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Thin nanocomposite layers based on a complex of polyaniline and graphene

  • Nanoscale and Nanostructured Materials and Coatings
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Abstract

Two techniques of manufacturing a nanocomposite based on a complex of polyaniline with polymer acid and graphene are proposed. The electric conductivity of thin nanocomposite layers is higher than that of a polymer complex of polyaniline and strongly depends on the degree of oxidation of graphene. An explanation of the effect is suggested that takes into account electron interactions between the graphene planes and polyaniline backbone, as well as the possibility of formation of hydrogen bonds between functional groups of semioxidized graphene and polyacid. The results of surface topography analysis for thin layers of polyaniline and nanocomposite agree well with the regularities of the structure of each layer that are due to the above interactions between graphene and the polymer complex.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    O. D. Omelchenko, O. L. Gribkova, A. R. Tameev, S. V. Novikov & A. V. Vannikov

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  1. O. D. Omelchenko
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  2. O. L. Gribkova
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  3. A. R. Tameev
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  4. S. V. Novikov
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  5. A. V. Vannikov
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Correspondence to O. D. Omelchenko.

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Original Russian Text © O.D. Omelchenko, O.L. Gribkova, A.R. Tameev, S.V. Novikov, A.V. Vannikov, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 5, pp. 512–518.

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Omelchenko, O.D., Gribkova, O.L., Tameev, A.R. et al. Thin nanocomposite layers based on a complex of polyaniline and graphene. Prot Met Phys Chem Surf 50, 613–619 (2014). https://doi.org/10.1134/S207020511405013X

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  • DOI: https://doi.org/10.1134/S207020511405013X

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