymer micelles close to the solid interface. Eur. Phys. J. E 16, 141–145 (2005). https://doi.org/10.1140/epje/e2005-00015-0

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  • DOI: https://doi.org/10.1140/epje/e2005-00015-0

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